Hydroprocessing reactor with extended operating life

• US 4,330,505 A
• Filed: 12/04/1980
• Issued: 05/18/1982
• Est. Priority Date: 12/04/1980
• Status: Expired due to Term

• Current Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Original Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Inventors: Gupta, Ramesh
• Primary Examiner(s): Clements, Gregory N.
• Application Number:
  US06/212,755
• Time in Patent Office: 530 Days
• Field of Search: 422/115, 422/217, 422/191, 422/171, 422/193, 422/195, 422/220, 261/94-98
• US Class Current: 422/217
• CPC Class Codes: B01J 8/0278 Feeding reactive fluids for solid material B01J8/0015
• CPC Class Codes: B01J 8/0453 the beds being superimposed one above the other
• CPC Class Codes: B01J 8/0492 Feeding reactive fluids for solid material, see B01J8/0015
• CPC Class Codes: C10G 49/002 Apparatus for fixed bed hydrotreatment processes

Abstract

The invention is for a fixed bed reactor with two phase gas and liquid flow. The reactor has at least one auxiliary bed of solid particles disposed above the main bed of solid particles. The auxiliary bed has separate liquid and gas bypasses comprised of hollow tubing extending through the auxiliary bed. Liquid receptacles provide a liquid seal above the liquid bypasses, thereby preventing gas from bypassing along with the liquid. The liquid spilled from the flow receptacles seeks its lowest level and flows through the auxiliary bed, thereby leaving only the gas to flow through the gas bypasses. This separate feed arrangement allows for a low pressure drop bypassing of the auxiliary bed, when the auxiliary bed becomes fouled and clogged. The invention is also applicable to other apparatuses which use a flow arrangement similar to fixed bed reactors, but which do not necessarily utilize a chemical reaction. One example of such apparatus is a packed absorption tower having co-current downflow of gas and liquid.

Claims

1. A reactor for reacting a two phase, gas and liquid mixture in a fixed bed of solids, comprising:

a vessel;

means to introduce both liquid and gas into said vessel;

means to remove both liquid and gas from said vessel;

at least one auxiliary bed disposed above said main bed, at least one gas bypass tube for passing gas through said auxiliary bed when said bed becomes fouled and at least one liquid bypass, said liquid bypass comprising a liquid receptacle disposed on top of a hollow unobstructed open tube extending through said auxiliary bed and located directly below said means to introduce liquid into said vessel, said liquid receptacle receiving liquid introduced into said vessel and allowing said liquid to spill over to said auxiliary bed when said auxiliary bed is not fouled, said unobstructed open tube having a flow resistance sufficient to act as a liquid seal against the passage of gas through said liquid bypass tube when said auxiliary bed is not fouled and to provide a low pressure drop bypass for said liquid flowing to said main bed when said auxiliary bed becomes fouled.

2. The reactor of claim 1, wherein there are at least two auxiliary beds disposed in tiers above said main bed, each having at least one liquid bypass.

3. The reactor of claim 2, further comprising a flow distributor above each bed.

4. The reactor of claim 1, further comprising a flow distributor above each bed.

5. The reactor of claim 1, wherein said beds comprise at least one catalyst.

6. The reactor of claim 5, wherein said catalyst consists of metals alone or in mixture, selected from the group:

cobalt, molybdenum and nickel, disposed on an alumina support.

7. The reactor of claim 1, wherein said means for passing gas through said auxiliary bed comprises at least one separate gas bypass tube.