Method to prevent low temperature degradation of zirconia

• US 20060121206A1
• Filed: 12/08/2005
• Published: 06/08/2006
• Est. Priority Date: 08/27/2004
• Status: Active Grant

• Current Assignee: Alfred E. Mann Foundation For Scientific Research
• Original Assignee: Alfred E. Mann Foundation For Scientific Research
• Inventors: Jiang, Guangqiang
• Granted Patent: US 7,435,443 B2
• Time in Patent Office: Days
• US Class Current: 427/457
• CPC Class Codes: A61L 27/10 Ceramics or glasses
• CPC Class Codes: A61L 27/306 Other specific inorganic materials not covered by A61L27/303 - A61L27/32
• CPC Class Codes: C04B 2111/00836 for medical or dental applications
• CPC Class Codes: C04B 35/48 based on zirconium or hafnium oxides, zirconates, zircon or hafnates
• CPC Class Codes: C04B 41/009 characterised by the material treated
• CPC Class Codes: C04B 41/4529 applied from the gas phase
• CPC Class Codes: C04B 41/5031 Alumina
• CPC Class Codes: C04B 41/87 Ceramics
• CPC Class Codes: C23C 14/081 of aluminium, magnesium or beryllium
• CPC Class Codes: C23C 14/22 characterised by the process of coating

Abstract

The invention is directed to a method of producing the material that is unaffected by the low-temperature degradation, humidity-enhanced phase transformation typical of yttria-stabilized zirconia, as well as of yttria-stabilized tetragonal zirconia polycrystalline ceramic (Y-TZP). Because of the high fracture toughness and high mechanical strength, this class of materials is widely used, including as implants, such as for the packaging material for small implantable neural-muscular sensors and stimulators. The destructive phase transformation rate is dramatically reduced by coating the surface of the Y-TZP component with dense alumina by a physical vapor deposition process, preferably ion beam assisted deposition.

Claims

1. A method of manufacturing a degradation resistant component for use in living tissue, comprising the steps of:

providing a component comprised of yttria-stabilized tetragonal zirconia polycrystal ceramic;

depositing a coating of alumina by ion beam assisted deposition on the component; and

selecting deposition parameters to achieve a coating comprised of less than about 1.0 percent total porosity.

2. The method according to claim 1, wherein said depositing a coating comprises the step of depositing alpha-alumina, amorphous alumina, or a blend thereof.

3. The method according to claim 1, wherein said depositing a coating comprises the step of depositing a coating comprised of an average grain size less than about 0.5 microns.

4. The method according to claim 1, wherein said depositing a coating of alumina comprises depositing a coating comprising a thickness that is greater than about 1.6 micron and less than about 10 microns.

5. The method according to claim 1, wherein said providing a component comprises providing a component comprising about 3 mole percent yttria.

6. The method according to claim 1, wherein said selecting deposition parameters comprises selecting an ion beam bombardment energy of about 1000 eV and an ion beam current of about 26 mA.

7. The method according to claim 1, wherein said depositing a coating comprises depositing at a rate of about 1.5 angstroms per second.