RECHARGEABLE LITHIUM BATTERY

• US 20090068565A1
• Filed: 09/11/2008
• Published: 03/12/2009
• Est. Priority Date: 09/12/2007
• Status: Active Grant

• Current Assignee: Samsung SDI Company Limited
• Original Assignee: Samsung SDI Company Limited
• Inventors: LEE, Doo-Kyoung
• Granted Patent: US 8,557,447 B2
• Time in Patent Office: Days
• US Class Current: 429/331
• CPC Class Codes: H01M 10/0567 characterised by the additives
• CPC Class Codes: H01M 10/0568 characterised by the solutes
• CPC Class Codes: H01M 10/0569 characterised by the solvents
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

The rechargeable lithium battery includes: a negative electrode including a non-carbon-based negative active material; a positive electrode including a positive active material that reversibly intercalates and deintercalates lithium ions; and an electrolyte that includes a non-aqueous organic solvent that includes ethylene carbonate in an amount of 20 volume % or less, a lithium salt including LiPF₆, a first additive represented by the following Formula 1 and a second additive that is LiB(C₂O₄)₂. The electrolyte has a viscosity of 3.02 cP or less:

• • wherein, R₁ and R₂ are independently selected from the group consisting of hydrogen, a halogen, a cyano (CN), a nitro (NO₂), and a C1 to C5 fluoroalkyl, provided that at least one of R₁ and R₂ is selected from the group consisting of a halogen, a cyano (CN), a nitro (NO₂), and a C1 to C5 fluoroalkyl.

Claims

1. A rechargeable lithium battery comprising:

a negative electrode including a non-carbon-based negative active material;

a positive electrode including a positive active material that reversibly intercalates and deintercalates lithium ions; and

an electrolyte that includes a non-aqueous organic solvent that includes ethylene carbonate in an amount of 20 volume % or less based on a total volume of the non-aqueous organic solvent, a lithium salt including LiPF₆, a first additive represented by the following Formula 1 and a second additive that is LiB(C₂O₄)₂,

wherein the electrolyte has a viscosity of 3.02 cP or less;

wherein, in the above Formula 1, R₁ and R₂ are independently selected from the group consisting of hydrogen, a halogen, a cyano (CN), a nitro (NO₂), and a C1 to C5 fluoroalkyl, provided that at least one of R₁ and R₂ is selected from the group consisting of a halogen, a cyano (CN), a nitro (NO₂), and a C1 to C5 fluoroalkyl.

2. The rechargeable lithium battery of claim 1, wherein the ethylene carbonate is present in an amount of 5 to 20 volume %.

3. The rechargeable lithium battery of claim 2, wherein the non-aqueous organic solvent further includes, in addition to the ethylene carbonate, an ether-based, carbonate-based, ester-based, ketone-based, alcohol-based, or aprotic solvent.

4. The rechargeable lithium battery of claim 2, wherein the non-aqueous organic solvent further includes, in addition to the ethylene carbonate, at least one solvent selected from the group consisting of dimethoxyethane (DME), bis(2-methoxyethyl)ether (DGM), triethylene glycol dimethylether (TEGDME), tetraethylene glycol dimethylether (TetGM), polyethylene glycol dimethylether (PEGDME), propylene glycol dimethylether (PGDME), dioxolane, dimethyl carbonate (DMC), diethyl carbonate (DEC), dipropyl carbonate (DPC), methylpropyl carbonate (MPC), ethylpropyl carbonate (EPC), methylethyl carbonate (MEC), ethylmethyl carbonate (EMC), propylene carbonate (PC), butylene carbonate (BC), methyl acetate, ethyl acetate, n-propyl acetate, methylpropionate, ethylpropionate, γ

-butyrolactone, decanolide, valerolactone, mevalonolactone, caprolactone, cyclohexanone and ethanol, isopropyl alcohol, a nitrile of the formula X—

CN, wherein X is a C2 to C20 linear, branched, or cyclic hydrocarbon group including a double bond, an aromatic ring, or an ether bond, dimethylformamide, 1,3-dioxolane and sulfolanes.

5. The rechargeable lithium battery of claim 2, wherein the non-aqueous organic solvent further includes ethyl methyl carbonate.

6. The rechargeable lithium battery of claim 1, wherein the first additive is selected from the group consisting of fluoroethylene carbonate, difluoroethylene carbonate, chloroethylene carbonate, dichloroethylene carbonate, bromoethylene carbonate, dibromoethylene carbonate, nitroethylene carbonate, cyanoethylene carbonate, and combinations thereof.

7. The rechargeable lithium battery of claim 1, wherein the first additive is present in an amount of 0.1 to 10 parts by weight based on 100 parts by weight of the electrolyte.

8. The rechargeable lithium battery of claim 7, wherein the first additive is present in an amount of 1 to 8 parts by weight based on 100 parts by weight of the electrolyte.

9. The rechargeable lithium battery of claim 1, wherein LiPF₆ is present at a concentration of 1.15 to 2.5M.

10. The rechargeable lithium battery of claim 1, wherein LiPF₆ is present at a concentration of 1.3 to 2.0M.

11. The rechargeable lithium battery of claim 1, wherein the electrolyte has a viscosity of 0.5 to 3.0 cP.

12. The rechargeable lithium battery of claim 1, wherein the second additive is present in an amount of 0.1 to 5 parts by weight based on 100 parts by weight of the electrolyte.

13. The rechargeable lithium battery of claim 1, wherein the second additive is present in an amount of 0.2 to 3 parts by weight based on 100 parts by weight of the electrolyte.

14. The rechargeable lithium battery of claim 1, wherein the non-carbon-based negative electrode comprises at least one selected from the group consisting of Si, silicon oxide (SiO_x, 0<

x<

2), Si-M (M is at least one metal selected from the group consisting of Al, Sn, Ag, Fe, Bi, Mg, Zn, In, Ge, Pb, and Ti), SnO₂, Sn, and combinations thereof.

15. The rechargeable lithium battery of claim 1, wherein the non-carbon-based negative electrode comprises Si powder or silicon oxide.