Aqueous polymeric latex coating compositions, products produced thereby, methods for preparing such compositions, and methods for using such compositions

• US 4,374,670 A
• Filed: 06/16/1977
• Issued: 02/22/1983
• Est. Priority Date: 06/16/1977
• Status: Expired due to Term

• Current Assignee: Solutia Incorporated (Eastman Chemical Company)
• Original Assignee: Monsanto Company (Bayer AG)
• Inventors: Slocombe, Robert J.
• Primary Examiner(s): Kight, III, John
• Assistant Examiner(s): Yarbrough, Amelia B.
• Application Number:
  US05/807,267
• Time in Patent Office: 2,077 Days
• Field of Search: 106/20, 106/23, 204/159.16, 260/29.6 N, 524/460
• US Class Current: 522/33
• CPC Class Codes: C09D 11/02 Printing inks C09D11/30 takes precedence
• CPC Class Codes: C09D 11/101 Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing

Abstract

The invention concerns compositions for producing adherent polymeric coatings on a variety of substrates. The coating compositions comprise polymeric latices of colloidal polymer particles of at least one polymer capable of being deposited in the form of a film. In addition to the film-forming polymer, the coating composition comprises a discrete latex component which is a precursor of a material aiding rapid film formation through inter-reaction with the polymer particles, and may also have an affinity toward the substrate so as to function as a linking agent. This material can cause film formation by disrupting the colloidal stability of the polymer particles. It is possible to select as the discrete latex component a precursor of a material which has the dual function of increasing speed of film formation while fostering the adherence and bonding of the film to the substrate because of the material'"'"'s relative affinities for the polymer and for the substrate.

Claims

1. A printing ink comprising

(i) a pigment and

(ii) a liquid coating composition comprising

(a) colloidal polymer particles of at least one polymer capable of being deposited in the form of a film;

(b) a precursor of a material capable of disrupting the colloidal stability of the polymer particles to cause film formation when said printing ink is applied to a substrate; and

(c) a liquid dispersion medium.

2. The printing ink of claim 1, wherein said precursor (b) has an affinity for the polymer (a) and an affinity for said substrate, said precursor (b) being capable of acting as an adhesion-promoting linking agent between said polymer (a) and said substrate.

3. The printing ink of claim 1, in the form of an aqueous latex of the polymer particles.

4. The printing ink of claim 3, wherein said precursor (b) is a polyelectrolyte.

5. The printing ink of claim 3, wherein said precursor (b) is a non-ionic polymer containing dipoles.

6. The printing ink of claim 3, wherein said percursor (b) is a non-ionic polymer capable of forming hydrogen bonds.

7. The printing ink of claim 1, including at least one of a UV sensitizer and a heat sensitizer.

8. The printing ink of claim 3, including at least one of a UV sensitizer and a heat sensitizer.

9. The printing ink of claim 4, including at least one of a UV sensitizer and a heat sensitizer.

10. The printing ink of claim 6, including at least one of a UV sensitizer and a heat sensitizer.

11. The printing ink of claim 3, wherein the polymer (a) contains at least one of acid and basic functional groups.

12. The printing ink of claim 4, wherein the polymer (a) contains at least one of acid and basic functional groups.

13. The printing ink of claim 6, wherein the polymer (a) contains at least one of acid and basic functional groups.

14. The printing ink of claim 11, wherein said polymer (a) is an acrylic acid or methacrylic acid copolymer.

15. The printing ink of claim 12, wherein said polymer (a) is an acrylic acid or methacrylic acid copolymer.

16. The printing ink of claim 13, wherein said polymer (a) is an acrylic acid or methacrylic acid copolymer.

17. The printing ink of claim 11, wherein said precursor (b) is a polymerizable amine.

18. The printing ink of claim 12, wherein said precursor (b) is a polymerizable amine.

19. The printing ink of claim 13, wherein said precursor (b) is a polymerizable amine.

20. The printing ink of claim 17, wherein the polymerizable amine is selected from the group consisting of N,N-dialkylaminoalkyl acrylates, N,N-dialkylaminoalkyl methacrylates, N-vinyl pyrrolidones, acrylamide and methacrylamide.

21. The printing ink of claim 18, wherein the polymerizable amine is selected from the group consisting of N,N-dialkylaminoalkyl acrylates, N,N-dialkylaminoalkyl methacrylates, N-vinyl pyrrolidones, acrylamide and methacrylamide.

22. The printing ink of claim 19, wherein the polymerizable amine is selected from the group consisting of N,N-dialkylaminoalkyl acrylates, N,N-dialkylaminoalkyl methacrylates, N-vinyl pyrrolidones, acrylamide and methacrylamide.

23. The printing ink of claim 3, wherein the polymer (a) has at least one of acid and basic functional groups, and said printing ink further contains at least one of a UV sensitizer and a heat sensitizer.

24. The printing ink of claim 4, wherein the polymer (a) has at least one of acid and basic functional groups, and said printing ink further contains at least one of a UV sensitizer and a heat sensitizer.

25. The printing ink of claim 6, wherein the polymer (a) has at least one of acid and basic functional groups, and said printing ink further contains at least one of a UV sensitizer and a heat sensitizer.

26. The printing ink of claim 23, wherein said UV sensitizer is a ketone containing one of more aromatic rings and said heat sensitizer is a peroxide or an azo free radical generating compound.

27. The printing ink of claim 24, wherein said UV sensitizer is a ketone containing one or more aromatic rings and said heat sensitizer is a peroxide or an azo free radical generating compound.

28. The printing ink of claim 25, wherein said UV sensitizer is a ketone containing one or more aromatic rings and said heat sensitizer is a peroxide or an azo free radical generating compound.

29. The printing ink of claim 26, wherein the precursor (b) is N,N-dimethylaminoethyl methacrylate, N,N-diethylaminoethyl acrylate, or N-vinyl-2-pyrrolidone.

30. The printing ink of claim 27, wherein the precursor (b) is N,N-dimethylaminoethyl methacrylate or N,N-diethylaminoethyl acrylate.

31. The printing ink of claim 28, wherein the precursor (b) is N-vinyl-2-pyrrolidone.

32. A flexographic printing ink comprising

(i) a pigment and

(ii) a liquid coating composition comprising

(a) colloidal polymer particles of at least one polymer capable of being deposited in the form of a film;

(b) a precursor of a material capable of disrupting the colloidal stability of the polymer particles to cause film formation when said flexographic printing ink is applied to a substrate; and

(c) a liquid dispersion medium.

33. The flexographic printing ink of claim 32, wherein said precursor (b) has an affinity for the polymer (a) and an affinity for said substrate, said precursor (b) being capable of acting as an adhesion-promoting linking agent between said polymer (a) and said substrate.