Liquid crystal cells

• US 4,007,077 A
• Filed: 08/21/1975
• Issued: 02/08/1977
• Est. Priority Date: 12/27/1973
• Status: Expired due to Term

• Current Assignee: DAI Nippon Toryo Kabushiki Kaisha
• Original Assignee: DAI Nippon Toryo Kabushiki Kaisha
• Inventors: Yaguchi, Masachika
• Primary Examiner(s): Whitby, Edward G.
• Application Number:
  US05/606,493
• Time in Patent Office: 537 Days
• Field of Search: 156/100, 156/106, 156/107, 156/94, 156/242, 156/246, 156/145, 156/278, 156/325, 156/331, 156/334, 260/78.4 N, 260/78.5 N, 260/86.1 N, 260/94.2 R, 350/160 LC, 53/43, 106/33, 106/162, 136/145, 428/1
• US Class Current: 156/145
• CPC Class Codes: C09K 19/02 characterised by optical, electrical or physical properties of the components, in general
• CPC Class Codes: G02F 1/1339 Gaskets; Spacers; Sealing of cells
• CPC Class Codes: G02F 1/1341 Filling or closing of cells

Abstract

A liquid crystal cell consisting of two planar supports and a spacer interposed between them only on the margin, said supports being fixed at intervals of a limit by the spacer to form an aperture, has at least one opening through which the liquid crystal material is poured into said aperture. The openings are sealed with use of cyanoacrylates or polybutadiene type resins so that the liquid crystal cell can be prevented from lowering of the characteristics caused by incorporating of impurities into the liquid crystal layer.

Claims

1. Process for sealing a liquid crystal cell having two planar supports fixed at limited intervals by a spacer and having at least one opening for pouring into the cell a liquid crystal material which process comprises pouring said liquid crystal material through said opening into the cell and applying at least one cyanoacrylate compound to each said opening thereby forming instantaneously an insoluble cured film on the boundary between the liquid crystal layer and the sealed layer, said liquid crystal material consisting essentially of at least one compound having the formula:

##STR5## wherein X represents --CH=N--, --N=N--, ##STR6## radicals, and Y₁ and Y₂ each independently represents halogen or --R, --OR, --COR, --CN, --OCOOR or --OCOR radicals wherein R is hydrogen or a hydrocarbon radical having from 1 to 4 carbon atoms, and said cyanoacrylate compound having the formula;

##STR7## wherein R is a hydrocarbon radical having 1 to 5 carbons atoms, whereby an insoluble cured film seal is formed between the seal layer and the liquid crystal layer so that incorporation or effusion of impurities into the liquid crystal layer is prevented and the liquid crystal cell so formed has improved mesomorphic range, current density and life.

4. Process for sealing a liquid crystal cell having two planar supports fixed at limited intervals by a spacer and having at least one opening for pouring a liquid crystal material into the cell, which process comprises pouring said liquid crystal material through said opening into the cell, sealing all the openings with a polybutadiene type resin of about 200 to 20,000 molecular weight exhibiting liquidity or fluidity at temperatures of from normal temperature to about 130°

C, and heating and curing the sealed parts at temperatures of about 130°

to 500°

C, said liquid crystal material consisting essentially of at least one compound having the formula;

##STR8## wherein X represents --CH=N--, --N=N--, ##STR9## radicals, and Y₁ and Y₂ each independently represents halogen or --R, --OR, --COR, --CN, --OCOOR or --OCOR radicals wherein R is hydrogen or a hydrocarbon radical having from 1 to 4 carbon atoms, whereby an insoluble cured film seal is formed between the seal layer and the liquid crystal layer so that incorporation or effusion of impurities into the liquid crystal layer is prevented and the liquid crystal cell so formed has improved mesomorphic range, current density and life.

5. Process according to claim 10, wherein said polybutadiene type resin is in the form of a composition containing from about 0.1 to about 4.0% by weight of an initiator for radical polymerization and/or a dryer.

6. Process for sealing a liquid crystal cell having two planar supports fixed at limited intervals by a spacer and having at least one opening for pouring into the cell a liquid crystal material which process comprises pouring said liquid crystal material through said opening into the cell and applying a sealing material to all the openings, said liquid crystal material consisting essentially of at least one compound having the formula:

##STR10## wherein X represents --CH=N--, --N=N--, ##STR11## radicals, and Y₁ and Y₂ each independently represents halogen or --R, --OR, --COR, --CN, --OCOOR or --OCOR radicals wherein R is hydrogen or a hydrocarbon radical, provided that X is --CH=N--, --N=N--, ##STR12## radicals when both of Y₁ and Y₂ are other radicals than --CN radical and at least one of Y₁ and Y₂ is --CN radical when X is other radicals then --CH=N--, ##STR13## radicals, and said sealing material being a cyanoacrylate compound of the formula;

##STR14## wherein R is a hydrocarbon radical having 1 to 5 carbon atoms, thereby forming instantaneously an insoluble cured film on the boundary between the liquid crystal layer and the sealed layer.

7. Process according to claim 12, wherein said liquid crystal material is compounds synthesized from aliphatic or primary aromatic amines, aliphatic or aromatic nitro compounds or aliphatic or aromatic hydroxyl group containing compounds.

2. Process according to claim 7, wherein said liquid crystal material is at least one compound synthesized from aliphatic or primary aromatic amines, aliphatic or aromatic nitro compounds or aliphatic or aromatic hydroxyl group containing compounds.

8. Process for sealing a liquid crystal cell having two planar supports fixed at limited intervals by a spacer and having at least one opening for pouring into a cell a liquid crystal material which process comprises pouring said liquid crystal material through said opening into the cell and applying a sealing material to all the openings wherein said liquid crystal material consists essentially of a liquid crystal composition containing at least one of aliphatic or primary aromatic amines, aliphatic or aromatic nitro compounds or aliphatic or aromatic hydroxyl group containing compounds in an amount of less than about 10⁴ ppm and said sealing material is a cyanoacrylate compound of the formula:

##STR15## wherein R is a hydrocarbon radical having 1 to 5 carbon atoms, thereby forming instantaneously an insoluble cured film on the boundary between the liquid crystal layer and the sealed layer.

3. Process according to claim 8, wherein said liquid crystal material consists essentially of a liquid crystal composition containing at least one of said amines, nitro compounds and hydroxyl group containing compounds in an amount of less than about 10⁴ ppm.