Gas detector

• US 4,343,768 A
• Filed: 07/23/1980
• Issued: 08/10/1982
• Est. Priority Date: 07/25/1979
• Status: Expired due to Term

• Current Assignee: Ricoh Company Limited
• Original Assignee: Ricoh Company Limited
• Inventors: Kimura, Mitsuteru
• Primary Examiner(s): Serwin, Ronald E.
• Application Number:
  US06/171,387
• Time in Patent Office: 748 Days
• Field of Search: 422/95, 422/97, 422/98, 23/232 E, 73/23, 324/71 R, 338/34
• US Class Current: 422/97
• CPC Class Codes: G01N 27/12 of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid , for detecting components in the fluid
• CPC Class Codes: G01N 27/16 caused by burning or catalytic oxidation of surrounding material to be tested, e.g. of gas

Abstract

A gas detector of the type using an electric heater in which a substrate consists of an upper film of electrically insulating substance having a resistance to heat and a lower film of substance different from the substance of the upper film, a recess is formed below or under the upper film by removing part of the lower film, and a film of electrically conductive substance is deposited over the bridge of the upper film across the recess in the lower film, thereby providing a heating element characterized in that said heating element consists of a film of a substance having catalytic effects in the presence of a gas to be detected deposited on said electrically conductive substance or a material responsive to a gas to be detected, or consists of said electrically conductive substance having catalytic effects in the presence of a gas to be detected or a substance containing said substance having catalytic effects in the presence of a gas to be detected or a substance responsive to a gas to be detected, and said heating element is exposed to a gas to be detected.

Claims

1. A gas detector of the type using an electric heater in which a substrate comprises an upper film and a lower film, said upper film being made of an electrically insulating substance having a resistance to heat while said lower film is made of a substance different from that of said upper film;

a recess is formed under said upper film by removing part of said lower film; and

an electrically conductive substance is disposed on said upper film at a portion immediately above said recess, thereby providing a heating element, characterized in that

the heating element consists of a film of a substance having catalytic effects in the presence of a gas to be detected, or a material responsive to a gas to be detected, deposited on said electrically conductive substance, or consists of said electrically conductive substance having catalytic effects in the presence of a gas to be detected or a substance containing said substance having catalytic effects in the presence of a gas to be detected or a substance responsive to a gas to be detected, and said heating element is exposed to a gas to be detected.

2. A gas detector as set forth in claim 1 further characterized in that a catalytic or gas responsive film is formed over said electrically conductive substance film directly or through an electrically insulating film.

3. A gas detector as set forth in claim 1 further characterized in that an electrically insulating film is formed over said electrically conductive substance film, a film of a substance having a high temperature coefficient of resistance in an operating temperature range is formed over said electrically insulating film, and a catalytic or gas responsive film is formed over said second mentioned film directly or through an electrically insulating film.

4. A gas detector as set forth in claim 1 further characterized in that two bridges across said recess of said upper film are formed in relatively closely spaced apart relationship, said electrically conductive substance is deposited over said upper film in such a way that said two bridges become heating elements, and one of the electrodes is connected in common to said heating elements.

5. A gas detector as set forth in claim 1 further characterized in that two bridges of said upper film are formed across said recess in relatively closely spaced apart relationship, and said electrically conductive substance is deposited over said upper film in such a way that said bridges become heating elements.

6. A gas detector as set forth in claim 5 further characterized in that one of said heating elements is coated with a substance which will not respond to a gas to be detected.

7. A gas detector as set forth in claim 1 further characterized in that said slit is provided in the form of a closed rectangular loop, and one pair of the parallel sides of said closed rectangular slit are projected inwardly in such a way that a pair of symmetrical projections are formed and separated from each other by a suitable distance.

8. A gas detector as set forth in claim 1 further characterized in that said bridge of said electrically conductive film has such an electrical resistance distribution that the resistance is gradually increased from the center to the ends of said bridge.

9. A gas detector as set forth in claim 1 further characterized in that the bridge of said lower film immediately under the bridge of said electrically conductive film is removed.

10. A gas detector of the type using an electric heater in which a substrate comprises an upper film and a lower film, said upper film being made of an electrically insulating substance having a resistance to heat while said lower film being made of a substance different from that of said upper film;

a recess is formed under said upper film by removing part of said lower film; and

an electrically conductive substance is disposed on said upper film at a portion immediately above said recess, thereby providing a heating element, characterized in that said heating element consists of said electrically conductive substance combined with a substance having catalytic effects in the presence of a gas to be detected or with a substance responsive to a gas to be detected, and said heating element is exposed to a gas to be detected.

11. A gas detector comprising

(a) a substrate,

(b) at least one recess formed in said substrate,

(c) an electrically insulating film which is formed to bridge across said recess at the portion at which is formed a heater for detecting a gas, and

(d) an electrically conductive film which is formed over said electrically insulating film so as to provide said heater and electrodes.

12. A gas detector as set forth in claim 11 wherein a catalytic layer is formed over said heater of said electrically conductive film.

13. A gas detector as set forth in claim 12 wherein an electrically insulating film is interposed between said catalytic film and said heater.

14. A gas detector as set forth in claim 12 or 13 wherein said catalytic layer comprises a metal oxide containing at least Pt and/or Pd.

15. A gas detector as set forth in claim 11 wherein said electrically conductive film and/or said electrically insulating film is so formed as to attain a uniform temperature distribution.

16. A gas detector as set forth in claim 15 wherein said electrically insulating film has a curved configuration.

17. A gas detector, comprising:

(a) a substrate,

(b) at least one recess formed in said substrate,

(c) an electrically insulating film which is formed to bridge said recess at the portion at which is formed a heater for detecting a gas,

(d) an electrically conductive film which is formed on said electrically insulating film so as to provide said heater and electrodes, and

(e) a catalytic film which is formed over said heater of said electrically conductive film.