ULTRACAPACITOR ELECTRODE WITH CONTROLLED IRON CONTENT

• US 20080204973A1
• Filed: 02/28/2007
• Published: 08/28/2008
• Est. Priority Date: 02/28/2007
• Status: Abandoned Application

• Current Assignee: Tesla Inc.
• Original Assignee: Maxwell Technologies Incorporated (Tesla Inc.)
• Inventors: Mitchell, Porter, Xi, Xiaomei, Zhong, Linda
• Application Number:
  US11/680,497
• Publication Number:
  US 20080204973A1
• Time in Patent Office: Days
• US Class Current: 361/502
• CPC Class Codes: H01G 11/28 arranged or disposed on a current collector; Layers or phases between electrodes and current collectors, e.g. adhesives
• CPC Class Codes: H01G 11/38 Carbon pastes or blends; Binders or additives therein
• CPC Class Codes: Y02E 60/13 Energy storage using capacitors

Abstract

Particles of active electrode material are made by blending or mixing a mixture of activated carbon, optional conductive carbon, and binder. In selected implementations, iron level in the activated carbon is relatively low, a small amount of conductive carbon with low impurity levels and high conductivity is used, and the binder is inert. For one example, iron content of the activated carbon and the resultant mixture is below 20 ppm. The electrode material may be attached to a current collector to obtain an electrode for use in various electrical devices, including a double layer capacitor. The electrode decreases current leakage of the capacitor.

Claims

1. A method of making an active electrode material, the method comprising:

providing activated carbon;

providing binder; and

mixing the activated carbon and the binder to obtain a mixture, wherein the mixture results with an iron content in the range of about 0 and about 20 parts per million.

2. A method in accordance with claim 1, wherein the providing activated carbon operation further comprises providing activated carbon with an iron content not exceeding about 20 parts per million.

3. A method in accordance with claim 1, wherein the operation of providing the activated carbon includes providing activated carbon in amount of between about 80 and about 97 percent by weight, and wherein the operation of providing the binder includes providing binder in amount of between about 3 and about 20 percent by weight.

4. A method in accordance with claim 1, further comprising providing an additional additive component having an iron content not exceeding an amount whereby the mixture has an iron content in the range of about 0 and about 20 parts per million.

5. A method in accordance with claim 4, wherein the additional additive component is conductive carbon.

6. A method in accordance with claim 1, wherein the operation of mixing includes dry blending the activated carbon and the binder.

7. A method in accordance with claim 1, wherein the operation of mixing is performed without processing additives.

8. A method in accordance with claim 1, wherein the operation of mixing is performed using non-iron containing apparatus.

9. A method in accordance with claim 1, wherein the operation of mixing is performed using a ceramic mixing apparatus.

10. A method in accordance with claim 1, wherein the operation of mixing is performed using a mixing apparatus having at least one ceramic surface in contact with one or more of the activated carbon, the binder and the mixture during mixing.

11. A method in accordance with claim 1, wherein the operation of mixing is performed using a mixing apparatus having at least one non-iron containing surface in contact with one or more of the activated carbon, the binder and the mixture during mixing.

12. An electrode comprising:

a current collector; and

a film of active electrode material attached to the current collector, wherein the active electrode material has an iron content in the range of about 0 and about 20 ppm.

13. The electrode of claim 12, wherein the active electrode material includes activated carbon and a binder, wherein the activated carbon is in an amount of between about 80 and about 97 percent by weight, and wherein the binder is in an amount of between about 3 and about 20 percent by weight.

14. The electrode of claim 12, wherein the active electrode material is formed from a mixture of activated carbon and binder, the mixture formed through mixing with one or more of a non-iron containing apparatus and a ceramic mixing apparatus.

15. The electrode of claim 12, wherein the active electrode material is formed from a mixture of activated carbon and binder, the mixture formed through mixing with a mixing device having one or more of at least one ceramic surface and at least one non-iron containing surface in contact with one or more of the activated carbon, the binder and the mixture during mixing.

16. An electrode comprising:

a current collector; and

a film of active electrode material attached to the current collector, the active electrode material including a mixture of carbon and binder, the mixture formed through mixing in an environment having at least one non-iron introducing source in contact with one or more of the carbon, the binder and the mixture during mixing.

17. An electrode according to claim 16 wherein the at least one non-iron introducing source is a ceramic surface in a mixing apparatus.

18. An electrode according to claim 16 wherein the film of active electrode material has an iron content of about equal to or less than about 20 ppm.

19. An electrochemical double layer capacitor comprising:

a first electrode comprising a first current collector and a first film of active electrode material, the first film comprising a first surface and a second surface, the first current collector being attached to the first surface of the first film;

a second electrode comprising a second current collector and a second film of active electrode material, the second film comprising a third surface and a fourth surface, the second current collector being attached to the third surface of the second film;

a porous separator disposed between the second surface of the first film and the fourth surface of the second film;

a container;

an electrolyte;

wherein;

the first electrode, the second electrode, the porous separator, and the electrolyte are disposed in the container;

the first film is at least partially immersed in the electrolyte;

the second film is at least partially immersed in the electrolyte;

the porous separator is at least partially immersed in the electrolyte;

each of the first and second films include a mixture of carbon and binder with a resulting iron content of about equal to or not exceeding about 20 parts per million.

20. The capacitor of claim 19, wherein the films are attached to respective collectors via a conductive adhesive layer.

21. Processing equipment for providing active electrode material, the processing equipment including:

a non-iron chamber for receiving mixing components of active electrode material; and

,

apparatus for mixing the components of the active electrode material.

22. Processing equipment according to claim 21 wherein the non-iron chamber is defined by a ceramic lining.

23. Processing equipment according to claim 21 wherein the apparatus for mixing is defined by one of a blender and a mill.

24. Processing equipment according to claim 21 wherein the apparatus for mixing includes a ceramic surface.

25. Processing equipment according to claim 21 wherein the apparatus for mixing includes apparatus for introducing one or more of high shear and high impact forces to the components of the active electrode material.

26. Processing equipment according to claim 21 wherein the apparatus for mixing includes a mill apparatus for introducing one or more of high shear and high impact forces to the components of the active electrode material, wherein the mill has a ceramic lining.

27. Processing equipment according to claim 21 wherein the apparatus for mixing includes one or more of a ball mill, an electromagnetic ball mill, a disk mill, a pin mill, a high-energy impact mill, a fluid energy impact mill, an opposing nozzle jet mill, a fluidized bed jet mill, a hammer mill, a fritz mill, a Warring blender, a roll mill, a mechanofusion processor, a Hosokawa AMS, or an impact mill.

28. Processing equipment according to claim 27 wherein the apparatus for mixing includes a ceramic chamber.

29. Processing equipment according to claim 21 wherein the apparatus for mixing includes a jet mill.

30. Processing equipment according to claim 21 wherein the apparatus for mixing includes a jet mill with ceramic chamber.