BONDING ELEMENT, BONDING MATRIX AND COMPOSITE MATERIAL HAVING THE BONDING ELEMENT, AND METHOD OF MANUFACTURING THEREOF

• US 20170044061A1
• Filed: 04/13/2016
• Published: 02/16/2017
• Est. Priority Date: 03/05/2011
• Status: Active Grant

• Current Assignee: Rutgers University
• Original Assignee: Rutgers University
• Inventors: Riman, Richard E., Gupta, Surojit, Atakan, Vahit, Li, Qinghua
• Granted Patent: US 10,266,448 B2
• Time in Patent Office: Days
• CPC Class Codes: C04B 14/043 Alkaline-earth metal silicates, e.g. wollastonite
• CPC Class Codes: C04B 14/465 Ca-silicate, e.g. wollastonite
• CPC Class Codes: C04B 20/023 Chemical treatment
• CPC Class Codes: C04B 20/107 Acids or salts thereof
• CPC Class Codes: C04B 20/1074 Silicates, e.g. glass
• CPC Class Codes: C04B 20/12 Multiple coating or impregnating
• CPC Class Codes: C04B 2111/2015 Sulfate resistance
• CPC Class Codes: C04B 2111/29 Frost-thaw resistance
• CPC Class Codes: C04B 28/04 Portland cements
• CPC Class Codes: C04B 28/10 Lime cements or magnesium oxide cements
• CPC Class Codes: C04B 28/188 the Ca-silicates being present in the starting mixture
• CPC Class Codes: C04B 38/0074 expressed as porosity percentage
• CPC Class Codes: C04B 40/0231 Carbon dioxide hardening
• CPC Class Codes: Y10T 428/24851 Intermediate layer is discontinuous or differential
• CPC Class Codes: Y10T 428/249953 Composite having voids in a component [e.g., porous, cellular, etc.]

Abstract

A bonding element, a bonding element matrix and composite materials with a wide range of attractive properties that may be optimized, including, but not limited to, mechanical properties, thermal properties, magnetic properties, optical properties and nuclear properties, as a result of a first layer and second layer structure or core, first layer, and second layer structure of the bonding elements, as well as methods for making the bonding elements and the corresponding ceramic and/or composite materials.

Claims

1. A composite material comprising:

a bonding matrix, and

a filler material incorporated in the bonding matrix, the bonding matrix comprising a plurality of bonding elements, each bonding element comprising;

a core, wherein the core has a first chemical composition that includes one or more chemical elements;

a first layer at least partially covering a peripheral portion of the core, wherein the first layer has a second chemical composition that is a different chemical composition than the first chemical composition, the second chemical composition including cations corresponding to one of the chemical elements of the first chemical composition; and

a second layer at least partially covering a peripheral portion of the first layer, wherein the second layer has a third chemical composition that is a different chemical composition than the first and second chemical compositions, the third chemical composition including cations corresponding to one of the chemical elements of the first chemical composition,

wherein the bonding matrix is prepared from a porous solid body, the porous solid body comprises a plurality of precursor particles, the precursor particles have a mean particle size of less than 70 μ

m, and the precursor particles are transformed into the bonding elements,

wherein the core comprises at least one synthetic formulation having chemical elements M, Me, and O (oxygen) and/or OH group, M is an alkaline earth metal selected from calcium or magnesium, and Me is selected from a group of metals consisting of silicon, titanium, aluminum, phosphorous, vanadium, tungsten, molybdenum, gallium, manganese, zirconium, germanium, copper, niobium, cobalt, lead, iron, indium, arsenic and tantalum,

the filler material comprising an active material, the active filler material physically or mechanically interacting with the bonding matrix, the active material comprising a material that acts as a nucleation site or chemically reacts with the bonding matrix.

2. The composite material of claim 1, wherein cations associated with the second and third chemical compositions comprise alkaline earth metals.

3. The composite material of claim 9, wherein the cations associated with the second and third chemical compositions are selected from Ca+2 and Mg+2.

4. The composite material of claim 1, wherein the core is equiaxed, elliptically-shaped, flake-shaped, or fiber-shaped.

5. The composite material of claim 1, wherein the core comprises CaSiO3 or MgSiO3.

6. The composite material of claim 1, wherein the first layer comprises an oxide or a hydroxide of aluminium, silicon, or iron.

7. The composite material of claim 1, wherein the second layer is composed of a carbonate phase which bonds with one or more of:

limestone, marble dusts, calcium carbonate rich aggregates, gypsum, sand and silica rich aggregates, or combinations thereof.

8. The composite material of claim 1, wherein the bonding matrix is porous.

9. The composite material of claim 1, wherein at least some of the bonding elements are in contact with one another.

10. The composite material of claim 1, wherein the bonding matrix comprises a hydrate-free cementitious bond.

11. The composite material of claim 1, wherein the active material comprises a plurality of equiaxed particles, anisotropic particles, or a combination thereof.

12. The composite material of claim 1, wherein the filler material comprises:

a first plurality of first size particles and a second plurality of second size particles, the second size particles being substantially larger in size than the first sized particles, and wherein the bonding matrix, the first size particles and the second size particles are arranged such that the composite material forms a hierarchic structure.

13. The composite material of claim 12, wherein the bonding matrix is substantially arranged in porous spaces between adjacent first size particles, and wherein the adjacent first size particles are arranged in porous spaces between adjacent second size particles.

14. The composite material of claim 1, wherein the composite material has a Vickers hardness between about 1 GPa and 30 GPa.

15. The composite material of claim 1, wherein the composite material has a compressive strength varying between 14 to about 3,000 MPa and a flexural strength of less than about 380 MPa.

16. The composite material of claim 1, wherein the composite material exhibits creep strain of less than 60×

10-6/psi.

17. The composite material of claim 1, wherein the composite material exhibits Cl⁻

permeability of less than 700 C.

18. The composite material of claim 1, wherein the composite material is self reinforced and has a ball impact resistance greater than 6 J.

19. The composite material of claim 1, wherein the composite material is reinforced with steel fibers and has a ball impact resistance greater than 10 J.

20. The composite material of claim 1, wherein the composite material has a thermal conductivity of greater than about 0.13 W/mk, and less than about 196 W/mk.

21. The composite material of claim 1, wherein, the composite material exhibits at least one of the following properties:

(i) modulus of elasticity of at least 4.04×

106 psi;

(ii) split tensile strength of at least 390 psi;

(iii) average wear of less than 1.00 mm using ASTM C944;

(iv) freeze-thaw resistance of at least 300 cycles by ASTM C666,

(v) visible scaling resistance of x<

1 when testing using ASTM C672,

(vi) negligible shrinkage measured by ASTM C157, and

(vii) negligible alkali-silicate reaction.

22. The composite material of claim 1, wherein the composite material has a thermal expansion coefficient between 3×

10-6/C and 15×

10-6.

23. The composite material of claim 1, wherein the composite material has a heat capacity between 6 and 900 J/mole·

K.

24. The composite material of claim 1, wherein the composite material has a reflectivity coefficient between 0.04 and 0.9.

25. The composite material of claim 1, comprising a porosity of about 1 to about 70 vol.

26. The composite material of claim 1, comprising a porosity about 1 to about 10 vol. %.

27. The composite material of claim 1, comprising a porosity of about 50 to about 70 vol. %.

28. The composite material of claim 1, wherein the bonding matrix comprises a volume fraction of about 8 to about 30 vol. %.