Molecular wire injection sensors
First Claim
1. A sensor for sensing the presence of an analyte component, which sensor does not rely on redox mediators, the sensor comprising:
- a substrate that reports reception of mobile charge carriers to an electronic circuit; and
a plurality of active molecular recognition groups wired to a surface of the substrate by molecular wires aligned in a non random orientation, wherein when the analyte component contacts the active molecular recognition surfaces, mobile charge carriers are transferred directly to and through the molecular wires attached to said headgroup surfaces, without redox reaction in the molecular wires, to thereby allow the substrate to sense the presence of the analyte component.
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Abstract
Disclosed is a sensor for sensing the presence of an analyte component without relying on redox mediators. This sensor includes (a) a plurality of conductive polymer strands each having at least a first end and a second end and each aligned in a substantially common orientation; (b) a plurality of molecular recognition headgroups having an affinity for the analyte component and being attached to the first ends of the conductive polymer strands; and (c) an electrode substrate attached to the conductive polymer strands at the second ends. The electrode substrate is capable of reporting to an electronic circuit reception of mobile charge carriers (electrons or holes) from the conductive polymer strands. The electrode substrate may be a photovoltaic diode.
184 Citations
1 Claim
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1. A sensor for sensing the presence of an analyte component, which sensor does not rely on redox mediators, the sensor comprising:
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a substrate that reports reception of mobile charge carriers to an electronic circuit; and
a plurality of active molecular recognition groups wired to a surface of the substrate by molecular wires aligned in a non random orientation, wherein when the analyte component contacts the active molecular recognition surfaces, mobile charge carriers are transferred directly to and through the molecular wires attached to said headgroup surfaces, without redox reaction in the molecular wires, to thereby allow the substrate to sense the presence of the analyte component.
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Specification