Process for sequentially dispersing and saponifying ethylene-vinyl acetate copolymer

• US 4,200,708 A
• Filed: 08/17/1978
• Issued: 04/29/1980
• Est. Priority Date: 08/17/1978
• Status: Expired due to Term

• Current Assignee: Equistar Chemicals LP (Lyondellbasell Industries NV)
• Original Assignee: National Distillers and Chemical Corporation
• Inventors: McClain, Dorothee M.
• Primary Examiner(s): Levin, Stanford M.
• Application Number:
  US05/934,648
• Time in Patent Office: 621 Days
• Field of Search: 526/10, 260/23 H
• US Class Current: 525/62
• CPC Class Codes: C08F 210/02 Ethene
• CPC Class Codes: C08F 218/08 Vinyl acetate
• CPC Class Codes: C08F 2810/50 wherein the polymer is a copolymer and the modification is taking place only on one or more of the monomers present in minority
• CPC Class Codes: C08F 8/12 Hydrolysis

Abstract

Finely divided saponified ethylene-vinyl acetate copolymer particles are prepared by forming an aqueous dispersion of the copolymer without effecting any appreciable saponification of the dispersed copolymer and thereafter saponifying the dispersed copolymer to the extent desired.

Claims

1. A process for obtaining finely divided saponified ethylene-vinyl acetate copolymer particles which comprises the sequential steps of:

(a) dispersing the copolymer in an aqueous dispersion medium containing a dispersing agent for EVA copolymer under such conditions of time and/or temperature that no appreciable saponification of the dispersed copolymer can occur, the resulting dispersion being made up of particles of an average diameter of from about 20 to about 500 microns; and

,

(b) saponifying the dispersed copolymer employing a strong base as the saponifying agent under such conditions of time and/or temperature that saponification to a predetermined extent is achieved.

2. The process of claim 1 wherein the ethylene-vinyl acetate copolymer contains up to about 15% by weight of combined vinyl acetate.

3. The process of claim 1 wherein the ethylene-vinyl acetate copolymer contains from above about 15% up to about 35% by weight of combined vinyl acetate.

4. The process of claim 1 wherein the ethylene-vinyl acetate copolymer contains above about 35% by weight of combined vinyl acetate.

5. The process of claim 2 wherein the dispersing agent is a combination of a soap of an alkali metal having an atomic weight of at least 23 and a water-soluble substantially neutral salt.

6. The process of claim 3 wherein the dispersing agent is a combination of a soap of an alkali metal having an atomic weight of at least 23 and a water-soluble substantially neutral salt.

7. The process of claim 4 wherein the dispersing agent is a soap of an alkali metal having an atomic weight of at least 23.

8. The process of claim 5 wherein the soap is sodium stearate and the salt is sodium chloride.

9. The process of claim 6 wherein the soap is sodium stearate and the salt is sodium chloride.

10. The process of claim 7 wherein the soap is sodium stearate.

11. The process of claim 1 wherein the dispersing agent is a lithium soap of a higher saturated fatty acid.

12. The process of claim 11 wherein the soap is lithium behenate.

13. The process of claim 1 wherein the dispersing agent is selected from the group of surface active agents consisting of the sulfates, sulfonates, sarcosinates, and sodium salts of organophosphate esters, fatty amide phosphates, polymeric acrylates, fatty amide derivatives, higher alkyl amines, amido amines, substituted imidazolines, substituted betaines, N-alkyl beta amino acid salts, protein derivatives, polyaminocarboxylic acid salts, cationic polyamines, alkyl amides and ethoxylated alkylol amides.

14. The process of claim 1 wherein the saponifying agent is present during the dispersing step.

15. The process of claim 14 wherein the saponifying agent is sodium hydroxide.

16. The process of claim 1 wherein the saponifying agent is added to the dispersed copolymer at the commencement of the saponifying step.

17. The process of claim 1 wherein the saponified copolymer particles are recovered from the aqueous dispersion medium.