METHOD FOR PRODUCING HYDROGENATED CONJUGATED DIENE POLYMER LATEX

• US 20200048375A1
• Filed: 01/18/2018
• Published: 02/13/2020
• Est. Priority Date: 01/20/2017
• Status: Active Grant

• Current Assignee: ZEON Corporation
• Original Assignee: ZEON Corporation
• Inventors: ONO, Kentaro, KATANO, Chikara, WATANABE, Yasuaki
• Granted Patent: US 10,968,287 B2
• Time in Patent Office: Days
• CPC Class Codes: C08C 19/02 Hydrogenation
• CPC Class Codes: C08F 236/04 conjugated
• CPC Class Codes: C08F 236/12 with nitriles
• CPC Class Codes: C08L 15/005 Hydrogenated nitrile rubber

Abstract

A method for producing a hydrogenated conjugated diene polymer latex includes: a hydrogenation step of dissolving or dispersing a hydrogenation catalyst containing a platinum group element in a latex of a conjugated diene polymer to hydrogenate a carbon-carbon unsaturated bond in the polymer; an insoluble complex formation step of complexing the platinum group element with a complexing agent to form an insoluble complex; and an insoluble complex removing step of continuously feeding the latex which has undergone the insoluble complex formation step to a centrifuge machine and continuously performing a centrifugation operation to continuously remove the insoluble complex from the latex and continuously discharge the insoluble complex out of the centrifuge machine. In the insoluble complex removal step the feed rate of the latex to the centrifuge machine is adjusted to 0.5 to 15 m³/hour, and the centrifugal force in the centrifugation operation is adjusted to 200 to 10,000 G.

Claims

1. A method for producing a hydrogenated conjugated diene polymer latex comprising:

a hydrogenation step of dissolving or dispersing a hydrogenation catalyst containing a platinum group element in a latex of a conjugated diene polymer to hydrogenate a carbon-carbon unsaturated bond in the conjugated diene polymer;

an insoluble complex formation step of complexing the platinum group element with a complexing agent to form an insoluble complex; and

an insoluble complex removing step of continuously feeding the latex which has undergone the insoluble complex formation step to a centrifuge machine and continuously performing a centrifugation operation to continuously remove the insoluble complex from the latex and continuously discharge the insoluble complex out of the centrifuge machine;

wherein in the insoluble complex removal step the feed rate of the latex to the centrifuge machine is adjusted to 0.5 to 15 m³/hour, and the centrifugal force in the centrifugation operation is adjusted to 200 to 10,000 G.

2. The method for producing a hydrogenated conjugated diene polymer latex according to claim 1, wherein the centrifuge machine is a decanter-type centrifuge machine.

3. The method for producing a hydrogenated conjugated diene polymer latex according to claim 1, wherein in the insoluble complex formation step, an oxidation treatment is performed on the latex to oxidize the hydrogenation catalyst in a reduced state present in the latex.

4. The method for producing a hydrogenated conjugated diene polymer latex according to claim 1, wherein the complexing agent is a dioxime compound.

5. The method for producing a hydrogenated conjugated diene polymer latex according to claim 1, wherein the conjugated diene polymer is a copolymer including a conjugated diene monomer unit and an α

,β

-ethylenically unsaturated nitrile monomer unit.