COMPOSITE MATERIAL INCLUDING A THERMOPLASTIC POLYMER, A PEST FOOD MATERIAL AND A PESTICIDE

• US 20150305326A1
• Filed: 07/02/2015
• Published: 10/29/2015
• Est. Priority Date: 12/21/2006
• Status: Active Grant

• Current Assignee: Corteva Agriscience LLC (Corteva, Inc.)
• Original Assignee: Dow Agrosciences LLC (Corteva, Inc.)
• Inventors: Hill, Robert L., King, James E., DeMark, Joseph J., Arnoldy, Anton, Tolley, Mike P., Williams, Donald E. III, Eger, Joseph E. Jr.
• Granted Patent: US 9,775,341 B2
• Time in Patent Office: Days
• US Class Current: 1/1
• CPC Class Codes: A01M 1/02 with devices or substances, e.g. food, pheronones attracting the insects
• CPC Class Codes: A01M 1/026 combined with devices for monitoring insect presence, e.g. termites bait stations A01M1/2005; detecting other animals in a given area A01M31/002
• CPC Class Codes: A01M 1/2011 for crawling insects
• CPC Class Codes: A01N 25/006 insecticidal
• CPC Class Codes: A01N 25/10 Macromolecular compounds
• CPC Class Codes: A01N 43/56 1,2-Diazoles; Hydrogenated 1,2-diazoles
• CPC Class Codes: A01N 45/02 having three carbocyclic rings
• CPC Class Codes: A01N 47/02 the carbon atom having no bond to a nitrogen atom
• CPC Class Codes: A01N 47/34 containing the groups , e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products

Abstract

Composite materials that are palatable to a wood-destroying pest species and also pesticidal to the pest species can be used in pest control devices and can be used as wood substitutes for structural components, which are resistant to destruction by wood-destroying pests. The composite materials include a thermoplastic polymer, a food material for the pest and a pesticide. The composite material is formed by mixing a thermoplastic polymer, wood fragments or other cellulosic materials and a quantity of pesticide, and thereafter creating a molten material within a mixer, compounder, extruder or the like. The molten material is extruded or molded to form the desired shape.

Claims

1-25. -25. (canceled)

26. A composite material for use in pest control, the composite material comprising:

a plastic structural matrix that comprises cellulose acetate butyrate (CAB);

a cellulosic food material that is palatable to a pest; and

a pesticide that is toxic to the pest.

27. The composite material of claim 26 wherein the CAB is selected from the group consisting of CAB having a degree of polymerization from about 50 units to about 400 units, CAB having a degree of polymerization from about 100 units to about 300 units, CAB having a degree of polymerization of about 160 units, and a combination thereof.

28. The composite material of claim 26 wherein the CAB comprises (a) a mixture of CAB having from about 50 monomer units to about 75 monomer units and CAB having from about 150 to about 300 monomer units, (b) a mixture of CAB having about 60 monomer units and CAB having about 300 monomer units, or (c) a mixture of CAB having about 64 monomer units and CAB having about 160 monomer units.

29. The composite material of claim 26 wherein the CAB comprises a mixture of CAB having a molecular weight of about 16,000 and CAB having a molecular weight of about 40,000.

30. The composite material of claim 26 wherein the plastic structural matrix further comprises at least one additional thermoplastic polymer.

31. The composite material of claim 30 wherein the at least one additional thermoplastic polymer is selected from the group consisting of cellulose acetate, cellulose acetate propionate, polylactic acid, and a combination thereof.

32. The composite material of claim 26 wherein the plastic structural matrix comprises from about 5% to about 50% by weight of the composite material.

33. The composite material of claim 26 wherein the cellulosic food material is selected from the group consisting of alpha cellulose, beta cellulose, gamma cellulose, preferred texture cellulose (PTC), wood, wood chips, wood fibers, sawdust, cardboard, paper, microcrystalline cellulose, and a combination thereof.

