POLYMERIZATION OF ISOPRENE FROM RENEWABLE RESOURCES
First Claim
1. A system for producing a copolymer of isoprene comprising:
- (a) an isoprene starting composition derived from renewable resources; and
(b) a polymer produced from at least a portion of the isoprene starting material;
wherein at least a portion of the isoprene starting composition undergoes polymerization with another non-isoprene molecule to produce a copolymer.
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Abstract
The invention features compositions and methods for producing polymers of isoprene derived from renewable resources such as isoprene produced from cultured cells that use renewable carbon sources. A starting isoprene composition, such as a bioisoprene composition, is distinguished from petroleum based isoprene by the purity profile (such as lower levels of certain C5 hydrocarbons other than isoprene, presence of certain compounds associated with the biological process for production) and the relative content of the carbon isotopes. Polymers obtained by polymerization of such starting isoprene composition according to this invention, such as a polyisoprene homopolymer or a copolymer having repeat units that are derived from isoprene, are distinguishable from isoprene containing polymers from petrochemical resources. The present invention more specifically discloses a polyisoprene polymer which is comprised of repeat units that are derived from isoprene monomer, wherein the polyisoprene polymer has δ13C value of greater than −22‰. This type of polyisoprene can be a cis-1,4-polyisoprene homopolymer rubber. Also provided are methods for verifying that a polyisoprene homopolymer or a copolymer having repeat units that are derived from isoprene contains isoprene that is from a sustainable renewable non-petroleum derived source.
33 Citations
18 Claims
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1. A system for producing a copolymer of isoprene comprising:
- (a) an isoprene starting composition derived from renewable resources; and
(b) a polymer produced from at least a portion of the isoprene starting material;
wherein at least a portion of the isoprene starting composition undergoes polymerization with another non-isoprene molecule to produce a copolymer. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11)
- (a) an isoprene starting composition derived from renewable resources; and
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12. A system for producing a polymer of isoprene comprising:
- (a) an isoprene starting composition derived from renewable resources; and
(b) a polymer produced from at least a portion of the isoprene starting material;
wherein at least a portion of the isoprene starting composition undergoes polymerization with other isoprene molecules to produce a polymer of isoprene with a molecular weight of about 5,000 to about 100,000.
- (a) an isoprene starting composition derived from renewable resources; and
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13. A method for producing a copolymer of isoprene derived from renewable resources comprising:
- (a) culturing cells comprising a heterologous nucleic acid encoding an isoprene synthase polypeptide under suitable culture conditions for the production of the isoprene;
(b) producing the isoprene; and
(c) polymerizing the isoprene derived from renewable resources with another non-isoprene molecules to produce a copolymer. - View Dependent Claims (14, 15, 17)
- (a) culturing cells comprising a heterologous nucleic acid encoding an isoprene synthase polypeptide under suitable culture conditions for the production of the isoprene;
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16. A method for producing a polymer of isoprene derived from renewable resources comprising:
- (a) culturing cells comprising a heterologous nucleic acid encoding an isoprene synthase polypeptide under suitable culture conditions for the production of the isoprene;
(b) producing the isoprene; and
(c) polymerizing the isoprene derived from renewable resources with other isoprene molecules to produce a polymer of isoprene with a molecular weight of about 5,000 to about 100,000. - View Dependent Claims (18)
- (a) culturing cells comprising a heterologous nucleic acid encoding an isoprene synthase polypeptide under suitable culture conditions for the production of the isoprene;
Specification