Powdery coating media and their use

• US 4,355,058 A
• Filed: 08/14/1978
• Issued: 10/19/1982
• Est. Priority Date: 08/25/1977
• Status: Expired due to Term

• Current Assignee: Chemische Werke Huls Aktiengesellschaft
• Original Assignee: Chemische Werke Huls Aktiengesellschaft
• Inventors: Gras, Rainer, Wolf, Elmar, Obendorf, Johann
• Primary Examiner(s): Nielsen, Earl A.
• Application Number:
  US05/933,583
• Time in Patent Office: 1,527 Days
• Field of Search: 528/45, 528/117, 528/367, 525/438, 525/528, 525/110, 525/111, 260/37 EP, 427/195, 427/386
• US Class Current: 427/386
• CPC Class Codes: C08G 18/58 Epoxy resins C08G18/42, C08G18/48 take precedence; reaction products of epoxy resins with at least equivalent amounts of compounds containing active hydrogen C08G18/6407, with at least equivalent amounts of amines C08G18/6415; polymeric products of isocyanates or isothiocyanates with epoxy compounds having no active hydrogen C08G18/003
• CPC Class Codes: C08G 18/808 Monoamines
• CPC Class Codes: C08G 59/4014 Nitrogen containing compounds
• CPC Class Codes: C08G 59/56 together with other curing agents
• CPC Class Codes: C09D 163/00 Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins

Abstract

Storage stable epoxy resin powder coating compositions are disclosed, which contain a solid epoxy resin and, as hardening agent, a blocked polyisocyanate compound or isocyanate terminated polymer, wherein the blocking agent is an imidazoline compound.

Claims

1. A curable finely divided solid composition comprising (1) an epoxy compound having more than one 1,2-epoxide group and having a lower fusion point of at least 40°

C. and (2) 2-15%, by weight, based on the solid epoxy compound, of a blocked polyisocyanate formed by the reaction of a polyisocyanate with a compound of the formula ##STR3## wherein each R is independently selected from hydrogen, alkyl, cycloalkyl, aralkyl, and aryl radicals.

2. A curable finely divided solid composition comprising (1) an epoxy compound having more than one 1,2-epoxide group and having a lower fusion point of at least 40°

C. and (2) 2-15% by weight, based on the solid epoxy compound, of a blocked polyisocyanate formed by the reaction of (a) an isocyanate terminated prepolymer obtained by reaction of a polyol with a polyisocyanate, with (b) a compound of the formula ##STR4## wherein each R is independently selected from hydrogen, alkyl, cycloalkyl, aralkyl, and aryl radicals.

3. A curable finely divided solid coating composition having a particle size of less than 0.25 mm comprising:

(i) an epoxy compound having more than one 1,2-epoxide group and having a lower fusion point greater than 40°

C.;

(ii) lacquer additives; and

(iii) 2-15 wt.% based on the solid epoxy compound of polyisocyanates blocked with cyclic amidines of the formula;

##STR5## wherein the R'"'"'s are the same or different and are selected from the group consisting of hydrogen, alkyl, cycloalkyl, aralkyl and aryl.

4. The coating composition of claim 3, wherein the polyisocyanate blocked with cyclic amidines is blocked diisocyanate of the general formula:

##STR6## wherein n is 0 or 1, X is O, S or an NH group, R'"'"' is an alkylene, cycloalkylene or arylene radical and R" is a saturated or unsaturated alkylene group with 2-18 C atoms optionally substituted by one or more alkyl radicals, where more than one radical can also jointly form a component of a cycloaliphatic ring, and optionally containing one or more oxygen or sulfur atoms in the hydrocarbon chain, or it is a cycloalkylene group.

5. A method for preparing the coating composition which comprises:

a. admixing a solid epoxide compound having more than one 1,2-epoxide group and having a lower fusion point of greater than 40°

C. with a polyisocyanate blocked by a cyclic amidine of the formula;

##STR7## wherein the R'"'"'s are the same or different and are selected from the group consisting of hydrogen, alkyl, cycloalkyl, aralkyl and aryl;

b. extruding the admixture at a temperature at least 30°

C. below the splitting temperature of said blocked polyisocyanate; and

c. grinding the extruded mixture to a particle size less than 0.25 mm.

6. The method of claim 5, wherein a lacquer additive is admixed with said solid epoxide compound and blocked isocyanate prior to extrusion.

7. The method of claim 5, wherein the extruded mixture is ground to a particle size of less than 100μ

.

8. The method of claim 5, wherein the extruded mixture is ground to a particle size of between 20 and 60μ

.

9. The method of claim 5, wherein the extruded mixture is ground to a particle size of between 10 and 50μ

.

10. A method of coating a substrate which comprises:

a. applying to said substrate the coating composition comprising;

(i) an epoxy compound having more than one 1,2-epoxide group and having a lower fusion point greater than 40°

C.;

(ii) lacquer additives; and

(iii) 2-15% based on the solid epoxy compound of polyisocyanates blocked with cyclic amidines of the formula;

##STR8## wherein the R'"'"'s are the same or different and are selected from the group consisting of hydrogen, alkyl, cycloalkyl, aralkyl and aryl; and

b. heating at a temperature above the splitting temperature of the blocked polyisocyanate.