Method of surface oxidizing zirconium and zirconium alloys and resulting product
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Accused Products
Abstract
A coating of blue-black or black oxidized zirconium of uniform and controlled thickness on a zirconium or zirconium alloy material is accomplished through the use of a single phase crystalline material substrate having an altered surface roughness. An oxidized zirconium coating of uniform and controlled thickness is especially useful on orthopedic implants of zirconium or zirconium-based alloys to provide low friction, highly wear resistant surfaces on artificial joints, such as, but not limited to, hip joints, knee joints, shoulders, elbows, and spinal implants. The uniformly thick oxidized zirconium surface of controlled depth on prostheses provide a barrier against implant corrosion caused by ionization of the metal prostheses. The invention is also useful in non-articulating implant devices such as bone plates, bone screws, etc.
41 Citations
54 Claims
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1-45. -45. (canceled)
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46. A prosthesis for implantation in a patient, comprising:
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(a) a hip prosthesis body for implantation into a femor comprising a head portion formed of zirconium or zirconium alloy;
(b) a bearing surface on the head portion of the prosthesis body;
(c) an acetabular cup having an inner surface formed of an organic polymer or a polymer-based composite, said inner surface being adapted to cooperate with the bearing surface on the head portion; and
(d) a coating of blue-black or black oxidized zirconium of uniform thickness directly on the bearing surface of the head portion for reducing wear of the acetabular cup inner surface prepared by the process comprising the steps of altering the surface roughness of a zirconium or zirconium alloy having a single phase crystalline structure and uniform composition and subsequently oxidizing said zirconium or zirconium alloy. - View Dependent Claims (47, 48, 49, 50, 51)
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52. A prosthesis for implantation in a patient, comprising:
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(a) a prosthesis body having an external surface at least a portion of which is formed of zirconium or zirconium alloy, each having single phase crystalline structure and uniform composition and an altered surface roughness;
(b) a blue-black or black oxidized zirconium coating of uniform thickness formed on said portion of the external surface by inducing an altered surface roughness on at least said portion of the external surface and subjecting said portion of the external surface of said prosthesis body to an oxidation process; and
,wherein the prosthesis body comprises a spinal implant.
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- 53. A non-articulating medical implant formed at least in part of zirconium or zirconium alloy material comprising a partial or complete coat of blue-black or black oxidized zirconium of uniform thickness prepared by the process comprising the steps of altering the surface roughness of a zirconium or zirconium alloy having a single phase crystalline structure and uniform composition and subsequently oxidizing said zirconium or zirconium alloy.
Specification