System and process for removal of pollutants from a gas stream
First Claim
1. An adaptable system for dry removal of oxides of sulfur (SOX) from gases with minimal differential pressure across the system, comprising:
- a. A feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
b. A reaction zone configured for introduction of the sorbent and a gas containing SOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX, the reaction zone being further configured to render the gas that has been substantially stripped of SOX free of reacted and unreacted sorbent so that the gas may be vented from the reaction zone; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
1 Assignment
0 Petitions
Accused Products
Abstract
System for removal of targeted pollutants, such as oxides of sulfur, oxides of nitrogen, mercury compounds and ash, from combustion and other industrial process gases and processes utilizing the system. Oxides of manganese are utilized as the primary sorbent in the system for removal or capture of pollutants. The oxides of manganese are introduced from feeders into reaction zones of the system where they are contacted with a gas from which pollutants are to be removed. With respect to pollutant removal, the sorbent may interact with a pollutant as a catalyst, reactant, adsorbent or absorbent. Removal may occur in single-stage, dual-stage, or multi-stage systems with a variety of different configurations and reaction zones, e.g., bag house, cyclones, fluidized beds, and the like. Process parameters, particularly system differential pressure, are controlled by electronic controls to maintain minimal system differential pressure, and to monitor and adjust pollutant removal efficiencies. Reacted sorbent may be removed from the reaction action zones for recycling or recycled or regenerated with useful and marketable by-products being recovered during regeneration.
24 Citations
96 Claims
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1. An adaptable system for dry removal of oxides of sulfur (SOX) from gases with minimal differential pressure across the system, comprising:
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a. A feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
b. A reaction zone configured for introduction of the sorbent and a gas containing SOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX, the reaction zone being further configured to render the gas that has been substantially stripped of SOX free of reacted and unreacted sorbent so that the gas may be vented from the reaction zone; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level. - View Dependent Claims (4, 5, 27, 30, 31, 32, 33, 36, 37, 38, 39, 44, 48, 77, 78, 79, 80, 81, 82)
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2. An adaptable system for dry removal of oxides of nitrogen (NOX) from gases with minimal differential pressure across the system, comprising:
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a. A feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
b. A reaction zone configured for introduction of the sorbent and a gas containing NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of nitrates of manganese and contacted with the sorbent for a time sufficient to effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, the reaction zone being further configured to render the gas that has been substantially stripped of NOX free of reacted and unreacted sorbent so that the gas may be vented from the reaction zone; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
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3. An adaptable system for dry removal of oxides of sulfur (SOX) and oxides of nitrogen (NOX) from gases with minimal differential pressure across the system, comprising:
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a. A feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
b. A reaction zone configured for introduction of the sorbent and a gas containing SOX and NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of nitrates of manganese and contacted with the sorbent for a time sufficient to simultaneously effect SOX capture at a targeted SOX capture rate set point and NOX capture at a targeted NOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX and the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the reaction zone being further configured to render the gas that has been substantially stripped of SOX and NOX free of reacted and unreacted sorbent so that the gas may be vented from the reaction zone; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level. - View Dependent Claims (34)
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6. An adaptable system for dry removal of oxides of sulfur (SOX) and/or oxides of nitrogen (NOX) from gases with minimal differential pressure across the system, comprising:
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a. A feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
b. A first reaction zone configured for introduction of the sorbent and a gas containing SOX and NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX; and
c. A second reaction zone configured for introduction of sorbent and the gas that has been substantially stripped of SOX from the first reaction zone where the gas is introduced at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the second reaction zone being further configured to render the gas that has been substantially stripped of SOX and NOX free of reacted and unreacted sorbent so that the gas may be vented from the second reaction zone; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
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7. A adaptable system for dry removal of oxides of sulfur (SOX) and/or oxides of nitrogen (NOX) from gases with minimal differential pressure across the system, comprising:
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a. At least one feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g; and
b. A modular reaction unit comprised of at least three (3) interconnected reaction zones, the reaction zones being connected so that a gas containing SOX and/or NOX can be routed through any one of the reaction zones, any two of the reaction zones in series, or all of the at least three reaction zones in series or in parallel, or any combination of series and parallel, each reaction zone being separately connected to the feeder so that sorbent can be introduced into each reaction zone where SOX and/or NOX capture can occur when the gas is contacted with sorbent for a time sufficient to allow formation of sulfates of manganese, nitrates of manganese, or both; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
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8. A adaptable system for dry removal of oxides of sulfur (SOX) and/or oxides of nitrogen (NOX) from gases with minimal differential pressure across the system, comprising:
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a. At least one feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g; and
b. A modular reaction unit comprised of at least three (3) interconnected bag houses, the bag houses being connected so that a gas containing SOX and/or NOX can be routed through any one of the bag houses, any two of the bag houses in series, or all of the at least three bag houses in series or in parallel, or any combination of series and parallel, each bag house being separately connected to the feeder so that sorbent can be introduced into each bag house where SOX and/or NOX capture can occur when the gas is contacted with sorbent for a time sufficient to allow formation of sulfates of manganese, nitrates of manganese, or both; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
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9. An adaptable system for dry removal of oxides of sulfur (SOX) and/or oxides of nitrogen (NOX) from gases with minimal differential pressure across the system, comprising:
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a. At least one feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g; and
b. A modular reaction unit comprised of at least three (3) interconnected reaction zones, the reaction zones being connected so that a gas containing SOX and/or NOX can be routed through any one of the reaction zones, any two of the reaction zones in series, or all of the at least three reaction zones in series or in parallel, or any combination of series and parallel, each reaction zone being separately connected to the feeder so that sorbent can be introduced into each reaction zone where SOX and/or NOX capture can occur when the gas is contacted with sorbent for a time sufficient to allow formation of sulfates of manganese, nitrates of manganese, or both, with SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX and NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, the reaction zones each being configured to render the gas that has been substantially stripped of SOX and/or NOX free of reacted and unreacted sorbent so that the gas that has been substantially stripped of SOX and/or NOX may be vented from the reaction zones or passed from one reaction zone to another reaction zone in series; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
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10. An adaptable system for dry removal of oxides of sulfur (SOX) and/or oxides of nitrogen (NOX) from gases with minimal differential pressure across the system, comprising:
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a. At least one feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g; and
b. A modular reaction unit comprised of at least three (3) interconnected bag houses, the bag houses being connected so that a gas containing SOX and/or NOX can be routed through any one of the bag houses, any two of the bag houses in series, or all of the at least three bag houses in series or in parallel, or any combination of series and parallel, each bag house being separately connected to the feeder so that sorbent can be introduced into each bag house where SOX and/or NOX capture can occur when the gas is contacted with sorbent for a time sufficient to allow formation of sulfates of manganese, nitrates of manganese, or both, with SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX and NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, the bag houses each being configured to render the gas that has been substantially stripped of SOX and/or NOX free of reacted and unreacted sorbent so that the gas that has been substantially stripped of SOX and/or NOX may be vented from the bag houses or passed from one bag house to another bag house in series; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
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11. An adaptable system for removal of oxides of sulfur (SOX) and oxides of nitrogen (NOX) from gases with minimal differential pressure across the system, comprising:
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a. At least one feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
b. A first reaction zone configured for introduction of sorbent and a gas containing SOX and NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX;
the first reaction zone being configured to render the gas that has been substantially stripped of SOX free of reacted and unreacted absorbent so that the gas can be directed out of the first reaction zone free of reacted and unreacted absorbent;
c. A second reaction zone and a third reaction zone each connected to the first reaction zone by a common conduit, where the gas that has been substantially stripped of SOX in the first reaction zone is introduced at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the second and third reaction zones each being configured to render the gas that has been substantially stripped of SOX and NOX free of reacted and unreacted sorbent so that the gas may be vented from the second and third reaction zones free of reacted and unreacted sorbent; and
d. A diverter valve positioned in the common conduit so as to direct the flow of gas from the first reaction zone to the second reaction zone and/or the third reaction zone, the diverter valve having variable positions, in one position gas from the first reaction zone is directed to the second reaction zone, in another position gas from the first reaction zone is directed to both the second and third reaction zones, and in a further position gas from the first reaction zone is directed to the third reaction zone;
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level. - View Dependent Claims (45, 46, 47)
