Stampable reinforced thermoplastic polyester sheets

• US 4,263,364 A
• Filed: 12/14/1979
• Issued: 04/21/1981
• Est. Priority Date: 12/14/1979
• Status: Expired due to Term

• Current Assignee: Eastman Chemical Company
• Original Assignee: Eastman Kodak Company
• Inventors: Weaver, James C., Seymour, Robert W., Wright, Benny W.
• Primary Examiner(s): Bell, James J.
• Application Number:
  US06/103,806
• Time in Patent Office: 494 Days
• Field of Search: 428/284, 428/285, 428/286, 428/287, 428/298, 428/300, 428/430
• US Class Current: 428/300.7
• CPC Class Codes: B29C 51/002 characterised by the choice of material
• CPC Class Codes: B32B 2262/101 Glass fibres
• CPC Class Codes: B32B 2305/08 Reinforcements
• CPC Class Codes: B32B 2307/702 Amorphous
• CPC Class Codes: B32B 2367/00 Polyesters, e.g. PET, i.e. polyethylene terephthalate
• CPC Class Codes: B32B 27/12 next to a fibrous or filamentary layer
• CPC Class Codes: B32B 27/34 comprising polyamides
• CPC Class Codes: B32B 27/36 comprising polyesters
• CPC Class Codes: B32B 37/00 Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
• CPC Class Codes: Y10T 428/24995 Two or more layers
• CPC Class Codes: Y10T 428/31616 Next to polyester [e.g., alkyd]

Abstract

The object of the invention is to provide a stampable sheet of reinforced thermoplastic material, the sheet being composed of a plurality of layers of polyester material and a plurality of layers of reinforcing material integrally formed together, the central layer or layers of polyester material being of more slowly crystallizing material than the outer layers. The polyester layers are all substantially amorphous and are made of polyester polymers selected from poly(ethylene terephthalate), selected copolymers of poly(ethylene terephthalate), poly(1,4-cyclohexylenedimethylene terephthalate), selected copolymers of poly(1,4-cyclohexylenedimethylene terephthalate), blends of poly(ethylene terephthalate) and any of the aforementioned selected copolymers, and blends of poly(1,4-cyclohexylenedimethylene terephthalate) and any of the aforementioned selected copolymers, The central polyester layer or layers are polyester polymers selected from the aforementioned selected copolymers and blends.

Another object of the invention is to provide a stamped sheet from the stampable sheet of reinforced thermoplastic material, the stamped sheet having a heat deflection temperature under 264 psi. load greater than T_m -50° C.

Claims

1. A stampable sheet of reinforced thermoplastic material, said sheet comprising a plurality of layers of polyester material and a plurality of layers of reinforcing material integrally formed together, the central layer or layers of polyester material being of more slowly crystallizing material than the outer layers;

said polyester layers being substantially amorphous and made of polyester polymers selected from the group consisting of

a. poly(ethylene terephthalate);

b. copolymers of poly(ethylene terephthalate) having about 5 to about 50 mole percent of 1,4-cyclohexanedimethanol, neopentyl glycol, 2,2,4,4-tetramethyl-1,3-cyclobutanediol, bisphenol A, isophthalic acid or 1,4-cyclohexanedicarboxylic acid;

c. poly(1,4-cyclohexylenedimethylene terephthalate);

d. copolymers of poly(1,4-cyclohexylenedimethylene terephthalate) having about 20 to about 50 mole percent of ethylene glycol, neopentyl glycol, 2,2,4,4-tetramethyl-1,3-cyclobutanediol, bisphenol A, isophthalic acid, or 1,4-cyclohexanedicarboxylic acid;

e. blends of poly(ethylene terephthalate) with greater than 35 weight percent of any of said copolymers in item (b) or item (d); and

f. blends of poly(1,4-cyclohexylene dimethylene terephthalate) with greater than 35 weight percent of any of said copolymers in item (b) or item (d);

said outer polyester layers having a minimum crystallization half-time upon heating of one minute or less, and said central polyester layer or layers being selected from the polymers identified in items b, d, e or f above and having a minimum crystallization half-time upon heating of greater than one minute, the minimum crystallization half-time being that as measured with respect to each individual layer of said polyester material.

