Cable with foamed plastic insulation comprising and ultra-high die swell ratio polymeric material

• US 20040222009A1
• Filed: 05/08/2003
• Published: 11/11/2004
• Est. Priority Date: 05/08/2003
• Status: Active Grant

• Current Assignee: CommScope Inc. (CommScope Holding Company, Inc.)
• Original Assignee: CommScope Inc. (CommScope Holding Company, Inc.)
• Inventors: Blew, Douglas J., Houston, Eddy R.
• Granted Patent: US 6,858,805 B2
• Time in Patent Office: Days
• US Class Current: 174/110F
• CPC Class Codes: H01B 3/441 from alkenes

Abstract

An electrical communications element having a foamed plastic insulation extruded about a conductor with said insulation comprising at least one component with no more than 20% by weight of an ultra-high die swell ratio polymer (UHDSRP), preferably around 15% by weight. The UHDSRP is defined as greater than 55% die swell ratio and more preferably greater than 65% die swell ratio. The insulation also preferably comprises at least a second component with a high degree of stress crack resistance, such that the combination of (minimally) these polymers will yield an insulation layer that has a unique combination of physical properties yielding a high degree of foaming, small uniform cell structure, characteristically lower attenuation, and stress crack resistance capable of withstanding greater than 100 hours at 100° C. while coiled at a stress level of 1 times the insulation outside diameter without failure (cracking).

Claims

1. An electrical communications element comprising a conductor and a surrounding foamed plastic insulation, said foamed plastic insulation comprising a blend of less than 20% by weight of a polymer having an ultra-high die swell ratio greater than 55% and at least one additional polymer composition having a high thermally accelerated stability as defined by an oxidative induction time (OIT) of greater than 15 minutes at 200°

C. according to ASTM method 4568.

3. The electrical communications element according to claim 1 wherein said at least one additional polymer has an oxidative induction time of greater than 20 minutes.

4. The electrical communications element according to claim 1 wherein said insulation has a thermally accelerated stress crack resistance of greater than 100 hours at 100°

C. while coiled at a stress level of 1 times the insulation outside diameter without exhibiting radial or longitudinal cracks.

5. The electrical communications element according to claim 1 wherein said at least one additional polymer has a dissipation factor lower than that of said ultra high die swell ratio polymer and less than 75 micro radians.

6. The electrical communications element according to claim 5 wherein said at least one additional polymer has a dissipation factor less than 50 micro radians.

7. The electrical communications element according to claim 1 wherein said at least one additional polymer having a high thermally accelerated stability as defined by an oxidative induction time (OIT) of greater than 15 minutes at 200°

C. according to ASTM method 4568 also has a dissipation factor less than 75 micro radians.

8. The electrical communications element according to claim 7 wherein said at least one additional polymer is a highly stabilized polyolefin a including phenolic antioxidants or phenolic antioxidant-phosphite blends as well as a hindered amine light stabilizer.

9. The electrical communications element according to claim 1 wherein said foamed plastic insulation comprises about 15% by weight of an olefin polymer having a die swell ratio greater than 55%.

10. The electrical communications element according to claim 1 wherein said polymer having a die swell ratio greater than 55% is a low density polyethylene and said at least one additional polymer having a high thermally accelerated stability defined by an oxidative induction time (OIT) of greater than 15 minutes at 200°

C. according to ASTM method 4568 is a polyolefin composition.

11. The electrical communications element according to claim 10 wherein said at least one additional polyolefin composition has a dissipation factor lower than that of said low density polyethylene and less than 75 micro radians.

12. A coaxial cable comprising a cable core including a center conductor and a surrounding dielectric and an outer conductor surrounding said cable core, and wherein the electrical communications element of claim 1 defines said cable core.

13. A twisted pair cable comprising at least two twisted pairs of insulated electrical conductors, wherein the electrical communications element of claim 1 defines each said insulated electrical conductor.

2. (Cancelled)

14. An electrical communications cable comprising a conductor and a surrounding foamed plastic insulation, said foamed plastic insulation comprising a blend of a first polyolefin having an ultra high die swell ratio greater than 55% present in an amount less than 20% by weight and at least one additional polyolefin having a high environmental stability as defined by an oxidative induction time (OIT) of greater than 15 minutes at 200°

C. according to ASTM method 4568.

15. The electrical communications cable according to claim 14 wherein said at least one additional polyolefin has a dissipation factor lower than the said ultra high die swell ratio polyolefin and which is less than 75 micro radians

16. The electrical communications cable according to claim 15 wherein said at least one additional polyolefin is a highly stabilized polyolefin including phenolic antioxidants or phenolic antioxidant-phosphite blends as well as a hindered amine light stabilizer.

17. The electrical communications cable according to claim 14 wherein the blend of said first polyolefin and said at least one additional polyolefin exhibits an oxidative induction time (OIT) of greater than 15 minutes at 200°

C. according to ASTM method 4568.

18. The electrical communications cable according to claim 17 wherein said blend exhibits an oxidative induction time of 20 minutes or greater.

19. The electrical communications cable according to claim 14 wherein said communications cable has a thermally accelerated stress crack resistance of greater than 100 hours at 100°

C. while coiled at a stress level of 1 times the insulation outside diameter without exhibiting radial or longitudinal cracks.

20. An electrical communications cable comprising a conductor and a surrounding foamed plastic insulation, said foamed plastic insulation comprising a blend of a first polyolefin having an ultra high die swell ratio greater than 55% present in an amount less than 20% by weight and a highly stabilized polyolefin containing phenolic antioxidants or phenolic antioxidant-phosphite blends together with a hindered amine light stabilizer.

21. The electrical communications cable according to claim 20 wherein the blend exhibits an oxidative induction time (OIT) of greater than 15 minutes at 200°

C. according to ASTM method 4568.

22. The electrical communications cable according to claim 20 wherein the blend exhibits a dissipation factor less than 75 micro radians.

23. The electrical communications cable according to claim 20 wherein the communications cable has a thermally accelerated stress crack resistance of greater than 100 hours at 100°

C. while coiled at a stress level of 1 times the insulation outside diameter without exhibiting radial or longitudinal cracks.

24. The electrical communications cable according to claim 20 wherein the ultra-high die swell ratio first polyolefin is about 15% by weight of said blend.

25. The electrical communications cable according to claim 24 wherein the ultra-high die swell ratio first polyolefin is low density polyethylene.