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12. An adaptable system for removal of oxides of sulfur (SOX) and oxides of nitrogen (NOX) from gases with minimal differential pressure across the system, comprising:
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a. At least one feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
b. A first bag house configured for introduction of sorbent and a gas containing SOX and NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX;
the first bag house being configured to render the gas that has been substantially stripped of SOX free of reacted and unreacted absorbent so that the gas can be directed out of the first bag house free of reacted and unreacted absorbent;
c. A second bag house and a third bag house each connected to the first bag house by a common conduit, where the gas that has been substantially stripped of SOX in the first bag house is introduced at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the second and third bag houses each being configured to render the gas that has been substantially stripped of SOX and NOX free of reacted and unreacted sorbent so that the gas may be vented from the second and third bag houses free of reacted and unreacted sorbent; and
d. A diverter valve positioned in the common conduit so as to direct the flow of gas from the first bag house to the second bag house and/or the third bag house, the diverter valve having variable positions, in one position gas from the first bag house is directed to the second bag house, in another position gas from the first bag house is directed to both the second and third bag houses, and in a further position gas from the first bag house is directed to the third bag house;
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level. - View Dependent Claims (40)
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13. An adaptable system for removal of oxides of sulfur (SOX) and oxides of nitrogen (NOX) from gases with minimal differential pressure across the system, comprising:
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a. At least one feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
b. A first bag house configured for introduction of sorbent and a gas containing SOX and NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX;
the first bag house being configured to render the gas that has been substantially stripped of SOX free of reacted and unreacted absorbent so that the gas can be directed out of the first bag house free of reacted and unreacted absorbent;
c. A second bag house and a third bag house each connected to the first bag house by a common conduit, where the gas that has been substantially stripped of SOX in the first bag house is introduced at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the second and third bag houses each being configured to render the gas that has been substantially stripped of SOX and NOX free of reacted and unreacted sorbent so that the gas may be vented from the second and third bag houses free of reacted and unreacted sorbent;
d. A diverter valve positioned in the common conduit so as to direct the flow of gas from the first bag house to the second bag house and/or the third bag house, the diverter valve having variable positions, in one position gas from the first bag house is directed to the second bag house, in another position gas from the first bag house is directed to both the second and third bag houses, and in a further position gas from the first bag house is directed to the third bag house; and
e. At least one off-line loading circuit for pre-loading of sorbent onto fabric filter bags mounted within the second and third bag houses when the bag houses are off-line, the off-line loading circuit being comprised of;
i. An off-line loading circuit conduit configured for introduction of sorbent, the loading circuit conduit having a first end and a second end, the first end being connected to the feeder and the second end being connected to the bag houses;
ii. A recirculation fan for blowing air and sorbent into each of the second and third bag houses to pre-load sorbent onto the filter fabric bags mounted therein;
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
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14. An adaptable system for dry removal of oxides of sulfur (SOX) and/or oxides of nitrogen (NOX) from gases with minimal differential pressure across the system, comprising:
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a. A feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
b. A first bag house configured for introduction of the sorbent and a gas containing SOX and NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX; and
c. A second bag house zone configured for introduction of sorbent and the gas that has been substantially stripped of SOX from the first reaction zone where the gas is introduced at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the second reaction zone being further configured to render the gas that has been substantially stripped of SOX and NOX free of reacted and unreacted sorbent so that the gas may be vented from the second reaction zone; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
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15. An adaptable system for dry removal of oxides of sulfur (SOX) and/or oxides of nitrogen (NOX) from gases with minimal differential pressure across the system, comprising:
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a. A feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
b. A cyclone/multiclone configured for introduction of the sorbent and a gas containing SOX and NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX; and
c. A bag house configured for introduction of sorbent and the gas that has been substantially stripped of SOX from the cyclone/multiclone where the gas is introduced at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the bag house being further configured to render the gas that has been substantially stripped of SOX and NOX free of reacted and unreacted sorbent so that the gas may be vented from the bag house; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
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16. An adaptable system for dry removal of oxides of sulfur (SOX) and/or oxides of nitrogen (NOX) from gases with minimal differential pressure across the system, comprising:
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a. A feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
b. A serpentine reactor configured for introduction of the sorbent and a gas containing SOX and NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX; and
c. A bag house configured for introduction of sorbent and the gas that has been substantially stripped of SOX from the section of serpentine pipe/duct where the gas is introduced at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the bag house being further configured to render the gas that has been substantially stripped of SOX and NOX free of reacted and unreacted sorbent so that the gas may be vented from the bag house; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
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17. An adaptable system for the removal of oxides of sulfur (SOX), oxides of nitrogen (NOX), mercury compounds in particulate form, and ash from gases with minimal differential pressure across the system, comprising:
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a. A feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
b. At least one reaction zone configured for introduction of the sorbent and the gas containing SOX, NOX, mercury compounds, and ash where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decompostion temperature(s) of nitrates of manganese and contacted with the sorbent for a time sufficient to simultaneously effect SOX capture at a targeted SOX capture rate set point and NOX capture at a targeted NOX, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the mercury compounds being captured in particulate form and by adsorption onto the sorbent, the reaction zone being further configured to render the gas that has been substantially stripped of SOX and NOX free of reacted and unreacted sorbent, mercury compounds, and ash so that the gas may be vented from the reaction zone; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
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18. An adaptable system for the removal of oxides of sulfur (SOX), oxides of nitrogen (NOX), mercury compounds in particulate form, and ash from gases with minimal differential pressure across the system, comprising:
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a. A feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
b. At least one bag house configured for introduction of the sorbent and the gas containing SOX, NOX, mercury compounds, and ash where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decompostion temperature(s) of nitrates of manganese and contacted with the sorbent for a time sufficient to simultaneously effect SOX capture at a targeted SOX capture rate set point and NOX capture at a targeted NOX, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the mercury compounds being captured in particulate form and by adsorption onto the sorbent, the bag house being further configured to render the gas that has been substantially stripped of SOX and NOX free of reacted and unreacted sorbent, mercury compounds, and ash so that the gas may be vented from the bag house; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
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19. An adaptable system for the removal of oxides of sulfur (SOX), oxides of nitrogen (NOX), mercury compounds in particulate form, and ash from gases with minimal differential pressure across the system, comprising:
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a. A feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1100 m2/g;
b. A first reaction zone configured for introduction of the sorbent and a gas containing SOX and NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX and the mercury compounds being captured in particulate form and by adsorption onto the sorbent to substantially strip the gas of mercury compounds, the first reaction zone being further configured to render the gas that has been substantially stripped of SOX and mercury compounds free of reacted and unreacted sorbent, mercury compounds, and ash so that the gas may be vented from the first reaction zone; and
c. A second reaction zone configured for introduction of sorbent and the gas vented from the first reaction zone where the gas is introduced at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the second reaction zone being further configured to render the gas that has been substantially stripped of NOX free of reacted and unreacted sorbent so that the gas may be vented from the second reaction zone; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
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20. An adaptable system for the removal of oxides of sulfur (SOX), oxides of nitrogen (NOX), mercury compounds in particulate form, and ash from gases with minimal differential pressure across the system, comprising:
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a. A feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
b. A first bag house configured for introduction of the sorbent and a gas containing SOX and NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX and the mercury compounds being captured in particulate form and by adsorption onto the sorbent to substantially strip the gas of mercury compounds, the first bag house being further configured to render the gas that has been substantially stripped of SOX and mercury compounds free of reacted and unreacted sorbent, mercury compounds, and ash so that the gas may be vented from the first bag house; and
c. A second bag house configured for introduction of sorbent and the gas vented from the first bag house where the gas is introduced at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the second bag house being further configured to render the gas that has been substantially stripped of NOX free of reacted and unreacted sorbent so that the gas may be vented from the second bag house; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
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21. An adaptable system for the removal of oxides of sulfur (SOX), oxides of nitrogen (NOX), mercury compounds in particulate form, and ash from gases with minimal differential pressure across the system, comprising:
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a. A feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
