Rubber Compositions, Methods of Making Rubber Compositions Rubber and Rubber-Containing Articles

• US 20070231532A1
• Filed: 09/23/2004
• Published: 10/04/2007
• Est. Priority Date: 09/23/2003
• Status: Abandoned Application

• Current Assignee: Haydale Limited (Haydale Graphene Industries PLC)
• Original Assignee: Haydale Limited (Haydale Graphene Industries PLC)
• Inventors: Walters, Ian, Hough, Philip
• Application Number:
  US10/574,024
• Publication Number:
  US 20070231532A1
• Time in Patent Office: Days
• US Class Current: 428/97
• CPC Class Codes: B32B 25/10 next to a fibrous or filamentary layer
• CPC Class Codes: C08K 3/013 Fillers, pigments or reinforcing additives
• CPC Class Codes: C08L 19/003 Precrosslinked rubber; Scrap rubber; Used vulcanised rubber
• CPC Class Codes: C08L 21/00 Compositions of unspecified rubbers
• CPC Class Codes: C08L 2666/08 Homopolymers or copolymers according to C08L7/00 - C08L21/00; Derivatives thereof
• CPC Class Codes: D06N 2201/02 Synthetic macromolecular fibres
• CPC Class Codes: D06N 2201/0254 Polyolefin fibres
• CPC Class Codes: D06N 2201/0263 Polyamide fibres
• CPC Class Codes: D06N 2203/02 Natural macromolecular compounds or derivatives thereof
• CPC Class Codes: D06N 2203/022 Natural rubber
• CPC Class Codes: D06N 2203/042 Polyolefin (co)polymers
• CPC Class Codes: D06N 2203/047 Arromatic vinyl (co)polymers, e.g. styrene
• CPC Class Codes: D06N 2205/04 Foam
• CPC Class Codes: D06N 2205/10 Particulate form, e.g. powder, granule
• CPC Class Codes: D06N 2205/106 Scrap or recycled particles
• CPC Class Codes: D06N 2205/20 Cured materials, e.g. vulcanised, cross-linked
• CPC Class Codes: D06N 2207/08 using gas
• CPC Class Codes: D06N 2207/123 using electromagnetic radiation, e.g. IR, UV, actinic light, laser, X-ray, gamma-ray, microwave, radio frequency
• CPC Class Codes: D06N 2211/066 Floor coverings
• CPC Class Codes: D06N 7/0076 the back coating or pre-coat being a thermoplastic material applied by, e.g. extrusion coating, powder coating or laminating a thermoplastic film
• CPC Class Codes: D06N 7/0081 : with at least one extra fibrous layer at the backing, e.g. stabilizing fibrous layer, fibrous secondary backing
• CPC Class Codes: Y02P 20/582 : Recycling of unreacted starting or intermediate materials
• CPC Class Codes: Y02P 70/62 : related technologies for production or treatment of textile or flexible materials or products thereof, including footwear
• CPC Class Codes: Y10T 428/23993 : Composition of pile or adhesive

Abstract

The application discloses coherent, processable rubber compositions containing cured rubber particles, especially recycled crumb rubber, dispersed in a curable base rubber. A processable composition, particularly one which can be roll-processed into a self-sustaining web is achieved by including in the curable rubber a low-viscosity curable rubber component such as a liquid rubber. This component wets the crumb rubber enabling it to disperse fully during mixing and connect intimately into the structure upon curing. This technique enables larger quantities and/or smaller particle sizes of the crumb rubber to be successfully incorporated while maintaining processability. Inert fillers can be used or omitted, reducing density. The novel rubber compounds are particularly suitable for making into layer products such as mats and flooring materials. Desirably these are laminated with fabric such as tufted textiles. This can be done in a compression moulding process.

Claims

1. A method of making a curable rubber compound in which particulate cured rubber (crumb rubber) is mixed with curable base rubber and a corresponding curing system, characterized by inclusion of a curable base rubber low-viscosity component sufficient to wet the crumb rubber whereby a curable compound which can be roll-processed is formed.

2. A method according to claim 1 in which to wet the crumb rubber a liquid curable rubber is combined with a non-liquid curable base rubber.

3. A method according to claim 1 in which the non liquid curable base rubber has a Mooney viscosity (ML1+4 @ 100°

C.) of from 30 to 80.

4. A method according to claim 1 in which the crumb rubber particles are all less than 0.5 mm in size.

5. A method according to claim 4 in which the crumb rubber particles are all less than 0.25 mm in size.

6. A method according to claim 1 in which the crumb rubber particles constitute at least 20% of the curable rubber compound.

7. A method according to claim 6 in which the crumb rubber particles constitute at least 30% of the curable rubber compound.

8. A method according to claim 1 in which the curable rubber compound contains not more than 15 wt % inert filler.

9. A method according to claim 8 in which the curable rubber compound contains not more than 5 wt % inert filler.

10. A method according to claim 1 in which the crumb rubber is recycled rubber.

11. A method according to claim 2, in which the liquid rubber and crumb rubber are separate from one another at least immediately before their respective addition to the mix.

12. A method according to claim 2, in which the amount of liquid curable rubber used is at least 5 phr.

13. A method according to claim 1 including forming the curable rubber compound into a coherent self-sustaining web between rollers.

14. A curable rubber compound, processable or processed by one or more methods selected from roll-processing, extrusion and flow moulding, obtainable by a method according to claim 1.

15. A compound according to claim 14 in sheet form.

16. A method of making an article comprising curing a compound according to claim 14.

17. A method according to claim 16 in which the compound is cured with heating in a compression mould.

18. A method of claim 15 comprising as a preliminary stage the preparation of the curable rubber compound by a method according to claim 1.

19. A method according to claim 16 in which the article is in layer form.

20. A method according to claim 19 in which the article comprises a layer of the rubber compound and a superimposed layer of fabric.

21. A method according to claim 20 in which the fabric is tufted.

22. An article comprising crumb rubber-filled cured rubber, obtainable by a method according to claim 16.

23. A mat or flooring material comprising a textile layer bonded to a rubber backing layer, the rubber backing layer comprising a uniform dispersion of cured rubber particles in a matrix of a cured second rubber, the cured rubber particles constituting at least 20 wt % of the rubber backing layer.

24. A mat or flooring material according to claim 23 in which the textile layer is tufted.

25. A mat or flooring material according to claim 23 in which the cured rubber particles have less than 0.25 mm particle size.

26. A mat or flooring material according to claim 23 in which the cured rubber particles are recycled rubber.

27. A mat or flooring material according to claim 23 in which the cured rubber particles and the matrix rubber include rubbers of the same type, selected from NBR, SBR and NR.

28. A mat or flooring material according to claim 23 in which the rubber backing layer is from 1 to 20 mm thick.

29. A mat or flooring material according to claim 23 in which the density of the rubber backing layer is not more than 1.2 g/cm³.

30. A method of making a mat or flooring material according to claim 23 in which a roll processed layer of uncured rubber compound, comprising a coherent web comprising the cured rubber particles dispersed in the uncured second rubber, is joined to the textile layer under heat and compression in a mould to cure the second rubber.