POLYMER NANO-COMPOSITES AS DRY SENSOR MATERIAL FOR BIOSIGNAL SENSING

• US 20140066740A1
• Filed: 11/11/2013
• Published: 03/06/2014
• Est. Priority Date: 02/23/2010
• Status: Active Grant

• Current Assignee: Cleveland Medical Polymers, Inc.
• Original Assignee: Cleveland Medical Polymers, Inc.
• Inventors: Taranekar, Prasad, Venkatesan, Arunkumar, Negandhi, Nishant, Banerjie, Asis
• Granted Patent: US 9,591,979 B2
• Time in Patent Office: Days
• US Class Current: 600/388
• CPC Class Codes: A61B 2562/06 Arrangements of multiple sensors of different types
• CPC Class Codes: A61B 5/25 Bioelectric electrodes therefor
• CPC Class Codes: A61B 5/268 containing conductive polymers, e.g. PEDOT:PSS polymers
• CPC Class Codes: A61B 5/28 for electrocardiography [ECG]
• CPC Class Codes: A61B 5/6804 Garments; Clothes
• CPC Class Codes: A61B 5/6891 Furniture
• CPC Class Codes: H01B 1/24 the conductive material comprising carbon-silicon compounds, carbon or silicon

Abstract

The multifunctional polymer nano-composite sensor system for detecting various biosignals, such as EKG, includes (1) a polymer nano-composite sensor material that is flexible, elastic, soft, and conductive, (2) a sensor material fabricated into a desired shape or form, and (3) a signal capturing interface for collecting, transmitting and processing the signals. The present invention more specifically reveals a multi-functional nano-composite sensor for detecting biologically generated electrical signals which is comprised of a polymeric composition having an electrically conductive wire embedded therein, wherein the polymeric composition has a dispersion phase and a dispersed phase, wherein the dispersion phase is comprised of a thermoplastic polymer or a thermoset polymer, wherein the dispersed phase includes an electrically conductive filler, wherein the polymeric composition is gel-free, and wherein the electrically conductive wire is adapted for conveying an electrical signal to a signal processing device.

Claims

1. A multi-functional nano-composite sensor for detecting biologically generated electrical signals in the absence of conductive gels which is comprised of a polymeric composition having an electrically conductive sensor interface embedded therein, wherein the polymeric composition has a dispersion phase and a dispersed phase, wherein the dispersion phase is comprised of an elastomeric polymer matrix, wherein the dispersed phase includes at least one electrically conductive filler, and wherein the electrically conductive sensor interface is adapted for conveying an electrical signal to a signal processing device.

2. The multi-functional nano-composite sensor as specified in claim 1 wherein the sensor is adapted for detecting and measuring bio-signals from a human body.

3. The multi-functional nano-composite sensor as specified in claim 1 wherein the sensor is integrated into a woven fabric, a non-woven fabric, a foam structure, a sheet, or a fiber.

4. The multi-functional nano-composite sensor as specified in claim 2 wherein the sensor is integrated into a chair, a bed, an article of clothing or a handgrip.

5. The multi-functional nano-composite sensor as specified in claim 1 wherein the elastomeric polymer matrix is selected from the group consisting of polyesters, polyamides, polyacrylates, polyurethanes, polyolefins, styrenic polymers, silicone rubbers and nitrile rubbers;

and wherein the electrically conductive filler is selected from the group consisting of multiwall carbon nanotubes, single wall carbon nanotubes, single multiwall nanotubes, carbon nanofibers, graphenes, metal nanoparticles, metal coated carbon fibers, and metal coated organic fillers, metal coated inorganic fillers, nano-particle coated organic fillers, and nano-particle coated inorganic fillers.

6. The multi-functional nano-composite sensor as specified in claim 1 wherein the elastomeric polymer matrix is a blend of thermoplastic polyurethanes and styrenic rubbers.

7. The multi-functional nano-composite sensor as specified in claim 5 wherein the electrically conductive filler is present in the composition at a level of 0.5 weight percent to 40 weight percent based on the total weight of the composition.

8. The multi-functional nano-composite sensor as specified in claim 5 wherein the metal nanoparticle is selected from the group consisting of gold nanoparticles, silver nanoparticles, tungsten nanoparticles, and copper nanoparticles.

9. The multi-functional nano-composite sensor as specified in claim 5 wherein the electrically conductive filler is selected from the group consisting of metal decorated multiwall carbon nanotubes, metal decorated single wall carbon nanotubes, metal decorated single multiwall nanotubes, metal decorated carbon nanofibers, and metal decorated graphenes.