b. A cyclone/multiclone configured for introduction of the sorbent and a gas containing SOX, NOX, mercury compounds and ash, where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX and the mercury compounds being captured in particulate form and by adsorption onto the sorbent to substantially strip the gas of mercury compounds, the cyclone/multiclone being further configured to render the gas that has been substantially stripped of SOX and mercury compounds free of reacted and unreacted sorbent, mercury compounds, and ash so that the gas may be vented from the cyclone/multiclone; and
c. A bag house configured for introduction of sorbent and the gas vented from the cyclone/multiclone where the gas is introduced at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the bag house being further configured to render the gas that has been substantially stripped of NOX free of reacted and unreacted sorbent so that the gas may be vented from the bag house; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
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22. An adaptable system for the removal of oxides of sulfur (SOX), oxides of nitrogen (NOX), mercury compounds in particulate form, elemental mercury vapor, and ash from gases with minimal differential pressure across the system, comprising:
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a. a feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
b. at least one reaction zone configured for introduction of the sorbent and the gas containing SOX, NOX, mercury compounds, mercury vapor, and ash where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decompostion temperature(s) of nitrates of manganese and contacted with the sorbent for a time sufficient to simultaneously effect SOX capture at a targeted SOX capture rate set point and NOX capture at a targeted NOX, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the mercury compounds being captured in particulate form and by adsorption onto the sorbent, the reaction zone being further configured to render the gas that has been substantially stripped of SOX and NOX free of reacted and unreacted sorbent, mercury compounds, mercury vapor, and ash so that the gas may be vented from the reaction zone; and
c. A mercury-alumina reactor configured for introduction of the gas vented from the reaction zone and alumina, where the gas is introduced at temperature(s) typically below the temperature at which desorption of mercury adsorbed on the surface(s) of alumina occurs and is contacted with alumina for a time sufficient to effect the capture of mercury compounds in the gas, the mercury being captured by adsorption on the surface of alumina, the reactor being further configured to render the gas that has been partially substantially stripped of mercury vapor free of reacted and unreacted alumina so that the gas may be vented from the reactor, wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level. - View Dependent Claims (28, 29, 35)
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23. An adaptable system for the removal of oxides of sulfur (SOX), oxides of nitrogen (NOX), mercury compounds in particulate form, elemental mercury vapor, and ash from gases with minimal differential pressure across the system, comprising:
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a. a feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
b. at least one bag house configured for introduction of the sorbent and the gas containing SOX, NOX, mercury compounds, mercury vapor, and ash where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decompostion temperature(s) of nitrates of manganese and contacted with the sorbent for a time sufficient to simultaneously effect SOX capture at a targeted SOX capture rate set point and NOX capture at a targeted NOX, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the mercury compounds being captured in particulate form and by reacting mercury vapor with the sorbent to form mercury oxide(s) which along with mercury compounds are captured by absorption onto the sorbent, the bag house being further configured to render the gas that has been substantially stripped of SOX and NOX free of reacted and unreacted sorbent, mercury compounds, mercury vapor, and ash so that the gas may be vented from the bag house; and
c. A mercury-alumina reactor configured for introduction of the gas vented from the bag house and alumina, where the gas is introduced at temperature(s) typically below the temperature at which desorption of mercury adsorbed on the surface(s) of alumina occurs and is contacted with alumina for a time sufficient to effect the capture of mercury compounds in the gas, the mercury being captured by adsorption on the surface of alumina, the reactor being further configured to render the gas that has been partially substantially stripped of mercury vapor free of reacted and unreacted alumina so that the gas may be vented from the reactor, wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
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24. An adaptable system for the removal of oxides of sulfur (SOX), oxides of nitrogen (NOX), mercury compounds in particulate form, mercury vapor, and ash from gases with minimal differential pressure across the system, comprising:
-
a. A feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
b. A first reaction zone configured for introduction of the sorbent and a gas containing SOX and NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX and the mercury compounds being captured in particulate form and by absorption onto the sorbent to substantially strip the gas of mercury compounds, the first reaction zone being further configured to render the gas that has been substantially stripped of SOX and mercury compounds free of reacted and unreacted sorbent, mercury oxide, salts of mercury, and ash so that the gas may be vented from the first reaction zone;
c. A second reaction zone configured for introduction of sorbent and the gas vented from the first reaction zone where the gas is introduced at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the second reaction zone being further configured to render the gas that has been substantially stripped of NOX free of reacted and unreacted sorbent so that the gas may be vented from the second reaction zone; and
d. An alumina reactor configured for introduction of the gas vented from the second reaction zone and alumina, where the gas is introduced at temperature(s) typically below the temperature at which desorption of mercury adsorbed on the surface(s) of alumina occurs and is contacted with alumina for a time sufficient to effect the capture of mercury compounds in the gas, the mercury being capture by adsorption on the surface of alumina, the reactor being further configured to render the gas that has been substantially stripped of mercury compounds free of reacted and unreacted alumina so that the gas may be vented from the reactor, wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
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25. An adaptable system for the removal of oxides of sulfur (SOX), oxides of nitrogen (NOX), mercury compounds in particulate form, mercury vapor, and ash from gases with minimal differential pressure across the system, comprising:
-
a. A feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
b. A first bag house configured for introduction of the sorbent and a gas containing SOX and NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX and the mercury compounds being captured in particulate form and by adsorption onto the sorbent to substantially strip the gas of mercury compounds, the first bag house being further configured to render the gas that has been substantially stripped of SOX and mercury compounds free of reacted and unreacted sorbent, and ash so that the gas may be vented from the first bag house;
c. A second bag house configured for introduction of sorbent and the gas vented from the first bag house where the gas is introduced at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the second bag house being further configured to render the gas that has been substantially stripped of NOX free of reacted and unreacted sorbent so that the gas may be vented from the second bag house; and
d. A mercury-alumina reactor configured for introduction of the gas vented from the second bag house and alumina, where the gas is introduced at temperature(s) typically below the temperature at which desorption of mercury adsorbed on the surface(s) of alumina occurs and is contacted with alumina for a time sufficient to effect the capture of mercury compounds in the gas, the mercury being captured by adsorption on the surface of alumina, the reactor being further configured to render the gas that has been substantially stripped of mercury compounds free of reacted and unreacted alumina so that the gas may be vented from the reactor, wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
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26. An adaptable system for the removal of oxides of sulfur (SOX), oxides of nitrogen (NOX), mercury compounds in particulate form, mercury vapor, and ash from gas with minimal differential pressure across the system, comprising:
-
a. A feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
b. A cyclone/multiclone configured for introduction of the sorbent and a gas containing SOX, NOX, mercury compounds, mercury vapor and ash, where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX and the mercury compounds being captured in particulate form and by adsorption onto the sorbent to substantially strip the gas of mercury compounds, the cyclone/multiclone being further configured to render the gas that has been substantially stripped of SOX and mercury compounds free of reacted and unreacted sorbent, and ash so that the gas may be vented from the cyclone/multiclone;
c. A bag house configured for introduction of sorbent and the gas vented from the cyclone/multiclone where the gas is introduced at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the bag house being further configured to render the gas that has been substantially stripped of NOX free of reacted and unreacted sorbent so that the gas may be vented from the bag house; and
d. An alumina reactor configured for introduction of the gas vented from the second bag house and alumina, where the gas is introduced at temperature(s) typically below the temperature at which desorption of mercury adsorbed on the surface(s) of alumina occurs and is contacted with alumina for a time sufficient to effect the capture of mercury compounds in the gas, the mercury being captured by adsorption on the surface of alumina, the reactor being further configured to render the gas that has been partially substantially stripped of mercury compounds free of reacted and unreacted alumina so that the gas may be vented from the reactor, wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
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41. An inverted bag house permitting downward vertical flow of gases and sorbent, comprised of;
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a. A bag house housing which permits the introduction of gases and sorbent entrained in the gases, the housing having a top and a bottom and being configured for gases to flow vertically downward from the top to the bottom of the bag house;
b. At least one inlet at the top of the housing, the inlet being located near the top of the bag house housing and configured for the introduction of gases and sorbent entrained in the gases into the bag house;
c. A plurality of fabric filter bags configured to allow gas to flow from the outside of the bags to the inside of the bags under an applied differential pressure and to prevent the passage of sorbent from the outside to the inside of the bags, thereby separating sorbent from the gas;
d. A support structure for receiving and supporting the plurality of fabric filter bags, the support structure being configured to receive and support the fabric filter bags and to provide openings through which particles may be freely passed downward into the hopper by gravity;
e. A hopper to receive and collect the particles that pass downward through the openings of the frame and from which the particles may be removed, the hopper being configured to permit the removal of the particles;
f. An outlet located near the bottom of the housing below the bags and above the hopper;
g. A conduit located below the fabric filter bags and positioned to receive gas passing through the fabric filter bags the conduit being in flow-through connection with the outlet.
