Conducting polymer composition and electronic device including layer obtained using the conducting polymer composition
First Claim
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1. A conducting polymer composition, comprising:
- a conducting polymer; and
a siloxane material of Formula (1);
where A is selected from the group consisting of a C1-C20 alkyl group, a C6-C30 aryl group, a C1-C20 alkoxy group, a C7-C30 alkylaryl group, a C7-C30 aralkyl group, and —
(CH2)n-MZ1Z2Z3 where n is 0 or an integer from 1 to 20, M is Si, Ti, Sn, or Al, and each of Z1, Z2, and Z3 is independently selected from the group consisting of a C1-C20 alkyl group, a C6-C30 aryl group, a C7-C30 alkylaryl group, a C7-C30 aralkyl group, a cross-linkable unit, a hole transport unit, an electron transport unit, and an emissive unit; and
a is an integer from 2 to 1,000.
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Abstract
A conducting polymer composition containing a siloxane material of Formula (1) below and a conducting polymer, and an electronic device including a layer formed using the conducting polymer composition:
68 Citations
26 Claims
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1. A conducting polymer composition, comprising:
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a conducting polymer; and
a siloxane material of Formula (1);
where A is selected from the group consisting of a C1-C20 alkyl group, a C6-C30 aryl group, a C1-C20 alkoxy group, a C7-C30 alkylaryl group, a C7-C30 aralkyl group, and —
(CH2)n-MZ1Z2Z3 where n is 0 or an integer from 1 to 20, M is Si, Ti, Sn, or Al, and each of Z1, Z2, and Z3 is independently selected from the group consisting of a C1-C20 alkyl group, a C6-C30 aryl group, a C7-C30 alkylaryl group, a C7-C30 aralkyl group, a cross-linkable unit, a hole transport unit, an electron transport unit, and an emissive unit; and
a is an integer from 2 to 1,000. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23)
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24. An electronic device having a conducting layer obtained from a conducting polymer composition, the conducting polymer composition, comprising
a conducting polymer; - and
siloxane material selected from the group consisting of a compound represented by Formula (2), and a hydrolysate or a condensate of at least one compound selected from the group consisting of the compound of said Formula (2), a compound of Formula (3), a compound of Formula (4), a compound of Formula (5), and a compound of Formula (6);
where n is 0 or an integer from 1 to 20;
M is Si, Ti, Sn, or Al;
each of Z1, Z2, and Z3 is independently selected from the group consisting of a C1-C20 alkyl group, a C6-C30 aryl group, a C7-C30 alkylaryl group, a C7-C30 aralkyl group, a cross-linkable unit, a hole transport unit, an electron transport unit, and an emissive unit, wherein the eight —
(CH2)nMZ1Z2Z3 groups are the same or different;
each of R1 and R2 is independently selected from the group consisting of —
CH2(CH2)mSiX1X2X3, —
O—
SiX4X5X6, a cross-linkable unit, a hole transport unit, an electron transport unit, an emissive unit, hydrogen, a halogen atom, a C1-C20 alkyl group, and a C6-C30 aryl group, wherein at least one of R1 and R2 is —
CH2(CH2)mSiX1X2X3, —
O—
SiX4X5X6, or a cross-linkable unit;
each of X1, X2, X3, X4, X5, X6, X7, X8, X9, X10, X11, X12, X13, X14, X15, X16, X17, X18, X19, X20, X21, X22, and X23 is independently selected from the group consisting of a cross-linkable unit, a hole transport unit, an electron transport unit, an emissive unit, hydrogen, a halogen atom, and a C1-C20 alkyl group, wherein at least one of X1, X2, and X3, at least one of X4, X5, and X6 , at least one of X7, X8, X9, X10, X11, X12, X13, and X14, at least one of X15, X16, X17, X18, X19, and X20, and at least one of X21, X22, and X23 is a cross-linkable unit;
D1 is a single bond or —
O—
;
D2 is a C1-C20 alkylene group, a C1-C20 alkylene group substituted with at least one halogen atom, —
(CF2)b-O—
, a C1-C20 alkylene group substituted with at least one of a hole transport unit, an electron transport unit, or an emissive unit, or a divalent hole transport unit, wherein b is an integer from 1 to 20;
D3 is a single bond, a C1-C20 alkylene group substituted with at least one halogen atom, or a C1-C20 alkylene group;
p is an integer from 3 to 8;
m is an integer from 1 to 10;
q is 0 or an integer from 1 to 10;
r is 0 or an integer from 1 to 10;
X10 are the same or different from each other;
X11 are the same or different from each other; and
D2 are the same or different from each other.
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25. An organic light-emitting device, comprising:
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a first electrode;
a second electrode;
an emitting layer interposed between the first electrode and the second electrode; and
at least one of a hole transporting layer and a hole injecting layer interposed between the emitting layer and the first electrode, said at least one of the hole transporting layer and the hole injecting layer obtained from a conducting polymer composition, the conducting polymer composition, comprising;
a conducting polymer; and
a siloxane material of Formula (1);
where A is selected from the group consisting of a C1-C20 alkyl group, a C6-C30 aryl group, a C1-C20 alkoxy group, a C7-C30 alkylaryl group, a C7-C30 aralkyl group, and —
(CH2)n-MZ1Z2Z3 where n is 0 or an integer from 1 to 20, M is Si, Ti, Sn, or Al, and each of Z1, Z2, and Z3 is independently selected from the group consisting of a C1-C20 alkyl group, a C6-C30 aryl group, a C7-C30 alkylaryl group, a C7-C30 aralkyl group, a cross-linkable unit, a hole transport unit, an electron transport unit, and an emissive unit; and
a is an integer from 2 to 1,000. - View Dependent Claims (26)
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Specification