Quantum dot white and colored light-emitting devices

• US 20040259363A1
• Filed: 06/25/2004
• Published: 12/23/2004
• Est. Priority Date: 04/01/1998
• Status: Active Grant

• Current Assignee: Lumileds LLC (Apollo Global Management, Inc.)
• Original Assignee: Lumileds Lighting US LLC (Apollo Global Management, Inc.)
• Inventors: Bawendi, Moungi G., Jensen, Klavs F., Moon, Ronald L., Miller, Jeffrey N., Heine, Jason
• Granted Patent: US 7,264,527 B2
• Time in Patent Office: Days
• US Class Current: 438/689
• CPC Class Codes: B82Y 10/00 Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
• CPC Class Codes: C09K 11/02 Use of particular materials as binders, particle coatings or suspension media therefor
• CPC Class Codes: C09K 11/565 with zinc cadmium
• CPC Class Codes: C09K 11/883 with zinc or cadmium
• CPC Class Codes: H01L 33/06 within the light emitting region, e.g. quantum confinement structure or tunnel barrier
• CPC Class Codes: H01L 33/502 Wavelength conversion materials
• CPC Class Codes: H01L 33/504 Elements with two or more wavelength conversion materials
• CPC Class Codes: H01S 3/169 Nanoparticles, e.g. doped nanoparticles acting as a gain material
• CPC Class Codes: Y02B 20/00 Energy efficient lighting technologies, e.g. halogen lamps or gas discharge lamps
• CPC Class Codes: Y10S 977/95 Electromagnetic energy

Abstract

A light-emitting device comprising a population of quantum dots (QDs) embedded in a host matrix and a primary light source which causes the QDs to emit secondary light and a method of making such a device. The size distribution of the QDs is chosen to allow light of a particular color to be emitted therefrom. The light emitted from the device may be of either a pure (monochromatic) color, or a mixed (polychromatic) color, and may consist solely of light emitted from the QDs themselves, or of a mixture of light emitted from the QDs and light emitted from the primary source. The QDs desirably are composed of an undoped semiconductor such as CdSe, and may optionally be overcoated to increase photoluminescence.

Claims

1. A method of producing a light-emitting device, comprising:

(a) providing a population of quantum dots (QDs) and a host matrix, wherein each QD of the population comprises a core of an independently selected size and composition, the population comprises a selected size distribution of QDs, and the QDs have a surface adapted to allow the QDs to be dispersed in the host matrix;

(b) dispersing the QDs in the host matrix; and

(c) illuminating the QDs disposed in the host matrix with a light source that emits primary light which causes the QDs to photoluminesce secondary light, thereby causing the light-emitting device to emit light comprising a mixture of primary and secondary light.

2. The method of claim 1, wherein step (a) comprises growing the QDs by precipitation from a solution.

3. The method of claim 1, wherein the core comprises a material independently selected from the group consisting of CdS, CdSe, CdTe, ZnS, ZnSe, ZnTe, GaAs, GaP, GaAs, GaSb, HgS, HgSe, HgTe, InAs, InP, InSb, AlAs, AlP, AlSb, alloys thereof, and mixtures thereof.

4. The method of claim 1, wherein step (a) further comprises coating the core with an overcoat.

5. The method of claim 4, wherein the core overcoat comprises a material independently selected from the group consisting of ZnO, ZnS, ZnSe, ZnTe, CdO, CdS, CdSe, CdTe, MgS, MgSe, GaAs, GaN, GaP, GaAs, GaSb, HgO, HgS, HgSe, HgTe, InAs, InN, InP, InSb, AlAs, AlN, AlP, AlSb, alloys thereof, and mixtures thereof.

6. The method of claim 4, wherein the core overcoat is produced by precipitation from a solution.

7. The method of claim 1, wherein step (a) further comprises coating the QDs with a coat material having an affinity for the host matrix.

8. The method of claim 7, wherein the host matrix comprises a polymer and the coat material comprises a related monomer.

9. The method of claim 1, wherein the host matrix comprises a material selected from the group consisting of liquids, polymers, epoxies, silica glasses, silica gels, and combinations thereof.

10. The method of claim 1, wherein the host matrix comprises a polymer selected from the group consisting of polyacrylate, polystyrene, polyimide, polyacrylamide, polyethylene, polyvinyl, poly-diacetylene, polyphenylene-vinylene, polypeptide, polysaccharide, polysulfone, polypyrrole, polyimidazole, polythiophene, polyether, epoxies, silica glass, silica gel, siloxane, polyphosphate, hydrogel, agarose, and cellulose.

11. The method of claim 1, wherein the light source is selected from the group consisting of a light-emitting diode, a laser, an arc lamp and a black-body light source.

12. The method of claim 1, wherein the population of QDs has a size distribution having less than a 10% rms deviation in diameter of the core.

13. A method of preparing a device, comprising:

(a) providing a prepolymer composition, comprising

(i) a precursor material capable of being reacted to form a solid host matrix that allows light to pass therethrough, and

(ii) a population of quantum dots (QDs) disposed in the precursor material, wherein each QD of the population comprises a core of an independently selected size and composition, and the population comprises a selected size distribution of QDs,

(b) reacting the precursor material to form the host matrix with QDs dispersed therein; and

(c) providing a primary light source in optical communication with the host matrix with QDs dispersed therein.