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42. A bag house reactor for removal of pollutants from a gas stream by contacting the gas with a sorbent and separation of sorbent that are entrained in the gas, comprising:
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a. a bag house having a housing with interior and exterior surfaces, and upper, central, and lower sections;
b. a variable venturi for adjusting the velocity of gas flowing though the venturi, thereby controlling depth of the pseudo-fluidized bed, the variable venturi being generally located in the central and/or lower sections of the bag house and configured for the adjustment of the position of the variable venturi by varying the distance between the variable venturi and the interior surface of the bag house and having a variable venturi position detector for determining the position of the variable venturi and a variable venturi positioner for adjusting the position of the variable venturi to increase or decrease the velocity of gas flow from the lower section past the variable venturi to the central and upper sections of the bag house;
c. a gas distribution conduit configured for introduction of gas, the first gas distribution port being positioned below the variable venturi, d. a sorbent port connected to a sorbent feeder conduit configured for introduction of sorbent into the bag house, the sorbent distribution port being positioned above the variable venturi, e. a plurality of fabric filter bags secured therein, the fabric filter bags being mounted in the upper section of the bag house and extending downward into the central section, f. a sorbent hopper located in the bottom section of the bag house where loaded sorbent is collected, g. a reacted sorbent outlet being connected to the sorbent hopper and having an outlet valve which in the open position allows for removal of sorbent from the hopper; and
h. a vent located in the top section of the bag house for venting of gas from the bag house.
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43. An adaptable system for dry removal of oxides of sulfur (SOX) and oxides of nitrogen (NOX) from gases with minimal differential pressure across the system, comprising:
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a. a bag house reactor for removal of pollutants from gases by contacting the gas with a sorbent and separation of the sorbent particles that are entrained in the gas, the bag house reactor being comprised of;
i. a bag house having a housing with interior and exterior surfaces, and upper, central, and lower sections;
ii. a variable venturi for adjusting the velocity of gas flowing though the venturi, thereby controlling depth of the pseudo-fluidized bed, the variable venturi being generally located in the central and/or lower sections of the bag house and configured for the adjustment of the position of the variable venturi by varying the distance between the variable venturi and the interior surface of the bag house and having a variable venturi position detector for determining the position of the variable venturi and a variable venturi positioner for adjusting the position of the variable venturi to increase or decrease the velocity of gas flow from the lower section past the variable venturi to the central and upper sections of the bag house;
iii. a gas distribution port connected to a conduit configured for introduction of gas into the bag house, the gas distribution port being positioned below the variable venturi, iv. a sorbent distribution port connected to a sorbent feeder conduit configured for introduction of sorbent into the bag house, the sorbent distribution port being positioned above the variable venturi, v. a plurality of fabric filter bags secured therein, the fabric filter bags being mounted in the upper section of the bag house and extending downward into the central section, vi. a sorbent hopper located in the bottom section of the bag house where loaded sorbent is collected, vii. aloaded sorbent outletbeing connected to the sorbent hopper and having an outlet valve which in the open position allows for removal of sorbent from the hopper; and
viii. a vent located in the top section of the bag house for venting of gas from the bag house; and
b. a sorbent feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size of less than about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g, the sorbent feeder being connected to the sorbent feeder conduit and being further configured to introduce sorbent into the first sorbent feeder conduit; and
wherein the system is regulated so that differential pressure across the system is no greater than a predetermined level.
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49. A process for dry removal of oxides of sulfur (SOX) from a gas stream, comprising the step of:
-
A. providing an adaptable system for dry removal of oxides of sulfur (SOX) from gases with minimal differential pressure across the system, the system being comprised of;
i. a feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size ranging from about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g; and
ii. a reaction zone configured for introduction of the sorbent and a gas containing SOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX, the reaction zone being further configured to render the gas that has been substantially stripped of SOX free of reacted and unreacted sorbent so that the gas may be vented from the reaction zone; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level;
B. introducing sorbent and a gas containing SOX into the reaction zone, the gas being at temperatures typically ranging from ambient temperature to a temperature below the thermal decomposition temperature(s) of sulfates of manganese;
C. contacting the gas with sorbent for a time sufficient to effect SOX capture at a targeted SOX capture set point through the formation of sulfates of manganese to substantially strip the gas of SOX thereby reacting with the sorbent;
D. rendering the gas free of reacted and unreacted sorbent;
E. venting the gas from the reaction zone. - View Dependent Claims (66, 67, 68, 69, 70, 71, 72, 73)
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50. A process for dry removal of oxides of nitrogen (NOX) from gases with minimal differential pressure across the system, comprising the steps of:
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A. providing an adaptable system for dry removal of oxides of nitrogen (NOX) from gases with minimal differential pressure across the system being comprised of;
i. a feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size ranging from about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g; and
ii. a reaction zone configured for introduction of the sorbent and a gas containing NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of nitrates of manganese and contacted with the sorbent for a time sufficient to effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, the reaction zone being further configured to render the gas that has been substantially stripped of NOX free of reacted and unreacted sorbent so that the gas may be vented from the reaction zone;
and wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level;
B. introducing sorbent and a gas containing NOX into the reaction zone, the gas being at temperatures typically ranging from ambient temperature to a temperature below the thermal decomposition temperature(s) of nitrates of manganese;
C. contacting the gas with sorbent for a time sufficient to effect NOX capture at a targeted NOX capture set point through the formation of nitrates of manganese to substantially strip the gas of NOX;
D. rendering the gas free of reacted and unreacted sorbent;
E. venting the gas from the reaction zone. - View Dependent Claims (83, 84, 85, 86, 87, 88)
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51. A process for dry removal of oxides of sulfur (SOX) and oxides of nitrogen (NOX) from gases with minimal differential pressure across the system, comprising the steps of:
-
A. providing an adaptable system for dry removal of oxides of sulfur (SOX) and oxides of nitrogen (NOX) from gases with minimal differential pressure across the system, the system being comprised of;
i. a feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size ranging from about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
ii. a reaction zone configured for introduction of the sorbent and a gas containing SOX and NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decompostion temperature(s) of nitrates of manganese and contacted with the sorbent for a time to sufficient to simultaneously effect SOX capture at a targeted SOX capture rate set point and NOX capture at a targeted NOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX and the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the reaction zone being further configured to render the gas that has been substantially stripped of SOX and NOX free of reacted and unreacted sorbent so that the gas may be vented from the reaction zone; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level;
B. introducing sorbent and a gas containing SOX and NOX into the first reaction zone, the gas being at temperatures typically ranging from ambient temperature to a temperature below the thermal decomposition temperature(s) of nitrates of manganese;
C. contacting the gas with sorbent for a time sufficient to simultaneously effect SOX capture at a targeted SOX capture set point through the formation of sulfates of manganese to substantially strip the gas of SOX and to effect NOX capture at a targeted NOX capture set point through the formation of nitrates of manganese to substantially strip the gas of NOX;
