Process for preparing cold water-soluble films from PVA by melt extrusion

• US 4,267,145 A
• Filed: 08/25/1978
• Issued: 05/12/1981
• Est. Priority Date: 01/03/1974
• Status: Expired due to Term

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Wysong, Robert D.
• Primary Examiner(s): Woo, Jay H.
• Application Number:
  US05/936,795
• Time in Patent Office: 991 Days
• Field of Search: 264/185, 264/211, 264/176 R, 264/563, 264/564, 264/209, 260/29.6, 526/7
• US Class Current: 264/563
• CPC Class Codes: B29C 33/60 Releasing, lubricating or separating agents in general C10M
• CPC Class Codes: B65D 85/82 for poisons
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/14 Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
• CPC Class Codes: C08L 29/04 Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
• CPC Class Codes: C08L 71/02 Polyalkylene oxides

Abstract

Films, 0.5-10 mils thick, which are rapidly and completely soluble in cold water, and which are suitable for use as packaging film in automatic packaging equipment, can be prepared by conventional melt extrusion processes when prepared from a novel composition consisting essentially of 5-20 parts by weight of a polyethylene glycol (having an average molecular weight in the range between 325 and 550) in 100 parts by weight of a partially hydrolyzed low molecular weight polyvinyl alcohol.

Claims

1. A process for making a cold water-soluble film 0.5-10 mils thick comprising melt-extruding a composition consisting essentially of 5 to 20 parts by weight of a polyethylene glycol, having an average molecular weight in the range between 325 and 550 (based upon measurement of the hydroxyl content thereof obtained by esterification of said glycol with phthalic anhydride/pyridine), in 100 parts by weight of a low molecular weight polyvinyl alcohol which is about 85 to about 90 mol% hydrolyzed (determined by saponification) and has a viscosity in the range between about 3 and about 10 cps as measured on a 4% aqueous solution at 20°

C. (determined by the Hoeppler Falling Ball Method ASTM-D 1343-56, Part

     8).

2. A process of claim 1 wherein said polyethylene glycol is present in an amount in the range between about 12 and about 17 parts per 100 parts by weight of said polyvinyl alcohol.

3. A process of claim 2 wherein about 15 parts of said polyethylene glycol per 100 parts by weight of said polyvinyl alcohol are present.

4. A process of claim 1 wherein said polyvinyl alcohol has a viscosity between about 4 and about 6 cps.

5. A process of claim 1 wherein said polyethylene glycol has an average molecular weight between about 380 and about 420.

6. A process of claim 5 wherein said polyethylene glycol is present in an amount of 12--17 parts by weight per 100 parts of said polyvinyl alcohol.

7. A process of claim 6 wherein said film is 1-5 mil thick and said polyethylene glycol is present in an amount of about 15 parts by weight per 100 parts of said polyvinyl alcohol.

8. A process of claim 7 wherein the viscosity of said polyvinyl alcohol is between about 4 and about 6 cps.

9. A process for making a cold water-soluble film 1-5 mils thick according to claim 1 wherein said composition contains 2 parts or less by weight per 100 parts of polyvinyl alcohol of a water-soluble polymer, said polymer being selected from polyethers of the formula --[CH₂ CH₂ O]_n -- with a molecular weight of at least 600 which are sometimes referred to as polyethylene glycols and sometimes as polyethylene oxides, polypropylene glycol having an average molecular weight of at least 400, and ethylene oxide/propylene oxide copolymers having an average molecular weight of at least 400.

10. A process of claim 1 wherein said film is 1-5 mils thick and said composition contains 5 parts or less by weight of an adjuvant per 100 parts by weight of said polyvinyl alcohol, said adjuvant being selected from antioxidants, release agents, anti-block agents, slip agents and fillers.

11. A process of claim 10 wherein said adjuvant is a slip agent.

12. A process of claim 11 wherein said slip agent is selected from calcium stearate, magnesium stearate, hydrated sodium silico-aluminate, and mixtures thereof.

13. A process of claim 12 wherein said slip agent is a mixture of magnesium stearate and hydrated sodium silico-aluminate.