Highly processible compounds of high MW conventional block copolymers and controlled distribution block copolymers

• US 20070066753A1
• Filed: 09/16/2005
• Published: 03/22/2007
• Est. Priority Date: 09/16/2005
• Status: Abandoned Application

• Current Assignee: Kraton Polymers US LLC (DL Holdings Co., Ltd.)
• Original Assignee: Kraton Polymers US LLC (DL Holdings Co., Ltd.)
• Inventors: Wright, Kathryn, Ehrlich, Martin
• Application Number:
  US11/228,107
• Publication Number:
  US 20070066753A1
• Time in Patent Office: Days
• US Class Current: 525/89
• CPC Class Codes: C08F 297/04 polymerising vinyl aromatic monomers and conjugated dienes
• CPC Class Codes: C08L 2205/02 containing two or more polymers of the same C08L -group
• CPC Class Codes: C08L 23/02 not modified by chemical after-treatment
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/24 Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
• CPC Class Codes: C08L 53/02 of vinyl-aromatic monomers and conjugated dienes
• CPC Class Codes: C08L 53/025 modified

Abstract

The present invention provides a polymeric compound (e.g., a compounded polymeric composition) of highly improved processibility that includes a conventional block copolymer, a controlled distribution block copolymer, and optionally one or more components selected from the group consisting of olefin polymers, styrene polymers, tackifying resins, extending oils, waxes, fillers, and engineering thermoplastic resins. The controlled distribution block copolymer is used as a flow modifier to enhance processability of the conventional block copolymer compound. The polymeric compound of the present invention suffers no reduction in mechanic properties while exhibiting improved processability. One advantage of the present invention is that high performance rubber compounds can be made which can be more easily thermally processed relative to prior art compounds. As such, lower energy consumption, reduced cycle times, reduced part warpage, and/or increasing mold complexity can be achieved.

Claims

1. A polymeric compound comprising:

(a) at least one block copolymer including at least one A₁ block and at least one B₁ block wherein (1) each A₁ block is a mono alkenyl arene homopolymer block having a number average molecular weight of about 3,000 to about 60,000;

(2) each B₁ block, prior to hydrogenation, is a conjugated diene hydrocarbon block selected from butadiene, isoprene and mixtures thereof having a number average molecular weight of about 30,000 to about 300,000; and

(3) the A₁ blocks constituting about 5 to about 40 weight percent of the copolymer; and

(b) at least one controlled distribution block copolymers including at least one A₂ block and at least one B₂ wherein (1) each A₂ block is a mono alkenyl arene homopolymer block and each B₂ block is a controlled distribution copolymer block of at least one conjugated-diene selected from butadiene and isoprene and at least one mono alkenyl arene;

(2) each A₂ block has a number average molecular weight from about 3,000 to about 60,000 and each B₂ block has a number average molecular weight from about 30,000 to about 300,000;

(3) each B₂ block comprises terminal regions adjacent to the A₂ blocks that are rich in conjugated diene units and one or more regions not adjacent to the A₂ blocks that are rich in mono alkenyl arene units;

(4) the total amount of mono alkenyl arene in the block copolymer is about 15 percent weight to about 80 percent weight; and

(5) the weight percent of mono alkenyl arene in each B₂ block is from about 10 percent to about 75 percent,

wherein the polymers of (a) and (b) are either selectively hydrogenated or unhydrogenated and the ratio of (a) to (b) is greater than or equal to 1;

1.

2. The polymeric compound of claim 1 further comprising (c) one or more components selected from the group consisting of olefin polymers, styrene polymers, tackifying resins, extending oils, waxes, fillers, and engineering thermoplastic resins.

3. The polymeric compound of claim 1 wherein said at least one block copolymer (a) has the formula A₁-B₁-A₁ or (A₁-B₁)_nX wherein n is between 1 and 30, and X is a coupling agent residue and wherein said at least one controlled distribution block copolymer (b) has the formula A₂-B₂-A₂ or (A₂-B₂)_nX wherein n is between 1 and 30, and X is a coupling agent residue.

