PREPARATION OF ASYMMETRIC POLYMER MEMBRANES
First Claim
2. The improvement as recited in claim 1 wherein the polyarylene oxide is polyxylylene oxide and the non-porous skin is less than about 3 microns thick.
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Abstract
A method is disclosed for the preparation (by the utilization of a proper solvent system) of dry asymmetric membranes comprising a porous layer of interconnected crystals of polymer material. Membranes of many polymer materials may be optionally prepared either with or without a dense surface layer as one face thereof. In either case the porous layer is structured with graded porosity. A three-component casting solution is prepared containing the polymer, a first good volatile solvent for the polymer and (relative to the first solvent) a poor less-volatile solvent for the polymer, which is miscible with the good solvent. A membrane is cast, allowed to desolvate for a short time and is then immersed in a leaching agent, that is miscible with both the aforementioned solvents but is a non-solvent for the polymer. The membrane is then permitted to dry.
16 Citations
2 Claims
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2. The improvement as recited in claim 1 wherein the polyarylene oxide is polyxylylene oxide and the non-porous skin is less than about 3 microns thick.
Specification