Redox Polymers
First Claim
1. An electrochemical sensor comprising:
- a working electrode and a counter electrode, wherein the working electrode comprises a polymeric transition metal complex, the polymeric transition metal complex comprising;
a transition metal complex;
a polymer backbone; and
at least one spacer covalently coupled to the polymer backbone, the at least one spacer comprising at least one non-cyclic functional group selected from the group consisting of —
(CRrRs)—
, —
O—
, —
S—
, —
C(O)O—
, —
S(O)2NRk—
, —
OC(O)NRm—
, —
OC(S)NRn, —
C(O)NRt—
, —
CRv═
N—
O—
, —
CRw═
NNRx—
, and —
(SiRyRz)—
, and wherein Rr and Rs are independently hydrogen, chlorine, fluorine, or substituted or unsubstituted alkyl, alkoxy, alkenyl, or alkynyl, and Rk, Rm, Rn, Rt, Ru, Rv, Rw, Rx, Ry, and Rz are independently hydrogen or substituted or unsubstituted alkyl,wherein the transition metal complex is covalently coupled to the spacer.
2 Assignments
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Accused Products
Abstract
Novel transition metal complexes of iron, cobalt, ruthenium, osmium, and vanadium are described. The transition metal complexes can be used as redox mediators in enzyme based electrochemical sensors. In such instances, transition metal complexes accept electrons from, or transfer electrons to, enzymes at a high rate and also exchange electrons rapidly with the sensor. The transition metal complexes include at least one substituted or unsubstituted biimidazole ligand and may further include a second substituted or unsubstituted biimidazole ligand or a substituted or unsubstituted bipyridine or pyridylimidazole ligand. Transition metal complexes attached to polymeric backbones are also described.
0 Citations
16 Claims
-
1. An electrochemical sensor comprising:
a working electrode and a counter electrode, wherein the working electrode comprises a polymeric transition metal complex, the polymeric transition metal complex comprising; a transition metal complex; a polymer backbone; and at least one spacer covalently coupled to the polymer backbone, the at least one spacer comprising at least one non-cyclic functional group selected from the group consisting of —
(CRrRs)—
, —
O—
, —
S—
, —
C(O)O—
, —
S(O)2NRk—
, —
OC(O)NRm—
, —
OC(S)NRn, —
C(O)NRt—
, —
CRv═
N—
O—
, —
CRw═
NNRx—
, and —
(SiRyRz)—
, and wherein Rr and Rs are independently hydrogen, chlorine, fluorine, or substituted or unsubstituted alkyl, alkoxy, alkenyl, or alkynyl, and Rk, Rm, Rn, Rt, Ru, Rv, Rw, Rx, Ry, and Rz are independently hydrogen or substituted or unsubstituted alkyl,wherein the transition metal complex is covalently coupled to the spacer. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16)
Specification