SURFACTANTS AND POLYMERIZABLE SURFACTANTS BASED ON ROOM-TEMPERATURE IONIC LIQUIDS THAT FORM LYOTROPIC LIQUID CRYSTAL PHASES WITH WATER AND ROOM-TEMPERATURE IONIC LIQUIDS
First Claim
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1. A polymerizable surfactant composition having the general formula:
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Abstract
A modular surfactant architecture based on room temperature ionic liquids (RTILs) has been developed that affords non-polymerizable and polymerizable amphiphiles that form lamellar (L), hexagonal (H) or bicontinuous cubic (Q) LLC phases when mixed with water or RTILs serving as the polar solvent. The amphiphiles are imidazolium salts having two or more imidazolium head groups joined by one or more spacers. Polymerization of the LLC assembly can produce polymeric materials having ordered nanopores, with the ordering of the pores determined by the LLC phase.
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Citations
22 Claims
- 1. A polymerizable surfactant composition having the general formula:
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6. A lyotropic liquid crystal system comprising
a surfactant having the composition given by Wherein X is an anion; -
Y1 and Y2 each are a hydrophobic tail group comprising at least 10 carbon atoms;
Z1, Z2, Z3 each are hydrogen or a hydrophobic tail group comprising from 1 to 12 carbon atoms; and
L is a spacer group which comprises an alkyl group having from 1 to 12 carbon atoms or comprises 1 to 6 ether groups; and
a polar solvent, wherein the concentration of the surfactant is between 10 wt % and 100 wt % and the surfactant forms a lyotropic liquid crystal phase in combination with the solvent. - View Dependent Claims (7, 8, 9, 10, 11, 12)
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Specification