PULSED DISCHARGE IONIZATION SOURCE FOR MINIATURE ION MOBILITY SPECTROMETERS

• US 20040164238A1
• Filed: 09/25/2002
• Published: 08/26/2004
• Est. Priority Date: 09/25/2002
• Status: Active Grant

• Current Assignee: UT-Battelle LLC
• Original Assignee: UT-Battelle LLC
• Inventors: Xu, Jun, Whitten, William B., Ramsey, J. Michael
• Granted Patent: US 6,822,225 B2
• Time in Patent Office: Days
• US Class Current: 250/287
• CPC Class Codes: G01N 27/622 Ion mobility spectrometry
• CPC Class Codes: H01J 49/168 field ionisation, e.g. corona discharge atmospheric pressure corona discharge per se H01T19/00

Abstract

A method and apparatus is disclosed for flowing a sample gas and a reactant gas (38, 43) past a corona discharge electrode (26) situated at a first location in an ion drift chamber (24), applying a pulsed voltage waveform comprising a varying pulse component and a dc bias component to the corona discharge electrode (26) to cause a corona which in turn produces ions from the sample gas and the reactant gas, applying a dc bias to the ion drift chamber (24) to cause the ions to drift to a second location (25) in the ion drift chamber (24), detecting the ions at the second location (25) in the drift chamber (24), and timing the period for the ions to drift from the corona discharge electrode to the selected location in the drift chamber.

Claims

1. A method of pulsed discharge for an analytical instrument, comprising:

flowing a sample gas and a reactant gas past a corona discharge electrode of non-radioactive material situated at a first location in an ion drift chamber;

applying a pulsed voltage to the corona discharge electrode to cause a corona which in turn produces ions from the sample gas and the reactant gas;

applying a dc bias to the ion drift chamber to cause the ions to drift to a second location in the ion drift chamber through a medium provided by a drift gas;

detecting the ions at the second location in the drift chamber;

timing a period for the ions to drift from the corona discharge electrode to the second location in the drift chamber; and

using the timed period to determine an identity of the sample gas.

2. The method of claim 1, wherein applying the pulsed voltage to the corona discharge element further includes generating a pulsed voltage comprising a controllable base dc component and a controllable varying pulse component.

3. The method of claim 1, wherein said pulsed voltage has a selected pulse width within a range from 40 ns to 100 μ

s.

4. The method of claim 1, wherein said pulsed voltage has a selected pulse height in a range from 0.2-3.3 kV.

5. The method of claim 1, wherein said pulse voltage has a frequency of approximately 20 Hz.

6. The method of claim 1, further comprising flowing the drift gas into the drift chamber proximate to the second location in the drift chamber.

7. The method of claim 1, further comprising recording the time at which ions from the sample gas arrive at the detector, comparing ions from the sample gas detected at the detector with a threshold, and when the threshold is exceeded, providing a visual display to a user indicating detection of a substance associated with the threshold.

8. An analytical instrument comprising:

a body forming an elongated chamber for reaction of gases and for movement of gases, said chamber having a first entrance for receiving a sample gas and having a second entrance for receiving a reactant gas and a drift gas;

a corona discharge electrode of non-radioactive material and a counter electrode positioned in the body at a first location in the chamber in a path of flow for the sample gas;

an ion detector at a second location the chamber spaced from the corona discharge electrode;

wherein a pair of electrodes are provided for applying a dc bias voltage along a length of the chamber; and

an electronic control for controlling application of a voltage to the corona discharge electrode and for timing an interval beginning with the application of the corona discharge voltage and ending with detection of the ions at the ion detector.

9. The instrument of claim 8, wherein the body forming the chamber has at least four electrode rings spaced apart and separated by dielectric spacer rings, said electrode rings and spacer rings having central openings which together form at least a portion of the chamber.

10. The instrument of claim 8, wherein the corona discharge electrode is disposed either axially or transversely to the elongated chamber through an opening in an end electrode and has a tip that is spaced from a next to the last electrode ring, which forms the counter electrode for the corona discharge element.

11. The instrument of claim 8, wherein the electronic control is operable for applying a voltage to the corona discharge electrode which further comprises a controllable base dc component and a controllable varying pulse component.

12. The instrument of claim 8, wherein the instrument does not have an ion injection gate at an end of the drift chamber where ions are introduced.

13. The instrument of claim 8, wherein the electronic control further comprises a microelectronic CPU for generating a start pulse, said CPU being connected to the detector through an amplifier and to a digitizer to received detected ion signals.

14. The instrument of claim 13, wherein the electronic control is connected to a visual display, and wherein the electronic control identifies sample gas by timing an ion drift time and compares ions detected at the detector with a threshold, and when the threshold is exceeded, provides a signal to a user through the visual display to indicate detection of a substance associated with the threshold.

15. The instrument of claim 8, wherein the electronic control further comprises means for applying a voltage to the corona discharge element which further comprises a base dc component and a varying pulse component.

16. The instrument of claim 8, further comprising means for flowing a second gas into the drift chamber proximate to the second location in the drift chamber and means for flowing a reactant gas into the chamber.