Process for the production of sprayed phosphate coats on iron and steel

• US 4,003,761 A
• Filed: 04/02/1975
• Issued: 01/18/1977
• Est. Priority Date: 04/13/1974
• Status: Expired due to Term

• Current Assignee: Gerhard Collardin GmbH
• Original Assignee: Gerhard Collardin GmbH
• Inventors: Gotta, Hans, Schroll, Franz-Heinz
• Primary Examiner(s): Kendall, Ralph S.
• Assistant Examiner(s): Wolfe, Jr., Charles R.
• Application Number:
  US05/564,556
• Time in Patent Office: 657 Days
• Field of Search: 148/6.15 R, 148/6.15 Z, 252/389 A, 106/14
• US Class Current: 148/259
• CPC Class Codes: C23C 22/08 Orthophosphates
• CPC Class Codes: C23C 22/76 Applying the liquid by spraying

Abstract

In the process for applying a phosphate coating to a ferric surface which comprises spraying an aqueous acidic solution at a pH of 4.3 to 6.5 containing an orthophosphate salt of a cation selected from the group consisting of alkali metals and ammonium, in the presence of oxidizing agent or reducing agent accelerators onto said surface, the improvement consisting of adding to said aqueous acidic solution from 0.05 to 1 gm per liter of a short-chain alkylolamine having from 2 to 4 carbon atoms in each alkylol and from 0.01 to 1.5 gm per liter of at least one non-ionic surface-active wetting agent.

Claims

1. A process for forming a phosphate coating on a corrodible ferric surface, thereby rendering said surface corrosion resistant which comprises spraying said surface for 0.5 to 5 minutes with a solution having a pH of 4.3 to 6.5 consisting essentially of 1 to 20 g./liter of an orthophosphate salt of a cation selected from the group consisting of alkali metals and ammonium, 0.05 to 5 g./liter of an oxidizing agent or reducing agent accelerator, 0.05 to 1 g./liter of a short-chain alkylolamine having from 2 to 4 carbon atoms in each alkylol group from 0.01 to 1.5 g./liter of at least one non-ionic wetting agent and the remainder water at a temperature in the range of about 40°

to 95°

C.

2. The process of claim 1 wherein said accelerator is selected from the group consisting of alkali metal nitrites, alkali metal perborates, alkali metal bromates, alkali metal and ammonium molybdates, hydroxylamine salts and organic nitro compounds.

3. The process of claim 1 wherein the spraying is effected in two stages and the concentration of the orthophosphate salt is larger by about 50% to 100% in the second stage than in the first stage.

4. The process of claim 3 wherein the concentration of the wetting agent is smaller by about 20% to 30% in the second state than in the first stage.

5. The process of claim 1 wherein said aqueous acidic solution contains polycondensed phosphates in addition to said orthophosphate salts.

6. The process of claim 1 wherein, after said acidic solution is sprayed on said ferric surface, said ferric surface is rinsed with water.

7. The process of claim 1 wherein said acidic solution has a further content of from 0.05 to 0.5 gm per liter of at last one alkanoic acid having from 6 to 10 carbon atoms.

8. The process of claim 1 wherein said acidic solution has a further content of from 0.05 to 0.5 gm per liter of at least one aromatic carboxylic acid selected from the group consisting of benzoic acid and alkylated benzoic acids having 1 to 4 carbon atoms in the alkyl group thereof.

9. A substantially anhydrous composition which when diluted with water to 1,000 parts by weight is useful for rendering corrodible ferrous surface corrosion resistant consisting essentially of 1 to 20 parts by weight of an orthophosphate salt of a cation selected from the group consisting of alkali metals and ammonium, 0.05 to 5 parts of an oxidizing or reducing accelerator, 0.05 to 1 part of a C₂ -C₄ alkanolamine, and 0.01 to 1.5 parts of a non-ionic wetting agent, and an acid or alkali to provide a pH between 4.3 and 6.5 when said composition is dissolved in water to 1,000 parts by weight.

10. A composition useful for the phosphatizing of corrodible ferrous surfaces, consisting essentially of 1 to 20 g./liter of an orthophosphate salt of a cation selected from the group consisting of alkali metals and ammonium, 0.05 to 5 g./liter of an oxidizing or reducing accelerator, 0.05 to 1 g./liter of a C₂ -C₄ alkanolamine, and 0.01 to 1.5 g./liter of a non-ionic wetting agent, and the remainer water;

said solution having a pH between 4.3 and 6.5.