D. rendering the gas free of reacted and unreacted sorbent;
E. venting the gas from the reaction zone.
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52. A process for dry removal of SOX and/or NOX from a gas stream, comprising the steps of:
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A. providing an adaptable system for dry removal (SOX) and/or (NOX) from gases with minimal differential pressure across the system, the system being comprised of;
i. a feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size ranging from about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
ii. a first reaction zone configured for introduction of the sorbent and a gas containing SOX and NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX; and
iii. a second reaction zone configured for introduction of sorbent and the gas that has been substantially stripped of SOX from the first reaction zone where the gas is introduced at temperature(s) typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the second reaction zone being further configured to render the gas that has been substantially stripped of SOX and NOX free of reacted and unreacted sorbent so that the gas may be vented from the second reaction zone; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level;
B. introducing sorbent and a gas containing SOX and/or NOX into the first reaction zone, the gas being at temperature(s) typically ranging from ambient to a temperature below the thermal decomposition temperature(s) of sulfates of manganese;
C. contacting the gas with sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point through the formation of sulfates of manganese to substantially strip the gas of SOX;
D. rendering the gas free of reacted and unreacted sorbent;
E. venting the gas from the first reaction zone;
F. introducing sorbent and the gas from the first reaction zone into the second reaction zone, the gas being at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese;
G. contacting the gas with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point through the formation of nitrates of manganese to substantially strip the gas of NOX thereby loading the sorbent;
H. rendering the gas free of reacted and unreacted sorbent nitrates of manganese; and
I. venting the gas from the second reaction zone.
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53. A process for dry removal of SOX and NOX from a gas stream, comprising the steps of:
-
A. providing an adaptable system for dry removal of oxides of sulfur (SOX) and/or oxides of nitrogen (NOX) from gases with minimal differential pressure across the system, the system being comprised of;
i. at least one feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size ranging from about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g; and
ii. a modular reaction unit comprised of at least 3 interconnected bag houses, the bag houses being connected so that a gas containing SOX and/or NOX can be routed through any one of the bag houses, any two of the bag houses in series, or all of the at least three bag houses in series or in parallel, or any combination of series and parallel, each bag house being separately connected to the feeder so that sorbent can be introduced into each bag house where SOX and/or NOX capture can occur when the gas is contacted with sorbent for a time sufficient to allow formation of sulfates of manganese, nitrates of manganese, or both; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level;
B. introducing sorbent in a gas containing SOX and/or NOX into a first bag house of at least three interconnected bag houses, the gas being at temperatures typically ranging from ambient to a temperature below the thermal decomposition temperature(s) of sulfates of manganese;
C. contacting the gas with sorbent for time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point through the formation of sulfates of manganese to substantially strip the gas of SOX;
D. rendering the gas free of sorbent reacted with sulfates of manganese;
E. venting the gas from the first bag house;
F. introducing sorbent and the gas from the first bag house into a second bag house, the gas being at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese;
G. contacting the gas with sorbent for time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point through the formation of nitrates of manganese to substantially strip the gas of NOX;
H. rendering the gas free of sorbent reacted with nitrates of manganese; and
I. venting the gas from the second bag house.
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54. A process for dry removal of SOX and NOX from a gas stream, comprising the steps of:
-
A. providing an adaptable system for dry removal of oxides of sulfur (SOX) and/or oxides of nitrogen (NOX) from gases with minimal differential pressure across the system, the system being comprised of;
i. at least one feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size ranging from about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g; and
ii. a modular reaction unit comprised of at least three (3) interconnected bag houses, the bag houses being connected so that a gas containing SOX and/or NOX can be routed through any one of the bag houses, any two of the bag houses in series, or all of the at least three bag houses in series or in parallel, or any combination of series and parallel, each bag house being separately connected to the feeder so that sorbent can be introduced into each bag house where SOX and/or NOX capture can occur when the gas is contacted with sorbent for a time sufficient to allow formation of sulfates of manganese, nitrates of manganese, or both, with SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX and NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, the bag houses each being configured to render the gas that has been substantially stripped of SOX and/or NOX free of reacted and unreacted sorbent so that the gas that has been substantially stripped of SOX and/or NOX may be vented from the bag houses or passed from one bag house to another bag house in series; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level;
B. introducing sorbent in a gas containing SOX and/or NOX into a first bag house of at least three interconnected bag houses, the gas being at temperatures typically ranging from ambient to a temperature below the thermal decomposition temperature(s) of sulfates of manganese;
C. contacting the gas with sorbent for time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point through the formation of sulfates of manganese to substantially strip the gas of SOX;
D. rendering the gas free of sorbent reacted with sulfates of manganese;
E. venting the gas from the first bag house;
F. introducing sorbent and the gas from the first bag house into a second bag house, the gas being at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese;
G. contacting the gas with sorbent for time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point through the formation of nitrates of manganese to substantially strip the gas of NOX;
H. rendering the gas free of sorbent reacted with nitrates of manganese; and
I. venting the gas from the second bag house.
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55. A process for dry removal of SOX and NOX from a gas stream, comprising the steps of:
-
A. providing an adaptable system for removal of oxides of sulfur (SOX) and oxides of nitrogen (NOX) from gases, the system being comprised of;
i. at least one feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size ranging from about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
ii. a first bag house configured for introduction of sorbent and a gas containing SOX and NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX;
the first bag house being configured to render the gas that has been substantially stripped of SOX free of reacted and unreacted sorbent so that the gas can be directed out of the first bag house free of reacted and unreacted sorbent;
iii. a second bag house and a third bag house each connected to the first bag house by a common conduit, where the gas that has been substantially stripped of SOX in the first bag house is introduced at temperature(s) typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the second and third bag houses each being configured to render the gas that has been substantially stripped of SOX and NOX free of reacted and unreacted sorbent so that the gas may be vented from the second and third bag houses free of reacted and unreacted sorbent; and
iv. a diverter valve positioned in the common conduit so as to direct the flow of gas from the first bag house to the second bag house and/or the third bag house, the diverter valve having variable positions, in one position gas from the first bag house is directed to the second bag house, in another position gas from the first bag house is directed to both the second and third bag houses, and in a further position gas from the first bag house is directed to the third bag house;
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level;
B. introducing sorbent and a gas containing SOX and/or NOX into the first bag house, the gas being at temperatures typically ranging from ambient to a temperature below the thermal decomposition temperature(s) of sulfates of manganese;
C. contacting the gas with sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point through the formation of sulfates of manganese to substantially strip the gas of SOX;
D. rendering the gas free of sorbent reacted with sulfates of manganese;
E. venting the gas from the first bag house;
F. directing the gas to the second bag house and/or the third bag house;
G. introducing sorbent and the gas from the first bag house into the second bag house and/or the third bag house, the gas being at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese;
H. contacting the gas with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point through the formation of nitrates of manganese to substantially strip the gas of NOX;
I. rendering the gas free of sorbent reacted with nitrates of manganese; and
J. venting the gas from the second bag house and/or the third bag house.
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56. A process for dry removal of SOX and NOX from a gas stream, comprising the steps of:
-
A. providing an adaptable system for removal of oxides of sulfur (SOX) and oxides of nitrogen (NOX) from gases, the system being comprised of;
i. at least one feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size ranging from about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
ii. a first bag house configured for introduction of sorbent and a gas containing SOX and NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX;
the first bag house being configured to render the gas that has been substantially stripped of SOX free of reacted and unreacted sorbent so that the gas can be directed out of the first bag house free of reacted and unreacted sorbent;
iii. a second bag house and a third bag house each connected to the first bag house by a common conduit, where the gas that has been substantially stripped of SOX in the first bag house is introduced at temperature(s) typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the second and third bag houses each being configured to render the gas that has been substantially stripped of SOX and NOX free of reacted and unreacted sorbent so that the gas may be vented from the second and third bag houses free of reacted and unreacted sorbent;
iv. a diverter valve positioned in the common conduit so as to direct the flow of gas from the first bag house to the second bag house and/or the third bag house, the diverter valve having variable positions, in one position gas from the first bag house is directed to the second bag house, in another position gas from the first bag house is directed to both the second and third bag houses, and in a further position gas from the first bag house is directed to the third bag house; and
V. at least one off-line loading circuit for pre-loading of sorbent on to fabric filter bags mounted within the second and third bag houses when the bag houses are off-line, the off-line loading circuit being comprised of;
a. an off-line loading circuit conduit configured for introduction of sorbent, the loading circuit conduit having a first end and a second end, the first end being connected to the feeder and the second end being connected to the bag houses;
b. a recirculation fan for blowing air and sorbent into each of the second and third bag houses to pre-load sorbent onto the filter fabric bags mounted therein;
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level;
B. introducing sorbent and a gas containing SOX and/or NOX into the first bag house, the gas being at temperatures typically ranging from ambient to a temperature below the thermal decomposition temperature(s) of sulfates of manganese;
C. contacting the gas with sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point through the formation of sulfates of manganese to substantially strip the gas of SOX;
D. rendering the gas free of sorbent reacted with sulfates of manganese;
E. venting the gas from the first bag house;
F. directing the gas to the second bag house and/or the third bag house;
G. introducing sorbent and the gas from the first bag house into the second bag house and/or the third bag house, the gas being at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese;
H. contacting the gas with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point through the formation of nitrates of manganese to substantially strip the gas of NOX;
