Methods of detection with surface acoustic wave and apparati therefor

• US 4,312,228 A
• Filed: 07/30/1979
• Issued: 01/26/1982
• Est. Priority Date: 07/30/1979
• Status: Expired due to Term

• Current Assignee: Henry Wohltjen
• Original Assignee: Henry Wohltjen
• Inventors: Wohltjen, Henry
• Primary Examiner(s): Gill, James J.
• Application Number:
  US06/062,019
• Time in Patent Office: 911 Days
• Field of Search: 73/596, 73/597, 73/599, 73/23, 73/23.1, 73/24, 310/313 R
• US Class Current: 73/597
• CPC Class Codes: G01N 2291/0256 Adsorption, desorption, surface mass change, e.g. on biosensors
• CPC Class Codes: G01N 2291/02827 Elastic parameters, strength or force
• CPC Class Codes: G01N 2291/0421 Longitudinal waves
• CPC Class Codes: G01N 29/022 Fluid sensors based on microsensors, e.g. quartz crystal-microbalance [QCM], surface acoustic wave [SAW] devices, tuning forks, cantilevers, flexural plate wave [FPW] devices microdevices per se B81B

Abstract

The invention is in the monitoring of physical parameters relating to various fluids and polymers by contacting same with the surface of a piezoelectric material unit through which is passing a surface acoustic wave, and measuring the alteration of that wave as an indication of these parameters. The invention is also in apparati for monitoring certain of said parameters.

Claims

1. A method detecting information relating to a polymer which comprises generating in a piezoelectric material element a surface acoustic wave;

during the traveling of the surface acoustic wave through the piezoelectric material element, contacting a thin layer of the polymer with the surface through which the wave travels;

subjecting the thin layer to a variation in environment during said contact thereby modifying a property of the polymer and changing either or both of the velocity of sound in, and a dielectric property of, the polymer so as to alter one or more of the frequency, amplitude and phase of the surface acoustic wave; and

measuring said alteration as an indication of the modification of the polymer property during the variation in environment.

2. A method as defined in claim 1, wherein an alteration in the amplitude of the surface acoustic wave is measured.

3. A method as defined in claim 1, wherein an alteration in the phase of the surface acoustic wave is measured.

4. A method as defined in claim 1, wherein the thin layer of polymer is about 10 mils thick.

5. A method as defined in claim 1, which comprises clamping the thin layer of the polymer to the surface of the piezoelectric material.

6. A method as defined in claim 1, which comprises casting the thin layer of the polymer on the surface of the piezoelectric material.

7. A method of detecting the glass transition temperature of a polymer, which consists essentially of generating in a piezoelectric material element a surface acoustic wave;

during the traveling of the surface acoustic wave through the piezoelectric material element, contacting a thin layer of the polymer with the surface through which the wave travels;

subjecting the thin layer of the polymer to increasing temperature during said contact, thereby changing either or both of the velocity of sound in, and a dielectric property of, the polymer so as to alter one or more of the frequency, amplitude and phase of the surface acoustic wave; and

measuring the maximum alteration and correlating it with the temperature at which said maximum alteration occurred.

8. A method of detecting the rate of solvent evaporation from a polymer which consists essentially of generating in a piezoelectric material element a surface acoustic wave;

during the traveling of the surface acoustic wave through the piezoelectric material element, contacting the polymer, in solution with a solvent, with the surface through which the travels;

evaporating the solvent, thereby changing either or both of the velocity of sound in, and a dielectric property of, the polymer or polymer solution so as to alter one or more of the frequency, amplitude and phase of the surface acoustic wave; and

measuring said alteration as an indication of the course of solvent evaporation.

9. A method of monitoring photo-crosslinking of a polymer, which consists essentially of generating in a piezoelectric material element a surface acoustic wave;

during the traveling of the surface acoustic wave through the piezoelectric material element, contacting a thin layer of the polymer with the surface through which the wave travels;

subjecting the thin layer of the polymer to irradiation thereby causing crosslinking of the polymer and changing either or both of the velocity of sound in, and a dielectric property of, the polymer so as to alter one or more of the frequency, amplitude and phase of the surface acoustic wave; and

measuring said alteration as an indication of the extent of said crosslinking.

10. A method of detecting a crystalline transition in a polymer, which consists essentially of generating in a piezoelectric material element a surface acoustic wave;

during the traveling of the surface acoustic wave through the piezoelectric material element, contacting a thin layer of the polymer with the surface through which the wave travels;

subjecting the thin layer of polymer to increasing temperature which is below the glass transition temperature during said contact thereby changing either or both of the velocity of sound in, and a dielectric property of, the polymer so as to alter one or more of the frequency, amplitude and phase of the surface acoustic wave; and

measuring said alteration and correlating same with the temperature or temperature range at which it occurs.

11. A surface acoustic wave apparatus for detecting information relating to a polymer during variation in its environment, which comprises a piezoelectric material element disposed for contact of a surface thereof with a thin layer of the polymer;

contacting means operatively associated with the piezoelectric material element and adapted for maintaining contact between said surface and the thin layer of polymer;

oscillation-generating means operatively associated with the piezoelectric material element to induce a surface acoustic wave in said surface of the piezoelectric material element; and

detecting means operatively associated with the piezoelectric material element and adapted for measuring alteration of one or more of the frequency, amplitude and phase of the surface acoustic wave due to modification of a property of the polymer and concomitant change in either or both of the velocity of sound in, and a dielectric property of, the polymer.

12. A surface acoustic wave detection apparatus as defined in claim 11, wherein the piezoelectric material is selected from the group consisting of quartz and lithium niobate.

13. A surface acoustic wave detection apparatus as defined in claim 11, wherein the contacting means is clamping means.

14. A surface acoustic wave apparatus for detecting information relating to a polymer during a change in its environment, which comprises a block having in one of its faces a cavity adapted for receiving a piezoelectric material element;

a piezoelectric material element mounted in said cavity and disposed for contact of a surface thereof with a thin layer of the polymer;

clamping means mounted on said block and operatively associated with the piezoelectric material element and adapted for maintaining contact between said surface and the thin layer of polymer;

a first transducer which interfaces with the piezoelectric material element;

a second transducer interfacing with said element and adapted to sample a surface acoustic wave traveling therethrough and convert same to an electrical signal;

oscillation-generating means electrically connected to said first transducer to induce a surface acoustic wave in said surface of the piezoelectric material element; and

detecting means electrically connected to said second transducer, said detecting means being adapted for measuring alteration in the electrical signal from the second transducer corresponding to an alteration of one or more of the frequency, amplitude and phase of the surface acoustic wave due to modification of a property of the polymer and concomitant change in either or both of the velocity of sound in, and a dielectric property of, the polymer.

15. A surface acoustic wave detecting apparatus as defined in claim 14, wherein said transducer and second transducer each is an interdigital electrode abutting said piezoelectric material element.

16. A surface acoustic wave detecting apparatus as defined in claim 14, wherein the transducer and second transducer each is of aluminum or a chromium and gold alloy.