Method of removing mecury from exhaust gases

• US 20050000357A1
• Filed: 07/03/2003
• Published: 01/06/2005
• Est. Priority Date: 07/03/2003
• Status: Active Grant

• Current Assignee: Lehigh University
• Original Assignee: Lehigh University
• Inventors: Simpson, Dale R.
• Granted Patent: US 6,962,617 B2
• Time in Patent Office: Days
• US Class Current: 95/134
• CPC Class Codes: B01D 2257/602 Mercury or mercury compounds
• CPC Class Codes: B01D 53/02 by adsorption, e.g. preparative gas chromatography solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01
• CPC Class Codes: B01D 53/64 Heavy metals or compounds thereof, e.g. mercury
• CPC Class Codes: Y10S 95/902 Molecular sieve

Abstract

Efficient removal of mercury from the exhaust gases of an industrial process or combustion process can be achieved using an adsorbent that can be regenerated by a simple and efficient method. The mercury is contacted with a sorbent material, the sorbent material being hydrogen mordenite or hydrogen clinoptilolite, for adsorbing mercury and causing the mercury to react with the sorbent material to produce mercury-laden sorbent material. The mercury-laden sorbent material can be heated to a temperature of at least about 400° C. so as to remove mercury from the mercury-laden sorbent material and to regenerate the sorbent material to allow reusing of the sorbent material for mercury removal.

Claims

1. A method of removing mercury from mercury-containing exhaust gases emanating from an industrial process or a combustion process, said method comprising:

contacting the mercury in the exhaust gases with a sorbent material, wherein the sorbent material is hydrogen mordenite or hydrogen clinoptilolite, for adsorbing mercury and causing the mercury to react with the sorbent material to produce mercury-laden sorbent material.

2. A method according to claim 1, wherein the sorbent material is hydrogen mordenite.

3. A method according to claim 2, further comprising a step of heating the mercury-laden sorbent material to a temperature of at least about 400°

C. so as to remove mercury from the mercury-laden sorbent material and to regenerate the sorbent material.

4. A method according to claim 3, further comprising a step of reusing of the sorbent material for mercury removal.

5. A method according to claim 3, further comprising a step of condensing mercury removed from the mercury-laden sorbent material.

6. A method according to claim 1, wherein the sorbent material is prepared by acid leaching mordenite or clinoptilolite.

7. A method according to claim 1, wherein the sorbent material is hydrogen clinoptilolite.

8. A method according to claim 7, further comprising a step of selecting a clinoptilolite stock, which can be ion exchanged and acid leached without degradation of the crystal structure.

9. A method according to claim 7, further comprising a step of disposing of the produced mercury-laden sorbent material.

10. A method according to claim 1, wherein the sorbent material is copper-impregnated hydrogen mordenite.

11. A method according to claim 1, wherein said step of contacting the mercury in the exhaust gases with the sorbent material occurs at a temperature higher than room temperature.

12. A method according to claim 1, wherein said step of contacting the mercury in the exhaust gases with the sorbent material occurs at a temperature higher than about 100°

C.

13. A method according to claim 1, wherein said step of contacting the mercury in the exhaust gases with the sorbent material occurs at a temperature higher than about 180°

C.

14. A method according to claim 1, further comprising a step of forming a particulate, fixed bed including the sorbent material, wherein said step of contacting of the mercury in the exhaust gases with the sorbent material is performed by conducting the exhaust gases through the fixed bed.

15. A method according to claim 14, further comprising a step of regenerating the sorbent material of the particulate bed by heating a portion of the sorbent material to a temperature of at least about 400°

C.

16. A method according to claim 15, wherein said regeneration step is performed by removing a portion of the sorbent material from the bed.

17. A method according to claim 1, wherein said step of contacting of the mercury in the exhaust gases with the sorbent material is performed by conducting the exhaust gases through a honeycomb element system comprising the sorbent material as an effective constituent.

18. A method according to claim 17, further comprising a step of regenerating the effective constituent of the honeycomb element system by heating the element system to a temperature of at least about 400°

C.

19. A method according to claim 18, further comprising a step of providing an exhaust gas train that includes two parallel honeycomb element units for receiving the exhaust gases.

20. A method according to claim 19, further comprising a step of regenerating one of the parallel honeycomb element units while simultaneously conducting the exhaust gases through the other unit.