I. rendering the gas free of sorbent reacted with nitrates of manganese; and
J. venting the gas from the second bag house and/or the third bag house.
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57. A process for dry removal of SOX and NOX from a gas stream, comprising the steps of:
-
A. providing an adaptable system for dry removal of oxides of sulfur (SOX) and/or oxides of nitrogen (NOX) from gases with minimal differential pressure across the system, comprising;
i. a feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size ranging from about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
ii. a first bag house configured for introduction of the sorbent and a gas containing SOX and NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX; and
iii. a second bag house zone configured for introduction of sorbent and the gas that has been substantially stripped of SOX from the first reaction zone where the gas is introduced at temperature(s) typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the second reaction zone being further configured to render the gas that has been substantially stripped of SOX and NOX free of reacted and unreacted sorbent so that the gas may be vented from the second reaction zone; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level;
B. introducing sorbent and a gas containing SOX and/or NOX into the first bag house, the gas being at temperature(s) typically ranging from ambient to a temperature below the thermal decomposition temperature(s) of sulfates of manganese;
C. contacting the gas with sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point through the formation of sulfates of manganese to substantially strip the gas of SOX thereby loading the sorbent;
D. rendering the gas free of reacted and unreacted sorbent;
E. venting the gas from the first bag house zone;
F. introducing sorbent and the gas from the first bag house into the second bag house, the gas being at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese;
G. contacting the gas with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point through the formation of nitrate of manganese to substantially strip the gas of NOX;
H. rendering the gas free of reacted and unreacted sorbent; and
I. venting the gas from the second bag house zone.
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-
58. A process for dry removal of SOX and NOX from a gas stream, comprising the steps of:
-
A. providing an adaptable system for dry removal of oxides of sulfur (SOX) and/or oxides of nitrogen (NOX) from gases with minimal differential pressure across the system, comprising;
i. a feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size ranging from about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
ii. a cyclone/multiclone configured for introduction of the sorbent and a gas containing SOX and NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX; and
iii. a bag house configured for introduction of sorbent and the gas that has been substantially stripped of SOX from the cyclone/multiclone where the gas is introduced at temperature(s) typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the bag house being further configured to render the gas that has been substantially stripped of SOX and NOX free of reacted and unreacted sorbent so that the gas may be vented from the bag house; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level;
B. introducing sorbent and a gas containing SOX and/or NOX into the cyclone/multiclone, the gas being at temperatures typically ranging from ambient to a temperature below the thermal decomposition temperature(s) of sulfates of manganese;
C. contacting the gas with sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point through the formation of sulfates of manganese to substantially strip the gas of SOX;
D. rendering the gas free of reacted and unreacted sorbent;
E. venting the gas from the cyclone/multiclone;
F. introducing sorbent and the gas from the cyclone/multiclone into the bag house, the gas being introduced at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese;
G. contacting the gas with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point through the formation of nitrate of manganese to substantially strip the gas of NOX;
H. rendering the gas free of reacted and unreacted sorbent reacted with nitrates of manganese;
I. venting the gas from the bag house zone.
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59. A process for dry removal of SOX and NOX from a gas stream, comprising the steps of:
-
A. providing an adaptable system for dry removal of oxides of sulfur (SOX) and/or oxides of nitrogen (NOX) from gases with minimal differential pressure across the system, comprising;
i. a feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size ranging from about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
ii. a section of serpentine pipe configured for introduction of the sorbent and a gas containing SOX and NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX; and
iii. a bag house configured for introduction of sorbent and the gas that has been substantially stripped of SOX from the section of serpentine pipe, where the gas is introduced at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the bag house being further configured to render the gas that has been substantially stripped of SOX and NOX free of sorbent so that the gas may be vented from the bag house; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level;
B. introducing sorbent and a gas containing SOX and/or NOX into the section of serpentine pipe, the gas being at temperature(s) typically ranging from ambient to a temperature below the thermal decomposition temperature(s) of sulfates of manganese;
C. contacting the gas with sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point through the formation of sulfates of manganese to substantially strip the gas of SOX;
D. introducing the sorbent and the gas from the section of serpentine pipe into the bag house, the gas being introduced at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese;
E. contacting the gas with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point through the formation of nitrate of manganese to substantially strip the gas of NOX;
F. rendering the gas free of reacted and unreacted sorbent;
G. venting the gas from the bag house.
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60. A process for dry removal of SOX, NOX, mercury compounds, and ash from a gas stream, comprising the steps of:
-
A. providing an adaptable system for the removal of oxides of sulfur (SOX), oxides of nitrogen (NOX), mercury in elemental, particulate and compound forms, and ash from gases with minimal differential pressure across the system, comprising;
i. a feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size ranging from about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
ii. at least one bag house configured for introduction of the sorbent and the gas containing SOX, NOX, mercury, mercury compounds and ash where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decompostion temperature(s) of nitrates of manganese and contacted with the sorbent for a time to sufficient to simultaneously effect elemental mercury oxidation, SOX capture at a targeted SOX capture rate set point, and NOX capture at a targeted NOX, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the mercury compounds being captured in particulate form and by reacting with the sorbent to form mercury oxide(s) and salts of mercury, the bag house being further configured to render the gas that has been substantially stripped of SOX and NOX free of reacted and unreacted sorbent, mercury oxide(s), salts of mercury, and ash so that the gas may be vented from the bag house; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level;
B. introducing sorbent and a gas containing SOX, NOX, mercury compounds, and ash, the gas being at temperatures typically ranging from ambient temperature to below the thermal decomposition of NOX;
C. contacting the gas with sorbent for a time sufficient to simultaneously effect the capture of SOX, NOX and mercury compounds, the SOX capture at a targeted SOX capture rate set point, NOX capture at a targeted NOX capture rate set point and the capture of mercury compounds, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the mercury compounds being captured in particulate form and by reacting with the sorbent to form mercury oxide(s) and salts of mercury to substantially strip mercury compounds from the gas;
D. rendering the gas free of reacted and unreacted sorbent, mercury oxide(s), salts of mercury, and ash;
E. venting the gas from the bag house. - View Dependent Claims (74, 75)
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61. A process for dry removal of SOX, NOX, mercury compounds, and ash from a gas stream, comprising the steps of:
-
A. providing an adaptable system for the removal of oxides of sulfur (SOX), oxides of nitrogen (NOX), mercury in elemental, particulate and compound forms, and ash from gases with minimal differential pressure across the system, the system being comprised of;
i. a feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size ranging from about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
ii. a first bag house configured for introduction of the sorbent and a gas containing SOX and NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect elemental mercury oxidation, and SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX and the mercury compounds being captured in particulate form and by reacting with the sorbent to form mercury oxide(s) and salts of mercury to substantially strip the gas of mercury oxide(s) and salts of mercury, the first bag house being further configured to render the gas that has been substantially stripped of SOX and mercury compounds free of reacted and unreacted sorbent, mercury oxide(s), salts of mercury, and ash so that the gas may be vented from the first bag house; and
iii. a second bag house configured for introduction of sorbent and the gas vented from the first bag house where the gas is introduced at temperature(s) typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the second bag house being further configured to render the gas that has been substantially stripped of NOX free of reacted and unreacted sorbent so that the gas may be vented from the second bag house; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level;
B. introducing sorbent and the gas containing SOX and/or NOX into the first bag house, the gas being at temperatures typically ranging from ambient to a temperature below the thermal decomposition temperature(s) of sulfates of manganese;
C. contacting the gas with sorbent for a time sufficient to effect SOX capture at a targeted SOX capture rate set point through the formation of sulfates of manganese to substantially strip the gas of SOX and to effect capture of mercury compounds, the mercury compounds being captured in particulate form and by reacting with the sorbent to form mercury oxide(s) and salts of mercury to substantially strip the gas of mercury compounds from the gas;
D. rendering the gas free of reacted and unreacted sorbent, mercury oxide(s), ash, and sulfates of manganese;
E. venting the gas from the first bag house;
F. introducing sorbent and the gas from the first bag house into the second bag house, the gas being introduced at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese;
G. contacting the gas with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point through the formation of nitrate of manganese to substantially strip the gas of NOX;