4. The polymeric compound of claim 1 wherein:

each A₁ block of the block copolymer (a) is a mono alkenyl arene homopolymer block having a number average molecular weight of about 6,500 to about 45,000;

each B₁ block, prior to hydrogenation, is a conjugated diene hydrocarbon block having a number average molecular weight of about 40,000 to about 275,000;

the A₁ blocks constituting from about 15 to about 40 weight percent of the copolymer;

the unsaturation of the B₁ block is less than 5% of the original unsaturation; and

the unsaturation of the A₁ blocks is above 95% of the original unsaturation; and

each A₂ block of the block copolymer (b) is a mono alkenyl arene homopolymer block having a number average molecular weight of about 6,500 to about 45,000;

each B₂ block, prior to hydrogenation, is a conjugated diene hydrocarbon block having a number average molecular weight of about 40,000 to about 275,000;

the A₂ blocks constituting from about 15 to about 63 weight percent of the copolymer;

the unsaturation of the B₂ block is less than 5% of the original unsaturation; and

the unsaturation of the A₂ blocks is above 95% of the original unsaturation.

5. The polymeric compound of claim 1 wherein said at least one controlled distribution block copolymer (b) comprises styrene as said mono alkenyl arene and butadiene as said conjugated diene.

6. The polymeric compound of claim 5 wherein about 15 to about 80 mol percent of the conjugated butadiene units in the B₂ block have a 1,2-configuration.

7. The polymeric compound of claim 2 wherein said one or more components is an olefin polymer comprising at least one of ethylene homopolymers, ethylene/alpha-olefin copolymers, propylene homopolymers, propylene/alpha-olefin copolymers, high impact polypropylene, butylene homopolymers, butylene/alpha olefin copolymers, linear low density polyethylene (LLDPE), ultra or very low density polyethylene (ULDPE or VLDPE), medium density polyethylene (MDPE), high density polyethylene (HDPE), high pressure low density polyethylene (LDPE), ethylene/acrylic acid (EEA) copolymers, ethylene/methacrylic acid (EMAA) ionomers, ethylene/vinyl acetate (EVA) copolymers, ethylene/vinyl alcohol (EVOH) copolymers, ethylene/cyclic olefin copolymers, propylene/styrene copolymers, ethylene carbon monoxide interpolymers, or ethylene/acrylic acid/carbon monoxide terpolymers.

8. The polymeric compound of claim 7 wherein said olefin is polypropylene or a propylene copolymer.

9. The polymeric compound of claim 2 wherein said one or more components is a styrene polymer comprising at least one of crystal polystyrene, high impact polystyrene, medium impact polystyrene, styrene/acrylonitrile copolymers, styrene/acrylonitrile/butadiene (ABS) polymers, syndiotactic polystyrene, styrene/methyl-methacrylate copolymers or styrene/olefin copolymers.

10. The polymeric compound of claim 2 wherein said one or more components is an extending oil comprising a mineral oil, a synthetic oil, or a combination thereof.

11. The polymeric compound of claim 10 wherein said extending oil is a mineral oil comprising paraffinic or naphthenic oil.

12. The polymeric compound of claim 1 comprising:

100 parts by weight of the at least one block copolymer (a) and the at least one controlled distribution block copolymer (b) wherein (a) and (b) are both selectively hydrogenated and wherein the controlled distribution block copolymer is present in an amount of less than or equal to 50 parts by weight; and

about 5 to about 400 parts by weight of a polymer extending oil.

13. The polymeric compound of claim 1 comprising:

100 parts by weight of the at least one block copolymer (a) and the at least one controlled distribution block copolymer (b) wherein (a) and (b) are both selectively hydrogenated and wherein the controlled distribution block copolymer is present in an amount of less than or equal to 50 parts by weight; and

about 400 to about 3000 parts by weight of a polymer extending oil.

14. The polymeric compound of claim 1 comprising:

100 parts by weight of the at least one block copolymer (a) and the at least one controlled distribution block copolymer (b) wherein (a) and (b) are both selectively hydrogenated and wherein the controlled distribution block copolymer is present in an amount of less than or equal to 50 parts by weight; and

about 5 to about 100 parts by weight of an olefin polymer.

15. The polymeric compound of claim 14 further comprising about 5 to about 50 parts by weight of a tackifying resin.

16. The polymeric compound of claim 15 further comprising about 1 to about 20 parts by weight of an olefin wax.

17. The polymeric compound of claim 1 comprising:

100 parts by weight of the at least one block copolymer (a) and the at least one controlled distribution block copolymer (b) wherein (a) and (b) are both unhydrogenated and wherein the controlled distribution block copolymer is present in an amount of less than or equal to 50 parts by weight; and

about 5 to about 100 parts by weight of an styrenic polymer.

18. The polymeric compound of claim 14 further comprising about 5 to about 300 parts by weight of a polymer extending oil.

19. An article comprising the polymeric compound of claim 1.

20. An article comprising the polymeric compound of claim 12.

21. An article comprising the polymeric compound of claim 18.