Dielectric fluid having defined chemical composition for use in electrical apparatus

• US 20030164479A1
• Filed: 11/25/2002
• Published: 09/04/2003
• Est. Priority Date: 12/21/1995
• Status: Active Grant

• Current Assignee: Cooper Industries LLC (Eaton Corporation PLC.)
• Original Assignee: Cooper Industries, Inc. (Eaton Corporation PLC.)
• Inventors: Goedde, Gary L., Lapp, John, Gauger, Gary A., Yerges, Alan P.
• Granted Patent: US 6,726,857 B2
• Time in Patent Office: Days
• US Class Current: 252/570
• CPC Class Codes: H01B 3/20 liquids, e.g. oils silicone oils H01B3/46
• CPC Class Codes: H01F 27/12 Oil cooling

Abstract

The present invention comprises a mixture of hydrocarbons having a well-defined chemical composition that is suitable for use as a dielectric coolant in electrical equipment in general, and specifically in transformers. The dielectric coolants of the present invention are particularly suited for use in sealed, non-vented transformers, and have improved performance characteristics, including decreased degradation of the paper insulating layers, as well as a greater degree of safety and environmental acceptability. The present dielectric coolants comprise relatively pure blends of compounds selected from the group consisting of aromatic hydrocarbons, polyalphaolefins, polyol esters, and natural vegetable oils, along with additives to improve pour point, increase stability and reduce oxidation rate.

Claims

1. A dielectric coolant suitable for use in power distribution equipment, consisting essentially of:

approximately 1-99 weight percent alphaolefin oligomers with carbon chain lengths of C₆ to C₁₂ and

approximately 1-99 weight percent of a compound selected from the group consisting of polyols esterified with linear or branched alkyl groups with chain lengths of C₅ to C₂₀, and triglycerides.

2. A dielectric coolant suitable for use in power distribution equipment, comprising:

a mixture of a polyalphaolefin with a polyol ester, said polyalphaolefin being selected from the group consisting of oligomers of C₆, C₈, C₁₀, and C₁₂ alphaolefins.

3. The dielectric coolant according to claim 2 wherein said polyol ester is selected from the group consisting of neopentyl glycol, trimethylolpropane, and pentaerythritol.

4. The dielectric coolant according to claim 3 wherein said polyol ester includes an alkyl group having a chain length of C₅ to C₂₀.

5. The dielectric coolant according to claim 4 wherein said polyol ester includes an alkyl group having a chain length of C₈ to C₁₀.

6. The dielectric coolant according to claim 3 wherein said alkyl group is branched.

7. The dielectric coolant according to claim 6 wherein the branching location is at an alpha position of said allyl group.

8. The dielectric coolant according to claim 2 including 1-99 weight percent of a 2 cS polyalphaolefin, 99-1 weight percent of said polyol ester, and 0-1 weight percent of an antioxidant.

9. The dielectric coolant according to claim 2 including 45-55 weight percent of a 2 cS polyalphaolefin, 55-45 weight percent of said polyol ester, and approximately 0.3 weight percent of an antioxidant.

10. The dielectric coolant according to claim 2, further including a diepoxide.

11. The dielectric coolant according to claim 2, further including an antioxidant.

12. The dielectric coolant according to claim 11 wherein the antioxidant is TBHQ, BHA, BHT or DBPC.

13. The dielectric coolant according to claim 2, further including a pour point depressant.

14. The dielectric coolant according to claim 13 where in the pour point depressant is polymethacrylate.

15. A dielectric coolant, comprising:

a blend of a polyalphaolefin with a triglyceride, said polyalphaolefin being selected from the group consisting of oligomers of C₆, C₈, C₁₀, and C₁₂ alphaolefins.

16. The dielectric coolant according to claim 15 wherein said triglyceride includes three fatty acid chains, each of said fatty acid chains having a chain length of C₄ to C₂₂.

17. The dielectric coolant according to claim 15 wherein said triglyceride comprises a naturally occurring vegetable oil.

18. The dielectric coolant according to claim 15 wherein said triglyceride is selected from the group consisting of soya oil, sunflower oil, rapeseed oil, cottonseed oil, corn oil, olive oil, safflower oil, jojoba oil, and lesquerella oil and combinations thereof.

19. The dielectric coolant according to claim 15, further including an antioxidant.

20. The dielectric coolant according to claim 19 wherein the antioxidant is TBHQ, BHA, BHT or DBPC.

21. The dielectric coolant according to claim 15, further including a pour point depressant.

22. The dielectric coolant according to claim 21 wherein the pour point depressant is polymethacrylate.

23. A dielectric coolant suitable for use in power distribution equipment, consisting essentially of:

approximately 1-60 weight percent alphaolefin oligomers with carbon chain lengths of C₆ to C₁₂ and

approximately 40-99 weight percent of a compound selected from the group consisting of polyols esterified with linear or branched alkyl groups with chain lengths of C₅ to C₂₀, and triglycerides.