Emulsion composition and method for use in treating glass fibers

• US 4,240,944 A
• Filed: 02/12/1979
• Issued: 12/23/1980
• Est. Priority Date: 02/12/1979
• Status: Expired due to Term

• Current Assignee: PPG Industries Incorporated (Nouryon BV)
• Original Assignee: PPG Industries Incorporated (Nouryon BV)
• Inventors: Temple, Chester S.
• Primary Examiner(s): Michl, Paul R.
• Application Number:
  US06/011,454
• Time in Patent Office: 680 Days
• Field of Search: 260/29.6 XA, 260/29.6 NR, 260/29.6 WB, 428/391, 428/392
• US Class Current: 524/188
• CPC Class Codes: C03C 25/30 Polyolefins
• CPC Class Codes: Y10T 428/2962 Silane, silicone or siloxane in coating
• CPC Class Codes: Y10T 428/2964 Artificial fiber or filament

Abstract

A binder composition and method for using same in sizing compositions for treating glass fibers is provided. The binder composition is an aqueous emulsion containing isotactic carboxylated polypropylene along with amorphous carboxylated polypropylene, base, and surfactant. The isotactic carboxylated polypropylene is incorporated in the emulsion by a method of co-emulsification of the isotactic and amorphous carboxylated polypropylene in a ratio of 1:1 to 1:4 parts by weight along with the base and surfactant. Water is added to the co-emulsified blend to obtain the emulsion with the desired solids content.

Claims

1. A size composition for treating glass fibers comprising:

(a) an aqueous emulsion of an isotactic carboxylated polypropylene and amorphous carboxylated polypropylene,

(b) coupling agent,

(c) a film former, and

(d) lubricant.

2. A size composition of claim 1 wherein the film former is a multifunctional polyurethane polymer.

3. A size composition of claim 1 wherein the coupling agent is an amino silane.

4. A size composition of claim 1 wherein the film former is selected from the group consisting of homopolymers and copolymers of vinyl acetates, epoxies, polyesters, polyurethanes, acrylic polymers and coreaction products thereof.

5. A size composition of claim 1 wherein the total solids on a non-aqueous basis of the size composition can range from about 2 to about 20 percent by weight.

6. A size composition for treating glass fibers comprising in percent by weight of the aqueous size composition:

(a) about 2 to about 15 percent of an aqueous emulsion of an isotactic carboxylated polypropylene and amorphous carboxylated polypropylene,

(b) about 0.1 to about 2.0 percent of an amino silane coupling agent,

(c) about 0.4 to about 12 percent of a film former selected from the group consisting of homopolymers and copolymers of epoxies, vinyl acetates, polyesters, polyurethanes and acrylic polymers, and

(d) about 0.2 to about 4 percent of a lubricant.

7. The sizing composition of claim 6 wherein the aqueous emulsion has present about 25 to about 99.5 percent by weight of the blend of isotactic carboxylated polypropylene and amorphous carboxylated polypropylene and about 0.5 to about 75 percent by weight of polyethylene.