Base coats covered by a clear lacquer coating and process for coating

• US 4,315,053 A
• Filed: 05/28/1980
• Issued: 02/09/1982
• Est. Priority Date: 02/16/1978
• Status: Expired due to Term

• Current Assignee: BASF Farben & Fasern AG
• Original Assignee: BASF Farben & Fasern AG
• Inventors: Poth, Ulrich, Moller, Dieter, Dobbelstein, Arnold
• Primary Examiner(s): Lusignan, Michael R.
• Application Number:
  US06/153,852
• Time in Patent Office: 622 Days
• Field of Search: 427/385.5, 427/388.2, 427/388.5, 427/409, 427/388.3, 427/389.7, 427/393.5, 427/407.2, 427/412.1, 428/458, 428/423.7, 428/424.4, 428/425.3, 428/430, 428/442, 428/463, 428/483, 525/157, 525/443
• US Class Current: 428/423.7
• CPC Class Codes: C08G 63/20 Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
• CPC Class Codes: C08G 63/48 by unsaturated higher fatty oils or their acids; by resin acids
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 33/08 Homopolymers or copolymers of acrylic acid esters
• CPC Class Codes: C08L 61/20 Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen with aminophenols C08L61/04
• CPC Class Codes: C08L 67/00 Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain of polyester-amides C08L77/12; of polyester-imides C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: C09D 167/00 Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain based on polyester-amides C09D177/12; based on polyester-imides C09D179/08; Coating compositions based on derivatives of such polymers
• CPC Class Codes: Y10T 428/31565 Next to polyester [polyethylene terephthalate, etc.]
• CPC Class Codes: Y10T 428/31576 Ester monomer type [polyvinylacetate, etc.]
• CPC Class Codes: Y10T 428/31594 Next to aldehyde or ketone condensation product [phenol-aldehyde, etc.]
• CPC Class Codes: Y10T 428/31616 Next to polyester [e.g., alkyd]
• CPC Class Codes: Y10T 428/31649 Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31681 Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
• CPC Class Codes: Y10T 428/31699 Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31797 Next to addition polymer from unsaturated monomers

Abstract

An article having a substrate and a multilayer coating composition adhered thereto. The multilayer coating has a pigmented base film and deposited on the base film is a transparent coating which has no intermixing and no intersolution between the base coating and the transparent coating. The transparent coating is a cross linking resin containing hydroxyl groups obtained by esterifying polycarboxylic acids with polyols.

Claims

1. In an article having a substrate and a multilayer coating composition adhered thereto, said composition comprising:

A. a dried nonaqueous base film produced from a composition comprising;

1. a first film-forming material selected from the group consisting of alkyd resins, polyester resins, acrylic resins, and polyurethane resins, wherein said first film-forming material contains from about 2 to about 50 weight percent, based on the film-forming solids, of a cellulose ester,

2. uniformly dispersed pigments, and

3. volatile organic solvents for said first film-forming material, and

B. a baked transparent coating composition deposited on said base film in a relationship to maintain substantially no intermixing and no intersolution of said base film and said transparent coating composition, said transparent coating composition comprising;

1. a second film-forming material selected from the group consisting of alkyd resins, polyester resins, acrylic resins and polyurethane resins, and

2. volatile organic solvents for said second film-forming material, the improvement comprising;

said second film-forming material consisting essentially of polyester resins comprising a crosslinking resin containing hydroxyl groups obtained by esterifying polycarboxylic acids selected from the group consisting of aliphatic polycarboxylic acids, cycloaliphatic polycarboxylic acids, and mixtures thereof with polyols selected from the group consisting of aliphatic polyols, cycloaliphatic polyols and mixtures thereof.

2. The article of claim 1, wherein said transparent coating composition contains a hydroxyl group containing acrylate resin as a further film-forming component.

3. The article of claim 2, wherein said hydroxyl group containing acrylate resin is free from aromatic groups.

4. The article of claim 2, wherein said hydroxyl group containing acrylate resin holds up to 15% by weight of monomers containing aromatic groups polymerized therein.

5. The article of claim 1, wherein said transparent coating composition contains:

10 to 40% by weight of aminoplast resin

60 to 90% by weight of a mixture of

5 to 100% by weight of a polyester resin containing hydroxyl groups, an alkyl resin, or a mixture thereof, and

0 to 95% by weight of acrylate resin containing hydroxyl groups,

where the same sums of the percentages by weight amount to 100%.

6. The article of claim 5, wherein said transparent coating composition further contains synthetic resins different from but compatible with the polyester resins, alkyd resins, acrylate resins and aminoplast resins.

7. The article of claim 1, wherein said polycarboxylic acid component of the hydroxyl group containing polyester resin contains cycloaliphatic polycarboxylic acids of the general formula ##STR5## where R stands for a non-substituted alkylene residue with 1 to 4 C atoms, or which is substituted by at least one --COOR₃ residue and/or a methyl group, or for residues of the general formula ##STR6## wherein R₁ =H or --COOR₃ or CH₃ --;

R₂ =H or CH₃ --;

R₃ =H or an alkyl residue with 1 to 4 C atoms of a hydroxylalkyl residue with 1 to 4 C atoms;

R₄ =H or --COOR₃ ;

n=0, 1 or 2.

8. The article of claim 1, wherein the polyester resins are modified by saturated fatty acids, unsaturated fatty acids and mixtures thereof, being esterified therein.

9. The article of claim 1, wherein the polyester resins contain aromatic monocarboxylic acids esterified therein.

10. The article of claim 5, wherein the polyol component of the polyester resin containing hydroxyl groups or of the alkyd resin contains cycloaliphatic polyols of the general formula ##STR7## where X₁ =X₂ =H or CH₃ --;

X₃ =OH-- or ##STR8## n=0 or 1.

11. The article of claim 1, wherein said base film contains organic or inorganic pigments or mixtures thereof.

12. The article of claim 1, wherein said base film contains metal pigments.

13. In a process for preparing an article having a substrate and a multilayer coating composition adhered thereto, comprising:

A. depositing a nonaqueous base film with drying a composition comprising;

1. a first film-forming material selected from the group consisting of alkyd resins, polyester resins, acrylic resins, and polyurethane resins, wherein said first film-forming material contains from about 2 to about 50 weight percent, based on the film-forming solids, of a cellulose ester,

2. uniformly dispersed pigments, and

3. volatile organic solvents for said first film-forming material, and

B. depositing with baking a transparent coating composition on said base film in a relationship to maintain substantially no intermixing and no intersolution of said base film and said transparent coating composition, said transparent coating composition comprising;

1. a second film-forming material selected from the group consisting of alkyd resins, polyester resins, acrylic resins and polyurethane resins, and

2. volatile organic solvents for said second film-forming material,

the improvement comprising;

said second film-forming material consisting essentially of polyester resins comprising a crosslinking resin containing hydroxyl groups and obtained by esterifying polycarboxylic acids selected from the group consisting of aliphatic polycarboxylic acids, cycloaliphatic polycarboxylic acids and mixtures thereof with polyols selected from the group consisting of aliphatic polyols, cycloaliphatic polyols and mixtures thereof.

14. The process of claim 13, wherein said transparent coating composition is deposited wet-on-wet on a last enamel layer containing the pigments and/or metal pigments and both layers are baked simultaneously.