Electrowinning metals

• US 4,039,403 A
• Filed: 02/26/1976
• Issued: 08/02/1977
• Est. Priority Date: 03/05/1975
• Status: Expired due to Term

• Current Assignee: IMI Refinery Holdings Limited, Imperial Metal Industries
• Original Assignee: IMI Refinery Holdings Limited, Imperial Metal Industries
• Inventors: Brookes, Garth Royston, Scholes, Ian Robert, Gilbert, John Roger Bawden, Astley, David John, Jacobi, Jan Stephan
• Primary Examiner(s): Andrews, R. L.
• Application Number:
  US05/661,786
• Time in Patent Office: 523 Days
• Field of Search: 204/105 R, 204/287, 204/291, 204/293-294, 204/108, 204/112
• US Class Current: 205/573
• CPC Class Codes: C25C 1/00 Electrolytic production, recovery or refining of metals by electrolysis of solutions C25C5/00 takes precedence
• CPC Class Codes: C25C 7/02 Electrodes consumable anodes for the refining the metals C25C1/00 - C25C5/00; Connections thereof
• CPC Class Codes: Y02P 10/20 Recycling

Abstract

A method of electrowinning metals in which the anode comprises a foraminate container containing particulate material chosen from the group electrically conducting non-polarizing compound of a metal and a non-metallic element.

Claims

1. A method of electrowinning a metal from an aqueous solution containing ions of the metal which includes the steps of inserting an anode and a cathode into the solution, connecting the anode positively with respect to the cathode, and passing an electrical current through the anode and cathode, characterised in that the anode is a foraminate container containing particulate material comprising electrically conducting, non-polarising compounds of a metal and a non-metallic element, there being provided means to supply the current to the particulate material.

2. A method as claimed in claim 1 in which the container is of a non-conducting material with a current lead-in in contact with the particulate material.

3. A method as claimed in claim 2 in which the foraminate container has a stereo-reticular array of plastics material on the inside between the container and the material.

4. A method as claimed in claim 3 in which the stereo-reticular array is a mass of non-woven fibres.

5. A method as claimed in claim 4 in which the mass of fibres is a molded fibre structure.

6. A method as claimed in claim 4 in which the fibres are randomly bonded one to the other where they are in contact with one another.

7. A method as in claim 3 wherein the foraminate container has a stereo-reticular array of plastics material on the outside of the container.

8. A method as claimed in claim 2 in which the lead-in is a copper-cored titanium bar.

9. A method as in claim 2 in which the container is constructed of a plastics material.

10. A method as claimed in claim 1 in which the non-metallic element is selected from the group consisting of oxygen, nitrogen, boron or carbon, and the metal is selected from the group consisting of titanium, vanadium, chromium, manganese, iron, cobalt, nickel, lead and copper.

11. A method as claimed in claim 10 in which the particulate material is selected from the group consisting of PbO₂, MnO₂, Co₂ O₃ and magnetite.

12. A method as claimed in claim 1 in which the foraminate container is formed of titanium or a titanium alloy.

13. A method as claimed in claim 12 in which the foraminate titanium container has a stereo-reticular array of plastics material on the outside thereof.

14. A method as claimed in claim 1 in which the non-metallic element is silicon and the metal is selected from the group consisting of titanium, vanadium, chromium, manganese, iron, cobalt, nickel and copper.

15. A method as claimed in claim 1 in which the container had a depth in excess of one half-meter.

16. A method as in claim 15 wherein the container has a depth of one meter.

17. A method as claimed in claim 1 in which the particulate material anodically dissolves at a rate less than half the faradaic dissolution rate.

18. A method as claimed in claim 1 in which the materials used as the anode materials contain as impurities several percent of elements other than those previously mentioned.