METHOD FOR PREPARING POLYOLEFINS CONTAINING A HIGH PERCENTAGE OF EXO-OLEFIN CHAIN ENDS
First Claim
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1. A method for preparing a polyolefin product containing exo-olefinic end groups on the polymer chain, comprising:
- (a) ionizing a polyolefin containing terminal tert-chloride chain ends on the polymer chain in the presence of a Lewis acid; and
(b) reacting the ionized polyolefin with;
(i) one or more pyrroles of formula I
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Abstract
The present invention is directed to a method for preparing polyolefins containing a high percentage of exo-olefin chain ends. The method involves ionizing a polyolefin containing tert-chloride chain ends and reacting the ionized polyolefin with one or more nitrogen-containing five-membered aromatic ring or one or more hindered secondary or tertiary amines, or mixtures thereof.
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Citations
37 Claims
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1. A method for preparing a polyolefin product containing exo-olefinic end groups on the polymer chain, comprising:
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(a) ionizing a polyolefin containing terminal tert-chloride chain ends on the polymer chain in the presence of a Lewis acid; and (b) reacting the ionized polyolefin with; (i) one or more pyrroles of formula I - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33)
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34. A method for preparing a polyolefin product containing exo-olefinic end groups on the polymer chain, comprising:
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(a) ionizing a polyolefin containing terminal tert-chloride chain ends on the polymer chain in the presence of a Lewis acid; and (b) reacting the ionized polyolefin with; (i) one or more pyrroles of formula I - View Dependent Claims (35, 36, 37)
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Specification