Nematic liquid crystal mixtures having homogeneous boundary conditions and method of making the same

• US 3,951,845 A
• Filed: 07/16/1973
• Issued: 04/20/1976
• Est. Priority Date: 06/23/1972
• Status: Expired due to Term

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Cole, Herbert S. Jr.
• Primary Examiner(s): Lovering, Richard D.
• Assistant Examiner(s): Gron, T. S.
• Application Number:
  US05/379,723
• Time in Patent Office: 1,009 Days
• Field of Search: 252/408, 252/299, 350/160 LC, 350/150
• US Class Current: 252/299.4
• CPC Class Codes: C09K 19/54 Additives having no specific mesophase characterised by their chemical composition
• CPC Class Codes: G02F 1/133703 by introducing organic surfactant additives into the liquid crystal material

Abstract

Nematic liquid crystal mixtures characterized by a homogeneous boundary condition are prepared by the addition of soluble compounds having at least two polar groups to nematic liquid crystals of either positive or negative dielectric anisotropy. Between approximately 0.5 and 5 percent by weight of compounds such as dicarboxylic acids, aliphatic diamines, aliphatic dinitriles, diols, polyalkylene glycol, alkanol amines, e.g., ethanolamine, diethanolamine, triethanolamine and diethylene triamine, for example, when dissolved in a nematic material produce spontaneous homogeneous boundary conditions therein.

Claims

1. A nematic liquid crystal mixture characterized by a homogeneous boundary condition when formed in a thin layer, said mixture comprising a nematic liquid crystal and between approximately 0.5 and 5 percent by weight of the mixture of a compound having at least two polar groups, one group at each end of the compound, said compound being characterized by a substantially straight chain organic radical containing from 1 to about 12 carbon atoms between said end polar groups and by a substantial solubility in the nematic liquid crystal, the molecules of said compound tending to align parallel to a boundary substrate and thereby produce said homogeneous boundary condition in said mixture.

2. The mixture of claim 1 wherein said compound is selected from the group consisting of dicarboxylic acids, aliphatic diamines, aliphatic dinitriles and diols.

3. The mixture of claim 1 wherein said compound is a polyalkylene glycol.

4. The mixture of claim 1 wherein said compound is an aliphatic amine selected from the group consisting of alkanolamines and alkylenepolyamines.

5. The mixture of claim 1 wherein said compound is 11-Bromo-Δ

10-undecylenic acid.

6. The mixture of claim 1 wherein said nematic liquid crystal has either a positive or a negative dielectric anisotropy.

7. The mixture of claim 1 wherein said compound is 1,5-dicyanopentane.

8. The mixture of claim 1 wherein said mixture has a negative dielectric anisotropy and an approximately 10 to 100 micron thick layer of said mixture is characterized by substantially the same transmissivity in the absence of an electric field as in the presence of a high frequency field which does not produce any turbulence in said mixture.

9. The mixture of claim 1 producing a homogeneous boundary condition when placed between planar substrates spaced apart by approximately 6 to 150 microns.

10. A liquid crystal display device comprising a sealed display cell with a thin layer of a nematic liquid crystal mixture contained therein, said mixture comprising a nematic liquid crystal and between approximately 0.5 and 5 percent by weight of the mixture of a compound dissolved in said nematic liquid crystal which contains at least two polar groups, one at each end of the compound, said compound including a substantially straight chain organic radical containing from 1 to about 12 carbon atoms between said end polar groups, the molecules of said compound tending to align parallel to a substrate forming a boundary wall of said display cell and thereby produce a homogeneous boundary condition in said mixture.

11. The display device of claim 10 wherein said compound is selected from the group consisting of dicarboxylic acids, aliphatic diamines, aliphatic dinitriles and diols.

12. The liquid crystal display device of claim 10 wherein said display device is substantially transparent in the absence of an electric field and in the presence of a high frequency alternating current field.

13. The liquid crystal display device of claim 10 wherein said nematic liquid crystal has a net positive dielectric anisotropy.

14. A method of producing a homogeneous boundary condition in a nematic liquid crystal material, said method comprising mixing a soluble compound having at least one polar group at each end of the compound and a substantially straight chain organic radical containing from 1 to about 12 carbon atoms between said end polar groups into said nematic liquid crystal material in a concentration of between approximately 0.5 and 5 percent by weight, so as to produce said homogeneous boundary condition.

15. The method of claim 14 wherein the step of mixing is accomplished at an elevated temperature.

16. The method of claim 14 wherein said compound is selected from the group consisting of dicarboxylic acids, aliphatic diamines, aliphatic dinitriles and diols.

17. The method of claim 14 wherein said compound is selected from the group consisting of oxydipropionitrile, ethanolamine, diethanolamine, 1,5-dicyanopentane and 11-Bromo-Δ

10-undecylenic acid.

18. In combination with a display device including a pair of closely spaced planar substrates with a nematic liquid crystal sealed in the space therebetween and means for applying an electric field to at least selected regions of said nematic liquid crystal, the improvement comprising the dissolution in said nematic liquid crystal of between approximately 0.5 and 5 percent by weight of the mixture of a compound having at least two polar groups, one at each end of the compound, said compound including a substantially straight chain organic radical containing from 1 to about 12 carbon atoms between said end polar groups, the molecules of said compound tending to align parallel to the adjacent surface of said spaced planar substrates, so as to cause said nematic liquid crystal to assume a homogeneous condition.

19. The combination of claim 18 wherein said compound is selected from the group consisting of dicarboxylic acids, aliphatic diamines, aliphatic dinitriles and diols.