10. The multi-functional nano-composite sensor as specified in claim 5 wherein the electrically conductive filler is present in the composition at a level of 3 weight percent to 20 weight percent based on the total weight of the composition.

11. The multi-functional nano-composite sensor as specified in claim 5 wherein the electrically conductive filler is a mixture which is comprised of 0.5 weight percent to 10 weight percent multiwall carbon nanotubes and 1 weight percent to 20 weight percent carbon black, based on the total weight of the composition.

12. The multi-functional nano-composite sensor as specified in claim 1 wherein the conductive sensor interface is selected from the group consisting of an electrically conductive wire, an electrically conductive snap connector, and an electrically conductive pin.

13. The multi-functional nano-composite sensor as specified in claim 1 wherein the polymeric composition is comprised of a polyester based thermoplastic polyurethane, a styrenic polymer, and at least one electrically conductive filler, wherein the styrenic polymer is present in the composition at a level which is within the range of 10 weight percent to 50 weight percent and wherein the electrically conductive filler is present at a level which is within the range of 0.5 weight percent to 40 weight percent, based on the total weight of the polymeric composition.

14. The multi-functional nano-composite sensor as specified in claim 13 wherein the styrenic polymer is selected from the group consisting of styrene ethylene butadiene styrene block copolymers, styrene isoprene butadiene styrene block copolymers, styrene butadiene styrene block copolymers, styrene isoprene styrene block copolymers, and styrene ethylene propylene styrene block copolymers.

15. The multi-functional nano-composite sensor as specified in claim 1 wherein the polymeric composition is comprised of a thermoplastic polyurethane, a styrenic polymer, and at least one electrically conductive filler, wherein the styrenic polymer is present in the composition at a level which is within the range of 10 weight percent to 50 weight percent and wherein the electrically conductive filler is present at a level which is within the range of 0.5 weight percent to 40 weight percent, based on the total weight of the polymeric composition, wherein the electrically conductive filler is a mixture which is comprised of 0.5 weight percent to 10 weight percent carbon nanotubes and 1 weight percent to 20 weight percent carbon black, based on the total weight of the composition.

16. The multi-functional nano-composite sensor as specified in claim 1 wherein the polymeric composition is comprised of a thermoplastic polyurethane, a styrenic polymer, and at least one electrically conductive filler, wherein the styrenic polymer is present in the composition at a level which is within the range of 10 weight percent to 50 weight percent and wherein the electrically conductive filler is present at a level which is within the range of 0.5 weight percent to 40 weight percent, based on the total weight of the polymeric composition, wherein the electrically conductive filler is a mixture which is comprised of 0.5 weight percent to 10 weight percent multiwall carbon nanotubes and 1 weight percent to 20 weight percent carbon black, based on the total weight of the composition.

17. The multi-functional nano-composite sensor as specified in claim 1 wherein the polymeric composition is comprised of a thermoplastic polyurethane, a styrenic polymer, and at least one electrically conductive filler, wherein the styrenic polymer is present in the composition at a level which is within the range of 10 weight percent to 50 weight percent and wherein the electrically conductive filler is present at a level which is within the range of 0.5 weight percent to 40 weight percent, based on the total weight of the polymeric composition, wherein the electrically conductive filler is a mixture of carbon nanotubes and at least one conductive additive selected from the group consisting of carbon black powder, carbon fibers, carbon nanofibers, graphites, graphite fibers, metal nanoparticles, metal coated carbon fibers, and metal or nano-particle coated organic and inorganic fillers.

18. A sensor system which is comprised of the multi-functional nano-composite sensor as specified in claim 12 and a signal processing device including an electronic circuit which is in electrical communication with at least one electrical component selected from the group consisting of an electronic circuit consisting of amplifiers, filters and capacitors, or an embedded micro-processor that uses a form of the aforesaid electronic components.

19. The sensor system as specified in claim 18 which is further comprised of at least one module for bio-signal capturing, processing, transmission, reception, data acquisition, storage and processing for an end-use application.

20. A method for monitoring the cardiovascular system of a patient for a prolonged period of time which comprises (1) the patient donning an article of clothing having integrated therein at least one multifunctional nano-composite sensor as specified in claim 1, (2) connecting the multifunctional nano-composite sensor to a signal processing device which is adapted for monitoring the cardiovascular system of a human being, and (3) monitoring the cardiovascular system of the patient.