Visual image display device

• US 4,037,928 A
• Filed: 06/04/1976
• Issued: 07/26/1977
• Est. Priority Date: 06/04/1976
• Status: Expired due to Term

• Current Assignee: International Business Machines Corporation
• Original Assignee: International Business Machines Corporation
• Inventors: Champ, Robert Bruce, Shattuck, Meredith David
• Primary Examiner(s): Sikes, William L.
• Application Number:
  US05/693,073
• Time in Patent Office: 417 Days
• Field of Search: 350/160 R, 350/160 P, 350/161 S, 350/161 P, 350/311, 350/312
• US Class Current: 359/242
• CPC Class Codes: C09K 9/02 Organic tenebrescent materials
• CPC Class Codes: C22B 3/28 Amines
• CPC Class Codes: C22B 3/306 Ketones or aldehydes
• CPC Class Codes: C22B 3/32 Carboxylic acids
• CPC Class Codes: C22B 3/38 containing phosphorus
• CPC Class Codes: G02F 1/1516 comprising organic material
• CPC Class Codes: G03C 1/675 Compositions containing polyhalogenated compounds as photosensitive substances for photopolymerisable or photocrosslinkable compositions G03F7/028, covered by G03C1/72
• CPC Class Codes: G03G 17/02 with electrolytic development
• CPC Class Codes: Y02P 10/20 Recycling

Abstract

A visual image display device with improved resolution contains a pair of conductive electrodes in spaced relationship. Adjacent one electrode is a first barrier layer which is typically a resin such as polyamide containing a readily oxidizable and reducible material such as zinc nitrate. Adjacent the other electrode is a thin film of solvent, for example, 1,2-dichloroethane. Positioned between the film of solvent and the first barrier layer is a second barrier layer which is a normally light transmitting recording medium. The second barrier layer is both photoionizable and capable of electrochemically producing a colored species. Typically the second barrier layer is a solid containing a resin such as polyvinyl butyral, an active material such as 1-p-anisyl-3 diethylamino styryl-5-diethylaminophenyl-2-pyrazoline and, in selected embodiments, an activator such as carbon tetrachloride.

Claims

1. A visual image display device comprising:

a first and a second conductive electrode in spaced relationship;

a first barrier layer positioned between said electrodes adjacent to said first electrode,

a film of solvent positioned between said electrodes and adjacent to said second electrode,

a second barrier layer positioned between said first barrier layer and said solvent film, said second layer being a normally light transmitting recording medium and having the properties of being both photoionizable and capable of electrochemically producing a colored specie, and

a voltage source and means for selectively applying this voltage between the electrodes to produce an electric field.

2. A device as described in claim 1 wherein said film of solvent is a chlorinated solvent.

3. A device as described in claim 2 wherein said film of solvent is taken from the group consisting of 1, 2-dichloroethane,

dichlorobutane, and

1, 1-trichloroethane.

4. A device as described in claim 1 wherein said film of solvent is sufficiently thick to make electrical contact between said second barrier and said second electrode.

5. A device as described in claim 1 wherein said film of solvent contains an activator.

6. A visual image display device comprising:

a first and a second conductive electrode in spaced relationship;

a first barrier layer positioned between said electrodes and adjacent to said first electrode,

a film of solvent positioned between said electrodes and adjacent to said second electrode,

a second barrier layer positioned between said first barrier layer and said solvent film, said second layer being normally light transmitting recording medium and having the properties of being both photoionizable and capable of electrochemically producing colored species, said second layer being solid containing a resin and an active material, and

a voltage source and means for selectively applying this voltage between the electrodes to produce an electric field.

7. A device as described in claim 6 wherein said active material is a triaryl pyrazoline.

8. A device as described in claim 6 wherein said resin is taken from the group consisting of

polyvinyl butyral

polycarbonate

polyamide

polyacrylates

polymethacrylates

polyvinylcarbazole.

9. A device as described in claim 6 wherein said second barrier layer contains an activator.

10. A device as described in claim 6 wherein said second barrier layer is 7 to 100 microns thick.

11. A device as described in claim 6 wherein said second barrier is in the form of a tape, said tape adapted to provide a plurality of regions for image forming.

12. A device as described in claim 6 wherein said second barrier layer is a composite consisting of two separate layers.