Nonaqueous electrochemical cell with improved energy density

• US 20030228518A1
• Filed: 06/05/2002
• Published: 12/11/2003
• Est. Priority Date: 06/05/2002
• Status: Active Grant

• Current Assignee: Energizer Brands, LLC (Energizer Holdings, Inc.)
• Original Assignee: Eveready Battery Company Incorporated (Energizer Holdings, Inc.)
• Inventors: Marple, Jack W.
• Granted Patent: US 6,849,360 B2
• Time in Patent Office: Days
• US Class Current: 429/221
• CPC Class Codes: H01M 4/06 Electrodes for primary cells
• CPC Class Codes: H01M 4/382 Lithium H01M4/405 takes precedence
• CPC Class Codes: H01M 4/5815 Sulfides
• CPC Class Codes: H01M 4/625 Carbon or graphite
• CPC Class Codes: H01M 4/661 Metal or alloys, e.g. alloy coatings H01M4/669 take precedence
• CPC Class Codes: H01M 6/16 with organic electrolyte H01M6/18 takes precedence
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

This invention relates to a nonaqueous cell comprising a lithium metallic foil anode and a cathode coating comprising iron disulfide as the active material wherein the coating is applied to at least one surface of a metallic substrate that functions as the cathode current collector. In particular, the cell of the within invention has improved performance on high rate discharge and is achieved, surprisingly, with an anode underbalance. The cell of the within invention has an anode to cathode input that is less than or equal to 1.0. We have discovered, unexpectedly, that the energy density for the cell both volumetrically and gravametrically can be improved by approximately 20 to 25% while only increasing the volume of the cathode coating solids by approximately 10% through a unique and novel cathode coating formulation used in conjunction with an alloyed lithium foil.

Claims

1. An electrochemical cell comprising a cathode assembly, said cathode assembly comprising a metallic cathode current collector having two major surfaces and a cathode coating disposed on at least one of said two major surfaces, said coating comprising iron disulfide, said cell further comprising a metallic lithium anode alloyed with aluminum, wherein the anode to cathode input ratio is less than or equal to 1.0.

2. The cell of claim 1, wherein said anode comprises less than 1.0 percent by weight of aluminum.

3. The cell of claim 2, wherein said anode comprises between 0.1 and 0.9 percent by weight of aluminum.

4. The cell of claim 3, wherein said anode comprises 0.5 percent by weight of aluminum.

5. The cell of claim 1, wherein said cathode coating further comprises a void volume of less than 43 percent.

6. The cell of claim 5, wherein said void volume is from 36 percent to 42 percent.

7. The cell of claim 6, wherein said cathode coating further comprises synthetic graphite.

8. The cell of claim 7, wherein said synthetic graphite is highly crystalline synthetic graphite.

9. The cell of claim 8, wherein said highly crystalline synthetic graphite has a mean particle size of 3.0 to 11.0 microns and a BET surface area of 3.0 to 11.0 m²/gm. and a DBP of 160 to 200.

10. The cell of claim 6, wherein said cathode coating further comprises acetylene black.

11. The cell of claim 6, wherein said cathode coating further comprises a micronized polytetrafluoroethylene powder.

12. The cell of claim 11, wherein said cathode coating further comprises a styrene-ethylene-butylene-styrene block copolymer.

13. The cell of claim 12, wherein said cathode coating further comprises fumed silica.

14. An electrochemical cell comprising a cathode assembly, said cathode assembly comprising a metallic cathode current collector having two major surfaces and a cathode coating disposed on at least one of said two major surfaces, said cathode coating comprising iron disulfide or pyrite, acetylene black and synthetic graphite, said cell further comprising a metallic lithium anode alloyed with aluminum.

15. The cell of claim 14, wherein said synthetic graphite and said acetylene black together comprise between 7.0 and 11.0 volume percent of the total solids content of said cathode coating.

16. The cell of claim 15, wherein said synthetic graphite and said acetylene black together comprise between 10.0 and 10.5 volume percent of the total solids content of said cathode coating.

17. The cell of claim 16, wherein the solids volume percent of said synthetic graphite is at least twice the solids volume percent of said acetylene black.

18. The cell of claim 14, wherein said synthetic graphite has a mean particle size of 3.0 to 11.0 microns and a BET surface area of 3.0 to 11.0 m²/gm. and a DBP of 160 to 200.

19. The cell of claim 14, wherein said cathode coating further comprises a micronized polytetrafluoroethylene powder.

20. The cell of claim 19, wherein said cathode coating further comprises a styrene-ethylene-butylene-styrene block copolymer.

21. The cell of claim 20, wherein said cathode coating further comprises fumed silica.

22. An electrochemical cell comprising a cathode assembly, said cathode assembly comprising a metallic cathode current collector having two major surfaces and a cathode coating disposed on at least one of said two major surfaces, said cathode coating comprising iron disulfide, acetylene black, highly crystalline synthetic graphite, micronized polytetrafluoroethylene, fumed silica and a styrene-ethylene-butylene-styrene block copolymer.

23. The cell of claim 22 wherein said cathode components are present in the following solids weight percents:

iron disulfide 90.0 to 94.0 percent;

acetylene black 1.0 to 3.0 percent;

synthetic graphite 3.0 to 6.0 percent;

polytetrafluoroethylene 0.2 to 0.6 percent;

silica 0.2 to 0.6 percent;

SEBS block copolymer 1.5 to 3.0 percent.