Low outgassing photo or electron beam curable rubbery polymer material, preparation thereof and device comprising same
First Claim
1. A composition of matter consisting essentially of a mixture, a blend or a reaction product of (i) a photo or electron beam curable material component based on a completely or substantially completely hydrogenated hydrocarbon based rubber material completely or substantially free of carbon-carbon double and triple bonds;
- (ii) a photoinitiator/photosensitizer component having essentially no volatility at room temperature and also yield photoproducts after exposure to actinic radiation that have minimal or no volatility at room temperature;
(iii) an optional viscosity adjustment component that is either homopolymerizable or is capable of copolymerizing with the photo or electron beam curable material component of (i); and
(iv) an optional inert filler.
1 Assignment
0 Petitions
Accused Products
Abstract
Disclosed are photo or electron beam polymerizable compositions, and preparation thereof and devices containing them. The composition contains completely or substantially completely hydrogenated hydrocarbon-based material completely free or substantially free of carbon-carbon double and triple bonds containing photo or electron beam curable terminal or pendant groups, low-outgassing photoinitiators, an optional viscosity adjustment component and an optional filler. The composition is visible light, UV or electron beam curable. It cures into a low-modulus, low outgassing polymer material. The composition can be used as an adhesive, sealant or lens potting material. It is ideal for use in lithographic tools involving deep or vacuum ultraviolet radiations, in particular, as lens potting materials for 157 nm lithographic tools.
-
Citations
17 Claims
-
1. A composition of matter consisting essentially of a mixture, a blend or a reaction product of
(i) a photo or electron beam curable material component based on a completely or substantially completely hydrogenated hydrocarbon based rubber material completely or substantially free of carbon-carbon double and triple bonds; -
(ii) a photoinitiator/photosensitizer component having essentially no volatility at room temperature and also yield photoproducts after exposure to actinic radiation that have minimal or no volatility at room temperature;
(iii) an optional viscosity adjustment component that is either homopolymerizable or is capable of copolymerizing with the photo or electron beam curable material component of (i); and
(iv) an optional inert filler. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 13, 14, 15, 16, 17)
-
-
11. A process for producing a composition of matter having low outgassing rate and low modulus between 25 and 10,000 psi (1.7×
- 105 to 6.8×
107 Pa), comprising the following steps of;
(A) providing a completely or substantially completely hydrogenated hydrocarbon-based rubber material (i) completely or substantially completely free of carbon-carbon double bond and triple bond having terminal and/or pendant groups that are photo and/or electron beam polymerizable;
(B) mixing the material (i) with a photoinitiator/photosensitizer (ii) having essentially no volatility at room temperature and also yielding photoproducts after exposure to actinic radiation that have minimal or no volatility at room temperature;
(iii) an optional viscosity adjustment component that is either homopolymerizable or is capable of copolymerizing with material (i); and
(iv) an optional inert filler;
(C) curing the mixture resulting from step (B) by visible light, UV light or electron beam to form a composition of matter having low outgassing rate and low modulus. - View Dependent Claims (12)
- 105 to 6.8×
Specification