34. The composite material of claim 26 wherein the cellulosic food material comprises a purified cellulose.

35. The composite material of claim 26 wherein the pest comprises a cellulose-consuming organism.

36. The composite material of claim 26 wherein the pest is selected from the group consisting of termites, carpenter ants, carpenter wasps, and a combination thereof.

37. The composite material of claim 26 wherein the pesticide is selected from the group consisting of hexaflumuron, noviflumuron, chlorpyrifos, spinosad, imidacloprid, fipronil, lufenuron, diflubenzuron, flufenoxuron, hydramethylnon, and a combination thereof.

38. The composite material of claim 26 wherein the pesticide is selected from the group consisting of hexaflumuron, noviflumuron, and a combination thereof.

39. The composite material of claim 26 further comprising a stabilizer, processing aid, herbicide, fungicide, antimicrobial, bactericide, defoliant, safener, synergist, algaecide, attractant, desiccant, pheromone, repellant, animal dip, avicide, disinfectant, semiochemical, molluscicide, and a combination thereof.

40. The composite material of claim 26 further comprising a lubricant.

41. The composite material of claim 40 wherein the lubricant comprises up to about 5% by weight of the composite material.

42. The composite material of claim 26 wherein the cellulosic food material comprises alpha cellulose and the pesticide comprises noviflumuron.

43. The composite material of claim 26 wherein the plastic structural material comprises from about 5% to about 50% by weight of the composite material, wherein the cellulosic food material comprises from about 50% to about 85% by weight of the composite material, and wherein the pesticide comprises from about 0.001% to about 5% by weight of the composite material.

44. The composite material of claim 26 wherein the plastic structural material comprises from about 10% to about 40% by weight of the composite material, wherein the cellulosic food material comprises from about 60% to about 85% by weight of the composite material, and wherein the pesticide comprises from about 0.001% to about 5% by weight of the composite material.

45. The composite material of claim 26 wherein the plastic structural material comprises from about 15% to about 30% by weight of the composite material, wherein the cellulosic food material comprises from about 70% to about 85% by weight of the composite material, and wherein the pesticide comprises from about 0.001% to about 5% by weight of the composite material.

46. The composite material of claim 26 wherein the pesticide comprises from about 0.4% to about 5% by weight of the composite material.

47. A composite material for use in pest control, the composite material comprising:

a plastic structural matrix that comprises cellulose acetate butyrate;

alpha cellulose contained in the plastic structural matrix; and

a pesticide selected from the group consisting of hexaflumuron, noviflumuron, chlorpyrifos, spinosad, imidacloprid, fipronil, lufenuron, diflubenzuron, flufenoxuron, hydramethylnon, and a combination thereof.

48. The composite material of claim 47 wherein the plastic structural matrix further comprises at least one additional thermoplastic polymer selected from the group consisting of cellulose acetate, cellulose acetate propionate, polylactic acid, and a combination thereof.

49. The composite material of claim 47 wherein the pesticide is selected from the group consisting of hexaflumuron, noviflumuron, and a combination thereof.

50. The composite material of claim 47 wherein the plastic structural material comprises from about 5% to about 50% by weight of the composite material, wherein the alpha cellulose comprises from about 50% to about 85% by weight of the composite material, wherein the pesticide comprises from about 0.001% to about 5% by weight of the composite material, and wherein the pesticide comprises noviflumuron.

51. A composite material for use in pest control, the composite material comprising:

a plastic structural matrix that comprises a polymer selected from the group consisting of cellulose acetate, cellulose acetate butyrate, and a combination thereof;

alpha cellulose contained in the plastic structural matrix; and

a pesticide selected from the group consisting of hexaflumuron, noviflumuron, chlorpyrifos, spinosad, imidacloprid, fipronil, lufenuron, diflubenzuron, flufenoxuron, hydramethylnon, and a combination thereof.

52. The composite material of claim 51 wherein the plastic structural matrix further comprises cellulose acetate propionate.

53. The composite material of claim 51 wherein the plastic structural matrix further comprises polylactic acid.