Process and composition for removing carbon dioxide containing acidic gases from gaseous mixtures

• US 4,217,236 A
• Filed: 09/22/1977
• Issued: 08/12/1980
• Est. Priority Date: 02/14/1977
• Status: Expired due to Term

• Current Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Original Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Inventors: Savage, David W., Sartori, Guido
• Primary Examiner(s): Padgett, Benjamin R.
• Assistant Examiner(s): Barr, J. L.
• Application Number:
  US05/835,773
• Time in Patent Office: 1,055 Days
• Field of Search: 252/189, 252/403, 252/190, 423/220, 423/228, 423/229, 260/584 R
• US Class Current: 252/189
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

Carbon dioxide containing acidic gases are substantially removed from a normally gaseous mixture by a process comprising contacting the normally gaseous mixture with an aqueous amine solution, wherein the amine consists of at least about 50 mol % of a sterically hindered amino alcohol and at least about 10 mol % of a tertiary amino alcohol, wherein said sterically hindered amino alcohol contains at least one secondary amino group which is part of a ring and is attached to either a secondary or tertiary carbon atom or a primary amino group attached to a tertiary carbon atom. The coaction of the sterically hindered amino alcohol and the tertiary amino alcohol provide an increase in the amount of carbon dioxide containing acidic gases absorbed compared to the use of the sterically hindered amines alone and lowers the heat of reaction.

Claims

1. An amine composition comprising an aqueous mixture of:

(a) at least about 50 mol % of a sterically hindered amino alcohol wherein the sterically hindered amino alcohol contains at least one secondary amino group which is part of a ring and is attached to either a secondary or tertiary carbon atom or a primary amino group attached to a tertiary carbon atom, and

(b) at least about 10 mol % of a tertiary amino alcohol.

2. The composition of claim 1 wherein the fraction of the sterically hindered amino alcohol is at least about 65 mol % of the total amine and the fraction of the tertiary amino alcohol is in the range from about 20 to about 35 mol % of the total amine.

3. The composition of claim 1, wherein the sterically hindered amino alcohol is 2-amino-2-methyl-1-propanol and the tertiary amino alcohol is a member selected from the group consisting of N-methyl-diethanolamine, 2-dimethylamino ethanol, 3-dimethylamino-1-propanol and 1-diethylamino-2-propanol.

4. The composition of claim 1 wherein the total amine concentration in the solution is in the range from about 1 to about 6 molar.

5. The composition of claim 1 wherein the total amine concentration in the solution is in the range from about 3 to about 5 molar.

6. The composition of claim 1 which additionally includes additives selected from the group consisting of antifoaming agents, antioxidants and corrosion inhibitors.

7. An amine composition comprising an aqueous mixture of (a) at least about 50 mol % of 2-amino-2-methyl-1-propanol, and (b) at least about 10 mol % of a tertiary amino alcohol selected from the group consisting of N-methyl diethanolamine, 2-dimethylamino ethanol, 3-dimethylamino-1-propanol and 1-dimethylamino-2-propanol.

8. The composition of claim 7 wherein the total amine concentration in the composition is in the range from about 1 to about 6 molar, the content of 2-amino-2-methyl-1-propanol is at least 65 mol % of the total amine and the content of the tertiary amino alcohol is in the range from about 20 to about 35 mol % of the total amine.

9. The composition of claim 8 wherein the total amine concentration in said composition is in the range from about 3 to about 5 molar.

10. The composition of claim 8 which additionally includes additives selected from the group consisting of antifoaming agents, antioxidants and corrosion inhibitors.