H. rendering the gas free of reacted and unreacted sorbent;
I. venting the gas from the second bag house.
-
-
62. A process for dry removal of SOX, NOX, mercury compounds, and ash from a gas, comprising the steps of:
-
A. providing an adaptable system for the removal of oxides of sulfur (SOX), oxides of nitrogen (NOX), mercury in elemental, particulate and compound forms, and ash from gases with minimal differential pressure across the system;
i. a feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size ranging from about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
ii. a cyclone/multiclone configured for introduction of the sorbent and a gas containing SOX, NOX, mercury compounds, and ash, where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX and the mercury compounds being captured in particulate form and by reacting with the sorbent to form mercury oxide(s) and salts of mercury to substantially strip the gas of mercury oxide(s) and salts of mercury, the cyclone/multiclone being further configured to render the gas that has been substantially stripped of SOX and mercury compounds free of reacted and unreacted sorbent, mercury oxide(s), salts of mercury, and ash so that the gas may be vented from the cyclone/multiclone; and
iii. a bag house configured for introduction of sorbent and the gas vented from the cyclone/multiclone where the gas is introduced at temperature(s) typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the bag house being further configured to render the gas that has been substantially stripped of NOX free of reacted and unreacted sorbent so that the gas may be vented from the bag house; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level;
B. introducing sorbent and the gas into the cyclone/multiclone, the gas being at temperatures typically ranging from ambient to a temperature below the thermal decomposition temperature(s) of sulfates of manganese;
C. contacting the gas with sorbent for a time sufficient to effect SOX capture at a targeted SOX capture rate set point through the formation of sulfates of manganese to substantially strip the gas of SOX and to effect capture of mercury compounds, the mercury compounds being captured in particulate form and by reacting with the sorbent to form mercury oxide(s) and salts of mercury to substantially strip the gas of mercury compounds;
D. rendering the gas that has been substantially stripped of SOX and mercury compounds free of reacted and unreacted sorbent, mercury oxide(s), ash, and salts of mercury;
E. venting the gas from the cyclone/multiclone;
F. introducing sorbent and the gas from the cyclone/multiclone into the bag house, the gas being introduced at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese;
G. contacting the gas with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point through the formation of nitrate of manganese to substantially strip the gas of NOX;
H. rendering the gas free of reacted and unreacted sorbent;
I. venting the gas from the bag house zone wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
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63. A process for dry removal of SOX, NOX, mercury compounds, and ash from a gas stream, comprising the steps of:
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A. providing an adaptable system for the removal of oxides of sulfur (SOX), oxides of nitrogen (NOX), mercury in particulate, compound and elemental forms, and ash from a gas with minimal differential pressure across the system, the system being comprised of;
i. a feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size ranging from about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
ii. at least one bag house configured for introduction of the sorbent and the gas containing SOX, NOX, mercury in elemental, particulate, and compound forms, and ash where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of nitrates of manganese and contacted with the sorbent for a time to sufficient to simultaneously effect SOX capture at a targeted SOX capture rate set point and NOX capture at a targeted NOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the mercury being captured in particulate form and by reacting with the sorbent to form mercury oxide(s) and salts of mercury, the bag house being further configured to render the gas that has been substantially stripped of SOX and NOX free of reacted and unreacted sorbent, mercury oxide(s), salts of mercury and ash so that the gas may be vented from the bag house; and
iii. a mercury-alumina reactor configured for introduction of the gas vented from the bag house and alumina, where the gas is introduced at temperature(s) typically below the temperature at which desorption of mercury adsorbed on the surface of alumina occurs and is contacted with alumina for a time sufficient to effect the capture of mercury compounds in the gas, the mercury compounds being captured by adsorption on the surface of alumina, the reactor being further configured to render the gas that has been substantially stripped of mercury free of reacted and unreacted alumina so that the gas may be vented from the reactor, wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level. B. introducing sorbent and the gas containing SOX, NOX, mercury compounds, and ash into the bag house, the gas being introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperatures(s) of nitrates of manganese;
C. contacting the gas with sorbent for a time sufficient to simultaneously effect the capture of SOX, NOX and mercury compounds, the SOX capture at a targeted SOX capture rate set point, NOX capture at a targeted NOX capture rate set point and the capture of mercury compounds, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the mercury compounds being captured in particulate form and by reacting with the sorbent to form mercury oxide(s) and salts of mercury to substantially strip mercury from the gas;
D. rendering the gas free of reacted and unreacted sorbent, mercury oxide(s), salts of mercury, and ash;
E. venting the gas from the bag house;
F. introducing the gas vented from the bag house and alumina into the mercury-alumina reactor, the gas being introduced at temperature(s) typically below the temperature at which desorption of mercury adsorbed on the surface of alumina occurs;
G. contacting the gas with the alumina for a time sufficient to effect the capture of mercury in the gas, the mercury being captured by adsorption to the surface of alumina to substantially strip the gas of mercury, thereby loading the alumina;
H. rendering the gas free of reacted and unreacted alumina;
I. venting the gas from the reactor. - View Dependent Claims (76)
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64. A process for dry removal of SOX, NOX, mercury, and ash from a gas stream, comprising the steps of:
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A. providing an adaptable system for the removal of oxides of sulfur (SOX), oxides of nitrogen (NOX), mercury compounds in elemental, particulate, and compound form, mercury vapor, and ash from gases with minimal differential pressure across the system, the system being comprised of;
i. a feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size ranging from about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
ii. a first bag house configured for introduction of the sorbent and a gas containing SOX and NOX where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX and the mercury being captured in particulate form and by reacting with the sorbent to form mercury oxide(s) and salts of mercury to substantially strip the gas of mercury oxide(s) and salts of mercury, the first bag house being further configured to render the gas that has been substantially stripped of SOX and mercury compounds free of reacted and unreacted sorbent, mercury oxide(s), salts of mercury, and ash so that the gas may be vented from the first bag house;
iii. a second bag house configured for introduction of sorbent and the gas vented from the first bag house where the gas is introduced at temperature(s) typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the second bag house being further configured to render the gas that has been substantially stripped of NOX free of reacted and unreacted sorbent so that the gas may be vented from the second bag house; and
iv. a mercury-alumina reactor configured for introduction of the gas vented from the second bag house and alumina, where the gas is introduced at temperature(s) typically below the temperature at which desorption of mercury adsorbed on the surface of alumina occurs and is contacted with alumina for a time sufficient to effect the capture of mercury in the gas, the mercury being captured by adsorption on the surface of alumina, the reactor being further configured to render the gas that has been substantially stripped of mercury free of reacted and unreacted alumina so that the gas may be vented from the reactor, wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level;
B. introducing sorbent and the gas into the first bag house, the gas being at temperatures typically ranging from ambient to a temperature below the thermal decomposition temperature(s) of sulfates of manganese;
C. contacting the gas with sorbent for a time sufficient to effect SOX capture at a targeted SOX capture rate set point through the formation of sulfates of manganese to substantially strip the gas of SOX and to effect the capture of mercury, the mercury being captured in particulate form and by reacting with the sorbent to form mercury oxide(s) and salts of mercury to substantially strip the gas of mercury;
D. rendering the gas that has been substantially stripped of SOX and mercury compounds free of reacted and unreacted sorbent, mercury oxide(s), ash, and salts of mercury;
E. venting the gas from the first bag house;
F. introducing the sorbent and the gas from the first bag house into the second bag house zone, the gas being introduced at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese;
G. contacting the gas with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point through the formation of nitrate of manganese to substantially strip the gas of NOX;
H. rendering the gas free of reacted and unreacted sorbent;
I. venting the gas from the second bag house;
J. introducing the gas vented from the second bag house and alumina into the mercury-alumina reactor, the gas being introduced below the temperature at which desorption of mercury adsorbed on the surface of alumina occurs;
K. contacting the gas with the alumina for a time sufficient to effect the capture of mercury in the gas, the mercury compounds being captured by adsorption to the surface of alumina to substantially strip the gas of mercury, thereby loading the alumina;
