Thermoplastic Fiber Material Spun from a Raw Material Containing Polyhydroxyether, Methods for Its Production and Uses for It

• US 20110298152A1
• Filed: 08/15/2011
• Published: 12/08/2011
• Est. Priority Date: 03/22/2005
• Status: Active Grant

• Current Assignee: Ems-Chemie AG (Emesta Holding AG)
• Original Assignee: Ems-Chemie AG (Emesta Holding AG)
• Inventors: Sutter, Simon, Spindler, Jürgen
• Granted Patent: US 8,409,486 B2
• Time in Patent Office: Days
• US Class Current: 264/258
• CPC Class Codes: D01D 5/08 Melt spinning methods D01D5/0023 takes precedence
• CPC Class Codes: D01F 6/66 from polyethers
• CPC Class Codes: Y10T 428/2913 Rod, strand, filament or fiber
• CPC Class Codes: Y10T 442/3976 Including strand which is stated to have specific attributes [e.g., heat or fire resistance, chemical or solvent resistance, high absorption for aqueous composition, water solubility, heat shrinkability, etc.]

Abstract

The invention describes a new synthetic fiber material of polyhydroxyether, as well as a melt-spinning method for its production. The new material can be used, in particular, for stabilization of the reinforcement fibers of high-performance fiber composite materials before they are embedded in the matrix material. During this usage, the polyhydroxyether fiber material dissolves at a temperature above its glass transition temperature entirely in the matrix material, so that the reinforcement fibers can be arranged largely free of kinking. In addition, it forms cross-links with the matrix material to form a homogeneous matrix and thus does not constitute a disruptive third phase in the composite material. The compatibility of the matrix and reinforcement fiber is also improved. It was possible to improve the bending strength of test slabs by 12% as compared to that of reference slabs with polyester filament.

Claims

1-24. -24. (canceled)

25. A method for making structural parts with reinforcement fibers embedded in a matrix material consisting of a cross-linkable resin system, comprising the steps:

a) providing the reinforcement fibers and a thermoplastic fiber material;

b) securing the reinforcement fibers with the thermoplastic fiber material in a defined geometrical arrangement to form a preform, wherein the thermoplastic fiber material is spun from a raw material containing polyhydroxyether as a single polymer, and wherein the polyhydroxyether has an essential amorphous structure, a molecular weight Mw of 10,000 to 80,000 Dalton, and a glass transition temperature Tg of no more than 100°

C.;

c) embedding the reinforcement fibers and the thermoplastic fiber material in the matrix material by injection of the matrix material into the preform; and

d) hardening the cross-linkable resin system, causing the thermoplastic fiber material to dissolve in the matrix material.

26. The method of claim 25, wherein the reinforcement fibers are secured with a thread made from the thermoplastic fiber material by embroidery, sewing or weaving techniques.

27. The method of claim 25, wherein the reinforcement fibers are secured with a two-dimensional textile form made from the thermoplastic fiber material.

28. The method of claim 25, wherein the reinforcement fibers are secured by at least partly melting the thermoplastic fiber material at a temperature above its softening point.

29. The method of claim 25, wherein the cross-linkable resin system is hardened at a temperature higher than the glass transition temperature Tg of the polyhydroxyether used in the thermoplastic fiber material.

30. The method of claim 25, wherein the reinforcement fibers consist of glass, carbon, aramide, polybenzoxazole, polybenzimidazole and/or other so-called “

rigid rod”

polymers.

31. The method of claim 25, wherein the cross-linkable resin system is at least one of epoxy resin, unsaturated polyester resin, isocyanate ester resin, phenol resin, phenol-formaldehyde resin and melamine resin.

32. The method of claim 25, wherein the cross-linkable resin system contains at least one of the following cross-linking components:

a polyisocyanate;

a carboxylic acid;

an anhydride, especially a cyclical anhydride;

a phenol resin, especially a butylated phenol resin;

a melamine resin, especially a methylated melamine resin;

a cyclical oxide resin and catalytic quantities of a strong acid.

33. The method of claim 25, wherein the polyhydroxyether has a molecular weight Mw of 20,000 to 60,000 Dalton.

34. The method of claim 25, wherein the polyhydroxyether has a molecular weight Mw between 30,000 and 55,000 Dalton.

35. The method of claim 25, wherein the polyhydroxyether has a glass transition temperature Tg less than 95°

C.

36. The method of claim 25, wherein the polyhydroxyether has a glass transition temperature Tg less than 90°

C.

37. The method of claim 25, wherein the polyhydroxyether is chemically modified by grafting of short polycaprolactone side chains, in order to lowers its glass transition temperature Tg to a value between 30 and 80°

C.

38. The method of claim 25, wherein the thermoplastic fiber material has a breaking strength greater than 5 cN/tex.

39. The method of claim 25, wherein the thermoplastic fiber material is or contains a monofilament with a titer of 100 to 3000 dtex.

40. The method of claim 25, wherein the thermoplastic fiber material is or contains a multifilament with a plurality of single filaments with an overall titer of 100 to 1000 dtex.

41. The method of claim 25, wherein the thermoplastic fiber material is or contains a multifilament with 10 to 120 single filaments.

42. The method of claim 25, wherein the thermoplastic fiber material is or contains a staple fiber.

43. The method of claim 25, wherein the thermoplastic fiber material is processed from staple fiber into ring yarn, compact yarn, rotor yarn or carded yarn.

44. The method of claim 25, wherein the thermoplastic fiber material is processed into a two-dimensional textile form, such as a woven or knitted form, a fleece, a felt, or a scrim.