Solid state, ambient temperature electrochemical cell

• US 4,268,587 A
• Filed: 10/11/1977
• Issued: 05/19/1981
• Est. Priority Date: 10/11/1977
• Status: Expired due to Term

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Farrington, Gregory C., Roth, Walter L.
• Primary Examiner(s): Walton, Donald L.
• Application Number:
  US05/840,997
• Time in Patent Office: 1,316 Days
• Field of Search: 429/191, 429/193, 429/218, 429/194
• US Class Current: 429/320
• CPC Class Codes: H01M 10/3909 Sodium-sulfur cells
• CPC Class Codes: H01M 6/18 with solid electrolyte
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A solid state, ambient temperature electrochemical cell is described which includes a lithium type or a sodium type anode, a cathode of pressed sulfur and carbon containing therein a nominal amount of a non-aqueous solvent with ionic conductivity enhancing material, a solid ion-conducting electrolyte between and in contact with the anode and the cathode, and a casing enclosing the anode, the cathode and the electrolyte. Such a cell is described also which includes a liquid mercury-indium alloy on at least a portion of the solid ion-conducting electrolyte in contact with the anode.

Claims

1. A sealed solid state, ambient temperature electrochemical cell comprises a casing including an anode compartment and a cathode compartment, the compartments insulated electrically from each other, an anode positioned within and in electrical contact with the anode compartment, the anode selected from the class consisting of lithium, lithium as an amalgam, alloys of lithium with aluminum or silicon, sodium, sodium as an amalgam or alloys of sodium with aluminum or silicon, a cathode positioned within and in electrical contact with the cathode compartment, the cathode comprising pressed sulfur powder and carbon powder containing therein a nominal amount of a non-aqueous solvent with ionic conductivity enhancing materials, and a solid ion-conducting electrolyte positioned between the anode and the cathode and in contact with both the anode and the cathode, the solid electrolyte selected from the class consisting of sodium beta-alumina, sodium beta"-alumina, or lithium-sodium aluminate having an approximate composition of LiNaO.9Al₂ O₃ of which 1.3 to 85.0 percent of the total alkali ion content is lithium.

2. A solid state, ambient temperature electrochemical cell as in claim 1, in which a liquid mercury-indium alloy layer adheres intimately to one major surface of the electrolyte adjacent to and in contact with the anode.

3. A sealed solid state, ambient temperature electrochemical cell comprises a casing including an anode compartment and a cathode compartment, the compartment insulated electrically from each other, a solid sodium anode positioned within and in electrical contact with the anode compartment, a cathode positioned within and in electrical contact with the cathode compartment, the cathode comprising pressed sulfur powder and carbon powder containing a polytetrafluoroethylene binder in a ratio of 60%:

30%;

10% and containing one drop of propylene carbonate with 0.2 M tetrabutylammonium tetrafluoroborate and 0.2 M NaClO₄, a nickel screen current collector pressed into the cathode, a solid sodium beta-alumina electrolyte, a liquid mercury-indium alloy layer adhering intimately to a portion of one major surface of the electrolyte, the electrolyte positioned between the anode and the cathode, the anode in contact with the mercury-indium alloy layer, and the cathode in contact with the opposite major surface of the electrolyte.