L. rendering the gas free of reacted and unreacted alumina;
M. venting the gas from the reactor.
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65. A process for dry removal of SOX, NOX, mercury, and ash from a gas stream, comprising the steps of:
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A. providing an adaptable system for the removal of oxides of sulfur (SOX), oxides of nitrogen (NOX), mercury compounds in elemental, particulate, and compound forms, and ash from a gas with minimal differential pressure across the system, the system being comprised of;
i. a feeder containing a supply of sorbent of regenerable oxides of manganese and/or regenerated oxides of manganese;
wherein the feeder is configured to handle and feed oxides of manganese which, upon regeneration, are in particle form and are defined by the chemical formula MnOX, where X is about 1.5 to 2.0 and wherein the oxides of manganese have a particle size ranging from about 0.1 to about 500 microns and a BET value ranging from about 1 to about 1000 m2/g;
ii. a cyclone/multiclone configured for introduction of the sorbent and a gas containing SOX, NOX, mercury compounds, mercury vapor and ash, where the gas is introduced at temperatures typically ranging from ambient temperature to below the thermal decomposition temperature(s) of sulfates of manganese and contacted with the sorbent for a time sufficient to primarily effect SOX capture at a targeted SOX capture rate set point, the SOX being captured by reacting with the sorbent to form sulfates of manganese to substantially strip the gas of SOX and the mercury being captured in particulate form and by reacting with the sorbent to form mercury oxide(s) and salts of mercury to substantially strip the gas of mercury oxide(s) and salts of mercury, the cyclone/multiclone being further configured to render the gas that has been substantially stripped of SOX and mercury free of reacted and unreacted sorbent, mercury oxide(s), salts of mercury, and ash so that the gas may be vented from the cyclone/multiclone;
iii. a bag house configured for introduction of sorbent and the gas vented from the cyclone/multiclone where the gas is introduced at temperature(s) typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese and is further contacted with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point, the NOX being captured by reacting with the sorbent to form nitrates of manganese to substantially strip the gas of NOX, and the bag house being further configured to render the gas that has been substantially stripped of NOX free of reacted and unreacted sorbent so that the gas may be vented from the bag house; and
iv. a mercury-alumina reactor configured for introduction of the gas vented from the second bag house and alumina, where the gas is introduced at temperature(s) typically below the temperature at which desorption of mercury adsorbed on the surface of alumina occurs and is contacted with alumina for a time sufficient to effect the capture of mercury in the gas, the mercury being captured by adsorption on the surface of alumina, the reactor being further configured to render the gas that has been partially substantially stripped of mercury free of reacted and unreacted alumina so that the gas may be vented from the reactor, wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level;
B. introducing sorbent and the gas into the cyclone/multiclone, the gas being at temperatures typically ranging from ambient to a temperature below the thermal decomposition temperature(s) of sulfates of manganese;
C. contacting the gas with sorbent for a time sufficient to effect SOX capture at a targeted SOX capture rate set point through the formation of sulfates of manganese to substantially strip the gas of SOX and to effect capture of mercury, the mercury being captured in particulate form and by reacting with the sorbent to form mercury oxide(s) and salts of mercury to substantially strip the gas of mercury oxide(s) and salts of mercury;
D. rendering the gas free of reacted and unreacted sorbent, mercury oxide(s), ash, and salts of mercury;
E. venting the gas from the cyclone/multiclone;
F. introducing sorbent and the gas from the cyclone/multiclone into the bag house, the gas being introduced at temperatures typically ranging from ambient to below the thermal decomposition temperature(s) of nitrates of manganese;
G. contacting the gas with sorbent for a time sufficient to primarily effect NOX capture at a targeted NOX capture rate set point through the formation of nitrates of manganese to substantially strip the gas of NOX;
H. rendering the gas free of reacted and unreacted sorbent;
I. venting the gas from the bag house;
J. introducing the gas vented from the bag house and alumina into the mercury-alumina reactor, where the gas is introduced below the temperature at which desorption of mercury adsorbed on the surface of alumina occurs;
K. contacting the gas with the alumina for a time sufficient to effect the capture of mercury in the gas, the mercury being captured by adsorption onto the surface of alumina to substantially strip the gas of mercury, thereby loading the alumina;
L. rendering the gas free of reacted and unreacted alumina;
M. venting the gas from the reactor.
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89. An adaptable system for dry removal of pollutants from gases with minimal differential pressure across the system, comprising:
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a. a feeder containing a supply of sorbent, the feeder being configured to handle and feed sorbent; and
b. a reaction zone configured for introduction of sorbent and a gas containing target pollutant, where gas is introduced and contacted with the sorbent for a time sufficient to effect capture of the target pollutant at a targeted pollutant capture rate; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level. - View Dependent Claims (93, 94, 95, 96)
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90. An adaptable system for dry removal of pollutants from gases with minimal differential pressure across the system, comprising:
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a. a feeder containing a supply of sorbent, the feeder being configured to handle and feed sorbent;
b. a first reaction zone configured for introduction of sorbent and a gas containing at least first and second target pollutants, where gas is introduced and contacted with the sorbent for a time sufficient to primarily effect capture of a first target pollutant at a target pollutant capture rate; and
c. a second reaction zone configured for introduction of sorbent and a gas containing target pollutants, where gas is introduced and contacted with the sorbent for a time sufficient to primarily effect capture of a second target pollutant at a targeted pollutant capture rate; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
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91. An adaptable system for dry removal of pollutants from gases with minimal differential pressure across the system, comprising:
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a. at least one feeder containing a supply of sorbent, the feeder being configured to handle and feed sorbent; and
b. a modular reaction unit comprised of at least three (3) interconnected reaction zones, the reaction zones being connected so that gas containing pollutants can be routed through any one of the reaction units, any two of the reaction units, or all of the reaction units in series, in or in any combination of series and parallel, each reaction zone being separately connected to the feeder so that sorbent can be introduced into the reaction zone where capture of pollutants can tQ occur when the gas is contacted with the sorbent; and
wherein differential pressure within the system is regulated so that differential pressure across the system is no greater that a predetermined level.
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92. An adaptable system for dry removal of pollutants from gases with minimal differential pressure across the system, comprising:
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a. at least one feeder containing a supply of sorbent, the feeder being configured to handle and feed sorbent;
b. a first reaction zone configured for introduction of sorbent and a gas containing at least first and second target pollutants, where gas is introduced and contacted with the sorbent for a time sufficient to effect capture of at least the first target pollutant;
c. a second and a third reaction zone each connected to the first reaction zone by a common conduit and configured for introduction of sorbent and gas passing from the first reaction zone, where the gas passing from the first reaction zone is introduced and contacted with the sorbent for a time sufficient to effect capture of a least the second target pollutant;
d. a diverter valve for directing the flow of gas from the first reaction zone; and
wherein differential pressure within the system is regulated so that any differential pressure across the system is no greater than a predetermined level.
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Specification