CURABLE TONER COMPOSITIONS AND PROCESSES
First Claim
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1. An emulsion aggregation toner composition comprising toner particles comprising:
- an unsaturated polymeric resin, wherein the unsaturated polyester resin is selected from the group consisting of amorphous resins, crystalline resins, and mixtures thereof;
an optional colorant;
an optional wax;
an optional coagulant; and
a photo initiator capable of initiating crosslinking of said unsaturated polymeric resin.
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Abstract
An emulsion aggregation toner composition includes toner particles including: an unsaturated polymeric resin, selected from amorphous resins, crystalline resins, and mixtures thereof; an optional colorant; an optional wax; an optional coagulant; and a photo initiator capable of initiating crosslinking of said unsaturated polymeric resin.
58 Citations
21 Claims
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1. An emulsion aggregation toner composition comprising toner particles comprising:
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an unsaturated polymeric resin, wherein the unsaturated polyester resin is selected from the group consisting of amorphous resins, crystalline resins, and mixtures thereof; an optional colorant; an optional wax; an optional coagulant; and a photo initiator capable of initiating crosslinking of said unsaturated polymeric resin. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 18, 19, 20, 21)
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17. A emulsion aggregation process for preparing a toner, comprising:
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(i) emulsifying an unsaturated polyester resin with optionally a photo-initiator, wherein the unsaturated polyester resin is selected from the group consisting of amorphous resins, crystalline resins, and mixtures thereof; (ii) adding thereto a colorant dispersion, optionally a photoinitiator dispersion, optionally a wax dispersion, and surfactant; (iii) adding thereto a coagulant to form a mixture, with homogenization of from about 2,000 to about 10,000 rpm, and optionally adjusting a pH of the mixture from about 7 to about 2.5, and thereby generating an aggregate mixture comprising aggregated composites of from about 1 to about 4 microns in diameter; (iv) heating the aggregate mixture to a temperature of from about 30 to about 50°
C. to generate aggregate composites with a particle size of from about 3 to about 11 microns in diameter;(v) adjusting the pH to about 6 to about 9 to freeze the toner composite particle size, and optionally adding a metal sequestering agent; (vi) heating the aggregate composites to a temperature of from about 63 to about 90°
C., and optionally adjusting the pH to about 8 to about 5.5, to result in coalesced toner particles; and(vii) optionally washing and drying the toner particles.
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Specification