HEAT TRANSFER LABEL

• US 20070254116A1
• Filed: 04/28/2006
• Published: 11/01/2007
• Est. Priority Date: 04/28/2006
• Status: Active Grant

• Current Assignee: Multi-Color Corporation
• Original Assignee: Multi-Color Corporation
• Inventors: Laprade, Jean-Paul
• Granted Patent: US 7,622,171 B2
• Time in Patent Office: Days
• US Class Current: 428/32.780
• CPC Class Codes: B32B 27/10 of paper or cardboard
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 29/00 Layered products comprising a layer of paper or cardboard
• CPC Class Codes: B44C 1/172 Decalcomanias provided with a layer being specially adapted to facilitate their release from a temporary carrier
• CPC Class Codes: Y10T 428/28 Web or sheet containing structurally defined element or component and having an adhesive outermost layer
• CPC Class Codes: Y10T 428/2822 Wax containing
• CPC Class Codes: Y10T 428/2826 Synthetic resin or polymer
• CPC Class Codes: Y10T 428/2848 Three or more layers

Abstract

A heat transfer label comprising a support portion and a transfer portion for transfer of the transfer portion from the support portion to an article. The article may be untreated polyethylene, polypropylene, PET, or acrylonitrile. Heat is applied to the support portion while the transfer portion is placed into contact with the untreated polyethylene, polypropylene, or acrylonitrile article. The transfer portion comprises an adhesive layer comprising a vinyl acetate resin, a tackifying petroleum hydrocarbon resin, and a microcrystalline wax.

Claims

1. A heat transfer label comprising:

(a) a support portion;

(b) a transfer portion over said support portion for transfer of the transfer portion, from the support portion to an article that has not undergone an oxidizing treatment, upon application of heat to the support portion while the transfer portion is placed into contact with the article, said transfer portion including an adhesive layer comprising a vinyl acetate resin, a tackifying petroleum hydrocarbon resin, and a microcrystalline wax.

2. The heat transfer label of claim 1, wherein said vinyl acetate resin is an ethylene vinyl acetate resin further comprising a 39-42% vinyl acetate resin which is soluble in organic solvents and has a bulk density of about 30 lb/ft³, a ring and ball softening point of about 200°

C., and a melt index of 48-66 grams per 10 minutes.

3. The heat transfer label of claim 2, wherein said vinyl acetate resin is ELVAX®

40-W.

4. The heat transfer label of claim 1, wherein said vinyl acetate resin is an ethylene vinyl acetate resin having a vinyl acetate content of between 18 and 42 percent.

5. The heat transfer label of claim 4, wherein said tackifying petroleum hydrocarbon resin has a Tg range of between 30°

C. and 85°

C.

6. The heat transfer label of claim 1, wherein said tackifying petroleum hydrocarbon resin has a Tg range of between 30°

C. and 85°

C.

7. The heat transfer label of claim 1, wherein said tackifying petroleum hydrocarbon resin further comprises Escorez 1315.

8. The heat transfer label of claim 3, wherein said tackifying petroleum hydrocarbon resin comprises Escorez 1315.

9. The heat transfer label of claim 1, wherein said microcrystalline wax further includes a melting point of 150-180°

F., a hardness of greater than 10 dmm at 77°

F., and is 30-60% normal paraffins.

10. The heat transfer label of claim 9, wherein said microcrystalline wax is Victory White.

11. The heat transfer label of claim 8, wherein said microcrystalline wax is Victory White.

12. The heat transfer label of claim 1, wherein said transfer portion further comprises a protective lacquer layer.

13. The heat transfer label of claim 12, wherein said protective lacquer layer further comprises a hard polyester or acrylic resin being a copolyester resin having a high tensile strength of 8000 psi, a low elongation of 7%, a 79 D scale Shore Durometer hardness, and a 156°

C. ring and ball melt flow point.

14. The heat transfer label of claim 12, wherein said transfer portion further comprises a release agent and at least one of a hard polyester resin and an acrylic resin.

15. The heat transfer label of claim 14, wherein said release agent is a surfactant or a wax.

16. The heat transfer label of claim 15, wherein said release agent is selected from the group consisting of dioctyl sodium sulfosuccinate in mineral seal oil, ethoxylated alcohol, and carnauba wax.

17. The heat transfer label of claim 16, wherein said release agent is carnauba wax.

18. The heat transfer label of claim 12, further comprising an ink layer proximal to said protective lacquer layer.

19. The heat transfer label of claim 18, said ink layer comprising a resin chosen from a polyamide, a polyester, a vinyl, and an acrylic.

20. The heat transfer label of claim 19, wherein said ink layer comprises a polyamide resin, and said polyamide resin is a clear alcohol soluble polyamide resin based on dimerized vegetable acid and aliphatic polyamines and having a Brookfield viscosity at 160°

C. of 4-7 poise, a softening point of 105-115°

C. and a Gardner color (maximum) of 7.

21. The heat transfer label of claim 1, further comprising a wax-like skim coat interposed between said support portion and said transfer portion.

22. The heat transfer label of claim 1, wherein said support portion includes a sheet of paper.

23. The heat transfer label of claim 22, wherein said support portion comprises one-sided clay-coated paper.

24. An adhesive composition comprising:

(a) a vinyl acetate resin;

(b) a tackifying petroleum hydrocarbon resin; and

(c) a microcrystalline wax.