EXTRACTION OF HYDROCARBONS FROM HYDROCARBON-CONTAINING MATERIALS AND/OR PROCESSING OF HYDROCARBON-CONTAINING MATERIALS
First Claim
1. A method for increasing recovery of hydrocarbon-containing organic matter from a production well coupled to a hydrocarbon-containing sub-surface formation, the subsurface formation comprising hydrocarbon-containing material, the method comprising the steps of extracting the hydrocarbon-containing organic matter by a process comprising:
- providing an injection well, said injection being in fluid communication with the sub-surface formation;
providing a substantially surfactant-free first liquid comprising non-aqueous hydrocarbon-extracting turpentine liquid;
injecting the non-aqueous hydrocarbon-extracting turpentine liquid through the injection well and into the formation, wherein the non-aqueous hydrocarbon-extracting turpentine liquid and the hydrocarbon-containing organic matter from the hydrocarbon containing sub-surface formation form an extraction mixture comprising at least a portion of the hydrocarbon-containing organic matter extracted into the non-aqueous hydrocarbon-extracting turpentine liquid;
recovering the extraction mixture from the formation through the production well; and
separating the extraction mixture to produce a hydrocarbon product stream and a hydrocarbon-extracting liquid stream.
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Abstract
A method of extracting hydrocarbon-containing organic matter from a hydrocarbon-containing material includes the steps of providing a first liquid comprising a turpentine liquid; contacting the hydrocarbon-containing material with the turpentine liquid to form an extraction mixture; extracting the hydrocarbon material into the turpentine liquid; and separating the extracted hydrocarbon material from a residual material not extracted.
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21 Claims
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1. A method for increasing recovery of hydrocarbon-containing organic matter from a production well coupled to a hydrocarbon-containing sub-surface formation, the subsurface formation comprising hydrocarbon-containing material, the method comprising the steps of extracting the hydrocarbon-containing organic matter by a process comprising:
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providing an injection well, said injection being in fluid communication with the sub-surface formation; providing a substantially surfactant-free first liquid comprising non-aqueous hydrocarbon-extracting turpentine liquid; injecting the non-aqueous hydrocarbon-extracting turpentine liquid through the injection well and into the formation, wherein the non-aqueous hydrocarbon-extracting turpentine liquid and the hydrocarbon-containing organic matter from the hydrocarbon containing sub-surface formation form an extraction mixture comprising at least a portion of the hydrocarbon-containing organic matter extracted into the non-aqueous hydrocarbon-extracting turpentine liquid; recovering the extraction mixture from the formation through the production well; and separating the extraction mixture to produce a hydrocarbon product stream and a hydrocarbon-extracting liquid stream. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 15, 16, 18, 20)
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14. A method of modifying sulfur compounds in a sulfur-containing hydrocarbon-containing material from a natural geological formation comprising the steps of:
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providing a substantially surfactant-free first liquid comprising a non-aqueous liquid consisting essentially of a turpentine liquid selected from the group consisting of natural turpentine, synthetic turpentine, mineral turpentine, pine oil, α
-pinene, β
-pinene, α
-terpineol, β
-terpineol, γ
-terpineol, terpene resins, α
-terpene, β
-terpene, γ
-terpene, geraniol, 3-carene, dipentene (p-mentha-1,8-diene), nopol, pinane, 2-pinane hydroperoxide, terpin hydrate, 2-pinanol, dihydromycenol, isoborneol, p-menthan-8-ol, α
-terpinyl acetate, citronellol, p-menthan-8-yl acetate, 7-hydroxydihydrocitronellal, menthol, anethole, camphene;
p-cymene, anisaldeyde, 3,7-dimethyl-1,6-octadiene, isobornyl acetate, ocimene, alloocimene, alloocimene alcohols, 2-methoxy-2,6-dimethyl-7,8-epoxyoctane, camphor, citral, 7-methoxydihydro-citronellal, 10-camphorsulphonic acid, cintronellal, menthone, and mixtures thereof, andcontacting the sulfur-containing hydrocarbon-containing material from a natural geological formation with said non-aqueous liquid so as to interact with sulfur in said sulfur-containing hydrocarbon-containing material from a natural geological formation and thereby modify said sulfur-containing hydrocarbon-containing material from a natural geological formation; wherein said sulfur-containing hydrocarbon-containing material from a natural geological formation is selected from the group consisting of natural gas, petroleum gas, crude oil, tar sands, oil shale, and coal.
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17. A composition consisting essentially of a hydrocarbon-extracting effective amount of α
- -terpineol, β
-terpineol, β
-pinene, α
-pinene, pine oil, p-cymene, or a combination thereof. - View Dependent Claims (19, 21)
- -terpineol, β
Specification