Polyimide porous film

• US 20030018094A1
• Filed: 07/22/2002
• Published: 01/23/2003
• Est. Priority Date: 07/23/2001
• Status: Active Grant

• Current Assignee: UBE Industries Limited
• Original Assignee: UBE Industries Limited
• Inventors: Fukunaga, Kenji, Yao, Shigeru, Ohya, Shyusei, Asano, Yukihiko, Nakayama, Kimio, Fujii, Yuuichi
• Granted Patent: US 6,565,962 B2
• Time in Patent Office: Days
• US Class Current: 521/50
• CPC Class Codes: B29C 41/28 by depositing flowable material on an endless belt
• CPC Class Codes: B29K 2079/08 PI, i.e. polyimides or derivatives thereof
• CPC Class Codes: B29K 2105/04 cellular or porous
• CPC Class Codes: C08G 73/1028 characterised by the process itself, e.g. steps, continuous
• CPC Class Codes: C08J 2379/08 Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
• CPC Class Codes: C08J 5/18 Manufacture of films or sheets
• CPC Class Codes: Y10T 428/249978 Voids specified as micro
• CPC Class Codes: Y10T 428/249987 With nonvoid component of specified composition
• CPC Class Codes: Y10T 428/249988 Of about the same composition as, and adjacent to, the void-containing component
• CPC Class Codes: Y10T 428/249989 Integrally formed skin

Abstract

A polyimide porous film obtained by drying and imidizing a polyimide precursor porous film which is substantially homogeneous on both sides, the polyimide porous film having pores on both sides wherein the pores all satisfy the conditions: 1) the difference in the mean pore size of both sides is less than 200% based on the smaller average value of the mean pore size, 2) the coefficient of variation for the pore size on each side is smaller than 70%, 3) the coefficient of variation for the pore centroid distance on each side is smaller than 50%, and 4) the mean pore size on each side is 0.05-5 μm.

Claims

1. A polyimide porous film obtained by drying and imidizing a polyimide precursor porous film which is substantially homogeneous on both sides, the polyimide porous film having pores on both sides wherein the pores all satisfy the following conditions 1) to 4):

1) The difference in the mean pore size of both sides is less than 200% based on the smaller average value of the mean pore size.

2) The coefficient of variation for the pore size on each side is smaller than 70%.

3) The coefficient of variation for the pore centroid distance on each side is smaller than 50%.

4) The mean pore size on each side is 0.05-5 μ

m.

2. A polyimide porous film according to claim 1, wherein the polyimide precursor porous film is obtained by a method in which a polyimide precursor dope solution is cast and immersed in a coagulating solution to obtain a polyimide precursor porous film, wherein the following conditions for the composition of the dope solution and coagulating solution are satisfied:

(1) The polyimide precursor dope solution comprises 0.2-30 wt % of a polyimide precursor and 99.8-70 wt % of a mixture of a solvent and a non-solvent therefor.

(2) The mixed solvent of the dope solution comprises 50-90 wt % of the solvent and 50-10 wt % of the non-solvent (for a total of 100 wt %).

(3) The coagulating solution comprises 50-90 wt % of the non-solvent and 50-10 wt % of the non-solvent for the polyimide precursor (for a total of 100 wt %).

(4) The compositional ratio of the solvent in the dope solution is greater than the compositional ratio of the solvent in the coagulating solution.

3. A polyimide porous film according to claim 1, wherein the polyimide precursor porous film is obtained by a method of casting the polyimide precursor dope onto a substrate, forming on said liquid film a protective layer comprising a mixture of a solvent and a non-solvent, with 30-70 wt % of a non-solvent and 70-30 wt % of a polar solvent for the polyimide precursor (for a total of 100 wt %), and then immersing it in a coagulating solution.

4. A polyimide porous film according to claim 3, wherein the polyimide precursor porous film is obtained using as the non-solvent component of the protective film an aliphatic monohydric alcohol of 3-5 carbons.

5. A polyimide porous film according to claim 3, wherein the polyimide precursor porous film is obtained using as the non-solvent component of the protective layer a polyhydroxy alcohol selected from among alkylene glycols, glycerin and polyalkylene glycols and their derivatives, and using a coagulating solution with a composition comprising at least 60 wt % water.

6. A polyimide porous film according to claim 1, which is used for a battery separator or micro-filter.