Composite anode material made of ionic-conducting electrically insulating material

• US 11,936,035 B2
• Filed: 12/25/2017
• Issued: 03/19/2024
• Est. Priority Date: 01/25/2017
• Status: Active Grant

• Current Assignee: StoreDot Ltd.
• Original Assignee: StoreDot Ltd.
• Inventors: Jacob, David, Remizov, Sergey, Shadmi, Nitzan, Farran, Hani, Aronov, Daniel
• Primary Examiner(s): Sheikh, Haroon S.
• Application Number:
  US15/853,885
• Publication Number:
  US 20180212240A1
• Time in Patent Office: 2,276 Days
• Field of Search: None
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 2004/027 Negative electrodes
• CPC Class Codes: H01M 4/366 as layered products
• CPC Class Codes: H01M 4/38 of elements or alloys
• CPC Class Codes: H01M 4/386 Silicon or alloys based on silicon
• CPC Class Codes: H01M 4/387 Tin or alloys based on tin
• CPC Class Codes: H01M 4/485 of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy H01M4/505, H01M4/525 take precedence
• CPC Class Codes: H01M 4/602 Polymers
• CPC Class Codes: H01M 4/624 Electric conductive fillers
• CPC Class Codes: H01M 4/625 Carbon or graphite
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

Core-shell particles, composite anode material, anodes made therefrom, lithium ion cells and methods are provided, which enable production of fast charging lithium ion batteries. The composite anode material has core-shell particles which are configured to receive and release lithium ions at their cores and to have shells that are configured to allow for core expansion upon lithiation. The cores of the core-shell particles are connected to the respective shells by conductive material such as carbon fibers, which may form a network throughout the anode material and possibly interconnect cores of many core-shell particles to enhance the electrical conductivity of the anode. Ionic conductive material and possibly mechanical elements may be incorporated in the core-shell particles to enhance ionic conductivity and mechanical robustness toward expansion and contraction of the cores during lithiation and de-lithiation.

Claims

1. Composite anode material comprising:

core-shell particles, wherein each of a plurality of the core-shell particles comprises;

a non-porous primary particle configured to receive and release lithium ions, and

a shell configured to allow for expansion of the non-porous primary particle upon lithiation thereof,

wherein the shells of the core-shell particles are made of ionic-conducting, electrically insulating material, and

wherein the core-shell particles comprise one non-porous primary particle fully enclosed by the shell; and

electrically conductive material, comprising conductive carbon fibers and/or CNTs (carbon nanotubes), wherein the conductive carbon fibers and/or CNTs electrically and physically interconnect the non-porous primary particles of different core-shell particles with each other and through the electrically insulating shells.

2. The composite anode material of claim 1, wherein at least some of the electrically conductive material reaches a surface of an anode made of the composite anode material.

3. The composite anode material of claim 1, wherein the core-shell particles further comprise ionic conductive material connecting the non-porous primary particles to the respective shells.

4. The composite anode material of claim 1, wherein the non-porous primary particles are made of at least one of:

Sn, Si, Ge, Pb, P, Sb, Bi, Al, Ga, Zn, Ag, Mg, As, In, Cd, Au, or an alloy thereof.

5. The composite anode material of claim 4, wherein the non-porous primary particles are made of at least one of:

Sn, Si, Ge, or an alloy thereof.

6. The composite anode material of claim 1, wherein the shells further comprise a carbon coating.

7. An anode made of the composite anode material of claim 1.

8. The anode of claim 7, comprising in a range of 50-95 wt % of the core-shell particles, 1-40 wt % of the electrically conductive material and 1-40 wt % of binder material.

9. The composite anode material of claim 1, wherein the conductive carbon fibers and/or CNTs are configured to span multiple core-shell particles, interconnecting with each other multiple respective non-porous primary particles per carbon fiber and/or CNT.

10. The composite anode material of claim 9, comprising SnSi non-porous primary particles, carbon shells and conductive fibers grown in a chemical vapor deposition (CVD) process, using the SnSi non-porous primary particles as seeds.

11. The composite anode material of claim 1, wherein at least some of the core-shell particles further comprise:

ionic conductive material connecting the respective non-porous primary particle with the respective shell,

electrically conductive material connecting the respective non-porous primary particle with the respective shell, and

mechanically compliant material connecting the respective non-porous primary particle with the respective shell.

12. A lithium ion cell comprising the anode of claim 7.

13. The lithium ion cell of claim 12, configured as a fast-charging lithium ion cell.

14. A method of making an anode for a lithium ion cell comprising:

producing core-shell particles to receive and release lithium ions at their cores and to allow for core expansion upon lithiation, within the respective shells, wherein the core-shell particles comprise one non-porous primary particle fully enclosed by the respective shell, and physically and electrically interconnecting non-porous primary particles of different core-shell particles with each other by electrically conductive material comprising conductive carbon fibers and/or CNTs,

wherein the shells of the core-shell particles are made of ionic conducting material which is an electrically insulating material and the physical and electrical interconnection is carried out through the electrically insulating shells.

15. The method of claim 14, further comprising preparing composite anode material from the core-shell particles and forming an anode therefrom.

16. The method of claim 14, further comprising connecting the non-porous primary particles of at least some of the core-shell particles with the respective shells by the electrically conductive material.

17. The method of claim 14, further comprising connecting the non-porous primary particles of the core-shell particles to the respective shells by ionic conductive material.

18. The method of claim 14, further comprising making the shells of the core-shell particles of a brittle, ionic conductive material embedded in a flexible electrically insulating material.

19. The method of claim 18, further comprising configuring the flexible electrically insulating material to expand with the non-porous primary particles upon lithiation of the non-porous primary particles.

20. The method of claim 14, further comprising configuring the lithium ion cell as a fast-charging lithium ion cell.