2. A stampable sheet as defined in claim 1, wherein said layers of reinforcing material are comprised of glass fiber.

3. A stampable sheet as defined in claim 1, wherein said sheet comprises at least three layers of said polyester material and at least two layers of glass fiber, said polyester layers being alternated with said glass fiber layers.

4. A stampable sheet as defined in claim 1, wherein said outer polyester layers comprise poly(ethylene terephthalate) having an inherent viscosity of about 0.3 to about 0.7 and a minimum crystallization half-time of about 40 seconds;

said central polyester layer or layers comprise copoly(69/31 ethylene terephthalate/1,4-cyclohexylenedimethylene terephthalate) having an inherent viscosity of about 0.60 and a minimum crystallization half-time of about 2650 minutes; and

said layers of reinforcing material comprise glass fibers;

said inherent viscosity being determined by a concentration of 0.5 grams polymer in 100 milliliter solvent (60% by weight phenol and 40% by weight tetrachloroethane), the polymer being dissolved at 125°

C. and being measured at 25°

C.

5. A stampable sheet as defined in claim 1, wherein said outer polyester layers comprise poly(ethylene terephthalate) having an inherent viscosity of about 0.3 to about 0.7 and a minimum crystallization half-time of about 40 seconds;

said central polyester layer or layers comprise copoly(87/13 ethylene terephthalate/1,4-cyclohexylenedimethylene terephthalate) having an inherent viscosity of about 0.65 and a minimum crystallization half-time of about 9 minutes; and

said layers of reinforcing material comprise glass fibers;

said inherent viscosity being determined by a concentration of 0.5 grams polymer in 100 milliliter of solvent (60% by weight phenol and 40% by weight tetrachloroethane), the polymer being dissolved at 125°

C. and being measured at 25°

C.

6. A stampable sheet as defined in claim 1, wherein said central layer or layers comprise a blend of poly(ethylene terephthalate) having about 50% by weight copoly(87/13 ethylene terephthalate/1,4-cyclohexylenedimethylene terephthalate) having an inherent viscosity of about 0.60 and a minimum crystallization half-time of about 1.5 minutes;

said inherent viscosity being determined by a concentration of 0.5 grams polymer in 100 milliliter of solvent (60% by weight phenol and 40% by weight tetrachloroethane), the polymer being dissolved at 125°

C. and being measured at 25°

C.

7. A stampable sheet as defined in claim 1, wherein the overall thickness of said sheet ranges from about 40 to about 250 mils, and said layers of glass fibers comprise about 20 to about 50% by weight of said stampable sheet.

8. A stampable sheet as defined in claim 1, wherein the overall thickness of said sheet ranges from about 50 to about 150 mils, and said layers of glass fibers comprise about 20 to about 50 percent by weight of said stampable sheet.

9. A stampable sheet as defined in claim 1, wherein the overall thickness of said sheet ranges from about 60 to about 100 mils, and said layers of glass fibers comprise about 30 to about 40% by weight of said stampable sheet.

10. A stamped sheet of reinforced thermoplastic material from the stampable sheet of claim 1 and having a heat deflection temperature under 264 psi. load greater than T_m -50°

C.

11. A stamped sheet as defined in claim 10, wherein said layers of reinforcing material are comprised of glass fiber.

12. A stamped sheet as defined in claim 10, wherein said sheet comprises at least three layers of said polyester material and at least two layers of glass fiber, said polyester layers being alternated with said glass fibers.

13. A stamped sheet of reinforced thermoplastic material from the stampable sheet of claim 4.

14. A stamped sheet of reinforced thermoplastic material from the stampable sheet of claim 5.

15. A stamped sheet of reinforced thermoplastic material from the stampable sheet of claim 6.