Combustible gases detector

• US 4,063,898 A
• Filed: 09/20/1976
• Issued: 12/20/1977
• Est. Priority Date: 09/20/1976
• Status: Expired due to Term

• Current Assignee: Elsag International NV
• Original Assignee: Bailey Meter Company
• Inventors: Fisher, Edward William
• Primary Examiner(s): Wolk, Morris O.
• Assistant Examiner(s): Marcus, Michael S.
• Application Number:
  US05/724,682
• Time in Patent Office: 456 Days
• Field of Search: 23/254 E, 23/255 E, 73/25, 73/15 B, 136/225, 60/276
• US Class Current: 422/94
• CPC Class Codes: G01N 25/32 using thermoelectric elements
• CPC Class Codes: Y10T 436/205831 Carbon monoxide only
• CPC Class Codes: Y10T 436/214 Acyclic [e.g., methane, octane, isoparaffin, etc.]

Abstract

A differential thermocouple combustible gas detector is provided by coating one thermocouple junction of a differential thermocouple pair with a catalyst and the other thermocouple junction with a non-catalyst. Heated combustible gases react with the catalyst to liberate heat to the catalyst coated thermocouple junction in proportion to the concentration of combustible gases and proportionally raise the temperature of that junction above the non-catalyst coated junction. The output signal from the differential thermocouple device is thus a signal indicative of the concentration of combustible gases.

Claims

1. A detector for monitoring combustible gases in an airstream comprising:

a first thermocouple junction located in the airstream;

a second thermocouple junction located in the airstream and connected to said first thermocouple to form a differential thermocouple;

catalytic means formed around said first thermocouple junction allowing heated combustibles in the airstream to react with said catalytic means to liberate heat and increase the temperature of said first thermocouple above that of said second thermocouple;

insulation means formed around said second thermocouple junction to prevent combustibles in the airstream from reacting with said second thermocouple junction to liberate heat including a tube of non-catalytic material mounted on said second thermocouple junction with a non-catalytic cement material formed around said non-catalytic tube; and

means connected to said first and second thermocouple junctions for indicating the temperature differential between said first and second thermocouple junctions.

2. A detector as set forth in claim 1 wherein said catalytic means includes a platinum tube mounted on said first thermocouple junction.

3. A detector as set forth in claim 1 wherein said catalytic means includes a platinum paste baked onto said first thermocouple junction.

4. A detector as set forth in claim 1 wherein said catalytic means includes a platinum tube mounted on said first thermocouple junction and a coating of platinum paste baked onto said platinum tube to increase the catalytic surface area thereby.

5. A detector as set forth in claim 1 including heater means for maintaining the temperature of said first and said second thermocouple junctions above a predetermined temperature below which combustibles in the airstream will not react with the catalytic means on said first thermocouple junction.

6. A detector as set forth in claim 5 wherein said heater means includes a coil heater mounted around said first and second thermocouple junction.

7. A detector as set forth in claim 6 wherein said coil heater is coated with a non-catalytic cement material to prevent combustibles in the airstream from reacting with the heater material.

8. A differential thermocouple device for detecting carbon monoxide in air comprising:

a first thermocouple junction formed from dissimilar metals;

a second thermocouple junction formed form the same dissimilar metals as said first thermocouple and being electrically connected to said first thermocouple to oppose the electrical output signal of said first thermocouple;

a catalytic material tube mounted on said first thermocouple junction to react with the carbon monoxide in the air to liberate heat in proportion to the concentration of carbon monoxide and increase the temperature of said first thermocouple junction located in said catalytic material tube;

a non-catalytic material tube located on said second thermocouple junction to prevent any reaction with the carbon monoxide in the air at the second thermocouple junction; and

detection means connected to said first and said second thermocouple junctions to provide an output responsive to the temperature difference between said first and second thermocouple junctions to indicate the concentration of carbon monoxide thereby.

9. A device as set forth in claim 8 including a coating of platinum paste baked onto said catalytic material tube to increase the catalytic surface area thereby.

10. A device as set forth in claim 9 including a non-catalytic cement material formed around said non-catalytic material tube.

11. A device as set forth in claim 10 including heater means for maintaining the temperature of said first and said second thermocouple junctions above a predetermined temperature below which combustibles in the airstream will not react with the catalytic means on said first thermocouple junction.

12. A device as set forth in claim 11 wherein said heater means includes a coil heater mounted around said first and second thermocouple junction.