Thermosensing article and method of manufacture

• US 4,388,139 A
• Filed: 07/14/1980
• Issued: 06/14/1983
• Est. Priority Date: 07/14/1980
• Status: Expired due to Term

• Current Assignee: David L. Fuller
• Original Assignee: David L. Fuller
• Inventors: Fuller, David L.
• Primary Examiner(s): Gallagher, John J.
• Application Number:
  US06/168,014
• Time in Patent Office: 1,065 Days
• Field of Search: 156/64, 156/310, 156/277, 156/314, 156/307.5, 156/330, 350/330, 350/351, 73/356, 73/901, 73/150 R, 116/207, 128/736, 264/1.7, 428/1, 428/913, 23/230 LC, 374/162
• US Class Current: 156/307.5
• CPC Class Codes: C09J 5/00 Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
• CPC Class Codes: C09K 2323/055 Epoxy
• CPC Class Codes: G01K 11/165 of organic liquid crystals
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture

Abstract

A method of fabricating a strip thermometer comprising the steps of applying a plurality of cholesteric liquid crystal compositions exhibiting color changes over different temperature responsive ranges to a first substrate; coating a second substrate with an uncured solid film forming epoxy resin composition; partially curing the epoxy resin composition coating on the second substrate to a non-absorbing partially cured state in which the cholesteric liquid crystal compositions will not be absorbed by the epoxy resin composition; placing the first and second substrates together so that the partially cured epoxy resin composition overlies the cholesteric liquid crystal compositions; forcing the first and second substrates toward each other to cause the partially cured epoxy resin composition to flow around the cholesteric liquid crystal compositions and into contact with the first substrate; and subsequently, finishing the curing of the epoxy resin composition to bond the epoxy resin composition to the first substrate. The thermometer produced by this method is also disclosed.

Claims

1. A method of fabricating a strip thermometer comprising the steps of:

applying to a first substrate a plurality of cholesteric liquid crystal compositions exhibiting color changes with different temperature responsive ranges that each such composition so applied is spaced from the other such compositions so applied and where the liquid crystal compositions are sufficiently viscous to flow under pressure;

coating a second substrate with an uncured solid film forming epoxy resin composition, which absorbs the liquid crystal compositions while in the uncured state;

partially curing the epoxy resin composition coating on the second substrate while maintaining the epoxy resin coating separated from the cholesteric liquid crystal compositions until the epoxy resin composition reaches a non-absorbing partially cured state in which the cholesteric liquid crystal compositions will not be absorbed by the epoxy resin composition;

placing the first and second substrates together so that the partially cured epoxy resin composition overlies all of the cholesteric liquid crystal compositions on the first substrate while the epoxy resin composition is in the non-absorbing partially cured state;

with the partially cured epoxy resin composition overlying the cholesteric liquid crystal compositions, forcing the first and second substrates toward each other while the epoxy resin composition has sufficient fluidity to flow around the cholesteric liquid crystal compositions without substantially distorting the cholesteric liquid crystal compositions to cause the partially cured epoxy resin composition to flow around the cholesteric liquid crystal compositions and into contact with the first substrate between the cholesteric liquid crystal compositions so that the epoxy resin composition adheres to the first substrate and confines the cholesteric liquid crystal compositions between the epoxy resin composition and the first substrate; and

subsequently, finishing the curing of the epoxy resin compound to bond the epoxy resin composition to the first substrate.

2. The method of claim 1 further including the step of maintaining the temperature of the cholesteric liquid crystal compositions below the lowest temperature range of color change of any of the cholesteric liquid crystal compositions until after the step of forcing the substrates together to assist in preventing distortion of the cholesteric liquid crystal compositions as the epoxy resin composition flows around the cholesteric liquid crystal compositions.

3. The method of claim 1 wherein the thickness of the cholesteric liquid crystal compositions on the first substrate is 5-15 microns and wherein the thickness of the epoxy resin composition on the second substrate is at least three times the thickness of the cholesteric liquid crystal compositions.

4. The method of claim 3 wherein the epoxy resin composition is selected to have an initial non-absorbing viscosity when the epoxy resin composition reaches the non-absorbing partially cured state lower than the minimum flowable viscosity at which the epoxy resin composition can flow around the cholesteric liquid crystal compositions without distorting the cholesteric liquid crystal compositions.

5. The method of claim 4 where the minimum flowable viscosity is about 1,000 poise, wherein the epoxy resin composition is selected to have an initial non-absorbing viscosity of about 500 poise, and wherein the step of forcing the substrates toward each other is performed after the epoxy resin composition reaches the initial non-absorbing viscosity of about 500 poise and before the epoxy resin composition reaches the minimum flowable viscosity of about 1,000 poise.

6. The method of claim 5 wherein the thickness of the epoxy resin composition coating on the second substrate is about 25-80 microns.